The reactions of (E)-chlorovinyl sulfones with 1,2-ethanedithiol or 1,3-propanedithiol in the presence of triethylamine in toluene at 80°C lead to the selective formation of 1,3-dithiolane and 1,3-dithiane derivatives with yields of up to 49%.
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E. Lukevics (Deceased).
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1326–1328, September, 2010.
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Višņevska, J., Abele, E. & Lukevics, E. New method for the synthesis of benzene- and phenylmethanesulfonylmethyl-substituted 1,3-dithiolanes and 1,3-dithianes. Chem Heterocycl Comp 46, 1068–1070 (2010). https://doi.org/10.1007/s10593-010-0628-5
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DOI: https://doi.org/10.1007/s10593-010-0628-5