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Structure and characteristics of the ionic forms of heteroarenium salts in organic solvents (review)

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Chemistry of Heterocyclic Compounds Aims and scope

The results of investigations into the formation of the various ionic forms of heteroarenium salts, their characteristics, and their reactivity are summarized. Salts containing (4n+2)π-electron aromatic cations (n = 0–3), including chalcogenopyrylium (O, S, Se), azinium, benzo- and dibenzoazinium, and chalcogenoazolium (O, S, Se, NR) ions are examined. In this system of compounds the relationships between the structure and the macroscopic characteristics of the heteroarenium salts (ionization constants, association/dissociation constants, distances of closest interionic approach) and the effect of the nature of the ionic forms in the solutions on their reactivity in heterolytic reactions are analyzed.

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  1. L. M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, 83114, Ukraine

    O. P. Shvaika & N. A. Kovach

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  1. O. P. Shvaika
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Correspondence to O. P. Shvaika.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1603–1621, November, 2009.

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Shvaika, O.P., Kovach, N.A. Structure and characteristics of the ionic forms of heteroarenium salts in organic solvents (review). Chem Heterocycl Comp 45, 1287–1301 (2009). https://doi.org/10.1007/s10593-010-0424-2

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