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3-Cyano-4,6-dimethyl-5-R-pyridine-2-sulfonyl chlorides and N-substituted sulfonylamides based on them

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Chemistry of Heterocyclic Compounds Aims and scope

3-Cyanopyridine-2-sulfonyl chlorides were synthesized by the oxidative chlorination of the respective 3-cyanopyridine-2(1H)-2-thiones. It was established that 3-cyano-4,6-dimethylpyridine-2-sulfonyl chloride eliminates a SO2 molecule at the isolation stage. N-Substituted sulfonylamides based on the latter were obtained by the reaction of the crude sulfonyl chloride with amines in an aqueous medium.

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Authors and Affiliations

  1. Kuban State Agrarian University, Krasnodar, 350044, Russia

    I. G. Dmitrieva & L. V. Dyadyuchenko

  2. All-Russia Research Institute of Biological Plants Protection, Krasnodar, 350039, Russia

    V. D. Strelkov

  3. Kuban State University of Technology, Krasnodar, 350072, Russia

    E. A. Kaigorodova

Authors
  1. I. G. Dmitrieva
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  2. L. V. Dyadyuchenko
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  3. V. D. Strelkov
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  4. E. A. Kaigorodova
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Corresponding author

Correspondence to I. G. Dmitrieva.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1311–1318, September, 2009.

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Dmitrieva, I.G., Dyadyuchenko, L.V., Strelkov, V.D. et al. 3-Cyano-4,6-dimethyl-5-R-pyridine-2-sulfonyl chlorides and N-substituted sulfonylamides based on them. Chem Heterocycl Comp 45, 1047–1052 (2009). https://doi.org/10.1007/s10593-009-0386-4

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  • DOI: https://doi.org/10.1007/s10593-009-0386-4

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