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Oxidative reactions of azines. 12. Dehydrogenation and oxidation of 2-methyl-9-phenyl-2,3-dihydro-1H-2-azafluorene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxidation of 2-methyl-9-phenyl-2,3-dihydro-1H-2-azafluorene by air, manganese dioxide, and potassium permanganate has been studied. Depending on the nature of the oxidant it was found that this dihydroazafluorene derivative can be dehydrogenated to the indeno[2,1-c]pyridine anhydro base series, be hydroxylated, oxygenated, or undergo fission to a 2-formamidomethyl-substituted indan-1-one.

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Authors and Affiliations

  1. Russian Peoples Friendship University, Moscow, 117198

    S. V. Volkov, A. N. Levov, O. E. Volkova, N. M. Kolyadina, K. B. Polyanskii & A. T. Soldatenkov

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  1. S. V. Volkov
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  2. A. N. Levov
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  3. O. E. Volkova
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  4. N. M. Kolyadina
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  5. K. B. Polyanskii
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  6. A. T. Soldatenkov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 724–730, May, 2006.

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Volkov, S.V., Levov, A.N., Volkova, O.E. et al. Oxidative reactions of azines. 12. Dehydrogenation and oxidation of 2-methyl-9-phenyl-2,3-dihydro-1H-2-azafluorene. Chem Heterocycl Compd 42, 636–641 (2006). https://doi.org/10.1007/s10593-006-0139-6

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  • DOI: https://doi.org/10.1007/s10593-006-0139-6

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