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Synthesis, complex-formation, and extracting ability of new derivatives of dithia-13(16)-crown-4(5) ethers

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Various methods of synthesizing functional derivatives of dithia-13(16)-crown-4(5) ethers are proposed. Complex-formation of the obtained compounds with Ag+ and Pb2+ ions has been studied using 1H NMR. A radiometric method was used to investigate the extracting ability of substituted dithia-13(16)-crown-4(5) ethers in relation to Ag+ and Cd2+ ions from aqueous solution in the presence of anions of various degree of hardness, with determination of the metal content.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow, 119992, Russia

    E. V. Tulyakova, E. V. Rakhmanov, E. V. Lukovskaya, A. A. Abramov, A. V. Khoroshutin, A. A. Bobylyova & A. V. Anisimov

  2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 117421

    O. A. Fedorova

Authors
  1. E. V. Tulyakova
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  2. E. V. Rakhmanov
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  3. E. V. Lukovskaya
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  4. O. A. Fedorova
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  5. A. A. Abramov
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  6. A. V. Khoroshutin
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  7. A. A. Bobylyova
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  8. A. V. Anisimov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 233–243, February, 2006.

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Tulyakova, E.V., Rakhmanov, E.V., Lukovskaya, E.V. et al. Synthesis, complex-formation, and extracting ability of new derivatives of dithia-13(16)-crown-4(5) ethers. Chem Heterocycl Compd 42, 206–215 (2006). https://doi.org/10.1007/s10593-006-0073-7

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  • DOI: https://doi.org/10.1007/s10593-006-0073-7

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