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Condensed Tetrazolo-1,3,5-triazines. 2. Alkylation and Nucleophilic Substitution of 5-Trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-ones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new heterocyclic compound, 3-methyl-5-trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-one, was synthesized by the reaction of methyl iodide and the silver salt of 5-trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-one. An X-ray diffraction structural analysis of this product was carried out and feasibility was demonstrated for the nucleophilic substitution of the trinitromethyl group in this compound by the action of phenol, phenol derivatives, and thiophenol.

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REFERENCES

  1. B. S. Fedorov, M. A. Fadeev, A. A. Gidaspov, E. A. Kosareva, and V. V. Bakharev, Khim. Geterotsikl. Soedin., 259 (2005).

  2. K. Ingold, Theoretical Basis of Organic Chemistry [Russian translation], Mir, Moscow (1973).

    Google Scholar 

  3. A. Gordon and R. Ford, The Chemist’s Companion [Russian translation], Mir, Moscow (1976).

    Google Scholar 

  4. S. S. Novikov, G. A. Shvekhgeimer, V. V. Sevost’yanova, and V. A. Slyapochnikov, Chemistry of Aliphatic and Alicyclic Nitro Compounds [in Russian], Khimiya, Moscow (1974).

    Google Scholar 

  5. I. V. Tselinskii, I. V. Shugalei, and M. B. Shcherbin, Physical Chemistry of Nitro Compounds. Molecular Geometry and Spectroscopy of Nitro Compounds [in Russian], Lensovet Leningrad Technical Institute, Leningrad (1985).

    Google Scholar 

  6. A. V. Shastin, T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii, Khim. Geterotsikl. Soedin., 674 (1995).

  7. A. V. Shastin, T. I. Godovikova, S. P. Golova, M. V. Povorin, D. E. Dmitriev, M. O. Dekaprilevich, Yu. A. Strelenko, Yu. T. Struchkov, L. I. Khmel’nitskii, and B. L. Korsunskii, Khim. Geterotsikl. Soedin., 679 (1995).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russia

    B. S. Fedorov, A. N. Utienyshev & M. A. Fadeev

  2. Samara State Technical University, 443010, Samara, Russia

    A. A. Ghidaspov, E. V. Kachanovskaya & V. V. Bakharev

Authors
  1. B. S. Fedorov
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  2. A. N. Utienyshev
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  3. A. A. Ghidaspov
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  4. E. V. Kachanovskaya
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  5. V. V. Bakharev
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  6. M. A. Fadeev
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 582–588, April, 2005.

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Fedorov, B.S., Utienyshev, A.N., Ghidaspov, A.A. et al. Condensed Tetrazolo-1,3,5-triazines. 2. Alkylation and Nucleophilic Substitution of 5-Trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-ones. Chem Heterocycl Compd 41, 496–502 (2005). https://doi.org/10.1007/s10593-005-0178-4

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  • DOI: https://doi.org/10.1007/s10593-005-0178-4

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