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Synthesis and Properties of Some New Nicotinoyl Isocyanates and Their Fragmentation under Electron Impact

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A convenient preparative route for synthesis has been developed and nicotinoyl isocyanates (NIC) have been obtained for the first time by the action of oxalyl chloride on amides of substituted nicotinic acids. A procedure has been found for suppressing the formation of hydrochlorides of nicotinoyl amides by the competing reaction of HCl with the initial amides of nicotinic acids. The special features of the fragmentation of nicotinoyl isocyanates under electron impact have been studied.

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Authors and Affiliations

  1. Kuban State Agricultural University, Krasnodar, 350044, Russia

    L. V. Dyadyuchenko, S. N. Mikhailichenko, I. G. Dmitrieva & V. N. Zaplishny

Authors
  1. L. V. Dyadyuchenko
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  2. S. N. Mikhailichenko
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  3. I. G. Dmitrieva
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  4. V. N. Zaplishny
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 549–553, April, 2005.

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Dyadyuchenko, L.V., Mikhailichenko, S.N., Dmitrieva, I.G. et al. Synthesis and Properties of Some New Nicotinoyl Isocyanates and Their Fragmentation under Electron Impact. Chem Heterocycl Compd 41, 466–470 (2005). https://doi.org/10.1007/s10593-005-0172-x

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  • DOI: https://doi.org/10.1007/s10593-005-0172-x

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