Abstract
The sorption and transport of Cs through mixture of Ca/Mg-bentonite and sand have been studied using five column experiments with different bentonite/sand ratio, initial Cs concentration and column height. For comparison the batch experiments with small m/V ratio and high Cs concentration were performed. The results showed that Cs removal from aqueous solution by bentonite is controlled by ion-exchange reaction between Cs and Ca/Mg initially sorbed on bentonite and that there is a consistency between the results obtained from batch equilibrium data and the results obtained from column experiments verified in the environment of PHREEQC.
Similar content being viewed by others
References
Miyahara B., Ashida T., Kohara Y., Yusa Y., and Sasaki N.: Radiochimica Acta 52/53 (1991) 293.
Oscarson D. W., Hume H. B., and King F.: Clays and Clay Minerals 42 (1994) 731.
Khan S. A., Riaz-ur Rehman, and Khan M. A.: Waste Management 14 (1994) 629.
Tsai S. Ch., Quyang S., and Hsu Ch. N.: Applied Radiation and Isotopes 54 (2001) 209.
von Gunten H. R., Waber U. E. and Krahenbûhl U.: J. Contam. Hydrol. 3 (1988) 237.
Aharoni C., Pasricha N. S., and Sparks D. L.: Soil Sci. 156 (1992) 233.
Vieno T.: Safety analysis of disposal of spent nuclear fuel. VTT Publications 177, Espoo 1994, 256 pp.
Smith J. T. and Comans R. N. J.: Geoch. Cosmoch. Acta 60 (1996) 995.
Parkhurst D. L. and Appelo C. A. J.: User’s guide to PHREEQC (version 2)-A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. Water-Resources Investigations Report 99-4259, U.S. Geological Survey, Denver 1999, 312 pp.
Kozaki T., Sato H., Sato S., and Ohashi H.: Engineering Geology 54 (1999) 223.
Beigel C. and Di Pietro L.: Soil Sci. Soc. Am. J. 63 (1999) 1177.
Jochová M., Punčochář M., Horáček J., Štamberg K., and Vopálka D.: Fuel 83 (2004) 1197.
Gaines G. L. and Thomas H. C.: Journal of Chemical Physics 21 (1953) 714.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kraus, L., Klika, Z. & Vopálka, D. Modeling of cesium transport through sand-bentonite mixtures. Czech J Phys 56, D111–D118 (2006). https://doi.org/10.1007/s10582-006-1006-5
Issue Date:
DOI: https://doi.org/10.1007/s10582-006-1006-5