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Czechoslovak Journal of Physics

, Volume 56, Supplement 4, pp D119–D128 | Cite as

Sorption and diffusion behaviours of strontium in sodium-type bentonite bed

  • M. Tsukamoto
  • T. Fujita
  • T. Ohe
Article
  • 82 Downloads

Abstract

Sorption and diffusion of Sr were examined using a typical Japanese bentonite. The experimental results showed that Sr sorption on the bentonite had linear relationship between the equilibrium Sr concentration and Sr sorption amount, i.e., Henry’s type of sorption, in wide initial Sr concentration from 1.1 × 10−9 to 1.1 × 10−4 mol L−1 at pH 10. The Sr sorption also indicated pH dependence in pH range between 2 and 12. Sorption modelling calculation indicated that cation-exchange reactions contributed to Sr sorption in the pH range studied and a surface complexation reaction was predominant above pH 8. Diffusion of Sr in loosely compacted bentonite bed was described by pore and surface diffusion and surface complexation of Sr. Chemical-transport calculations reproduce the diffusion data at pH 5 using the cation-exchange parameters obtained in the analysis of the batch sorption experiment.

Keywords

Bentonite Apparent Diffusion Coefficient Diffusion Experiment Compact Bentonite Batch Sorption Experiment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Institute of Physics, Academy of Sciences of Czech Republic 2006

Authors and Affiliations

  • M. Tsukamoto
    • 1
  • T. Fujita
    • 1
  • T. Ohe
    • 2
  1. 1.Central Research Institute of Electric Power IndustryTokyoJapan
  2. 2.Energy Engineering CourseTokai UniversityKanagawaJapan

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