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Uranyl p-toluenesulphonate and its crystal hydrates. Synthesis and dehydration-hydration processes

  • Session 3 Chemistry of Actinide and Trans-Actinide Elements
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Czechoslovak Journal of Physics Aims and scope

Abstract

Lowest hydrates of uranyl p-toluenesulphonate (UPTS) and anhydrous salt were synthesised. The dehydration-hydration processes were studied by thermal gravimetric analysis. It has been established that the hydrate shell of UPTS has a layered structure. The IR spectra of UPTS and its hydrates were recorded. It was found that the IR spectra of UPTS crystal hydrates of the same composition, produced in dehydration-hydration, noticeably differ in the range of water vibrations and are the same in the range corresponding to vibrations of sulphonate groups.

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Authors and Affiliations

  1. V. G. Khlopin Radium Institute, St. Petersburg, Russia

    A. V. Baluev, V. S. Mityakhina & S. V. Bogachev

  2. St. Petersburg State University, St. Petersburg, Russia

    I. G. Suglobova

Authors
  1. A. V. Baluev
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  2. V. S. Mityakhina
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  3. S. V. Bogachev
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  4. I. G. Suglobova
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Additional information

This work was supported by the International Science and Technology Center (project no. 1306)

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Baluev, A.V., Mityakhina, V.S., Bogachev, S.V. et al. Uranyl p-toluenesulphonate and its crystal hydrates. Synthesis and dehydration-hydration processes. Czech J Phys 53 (Suppl 1), A331–A337 (2003). https://doi.org/10.1007/s10582-003-0042-7

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  • DOI: https://doi.org/10.1007/s10582-003-0042-7

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