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Chain-branching reactions in the processes of promotion and inhibition of hydrogen combustion

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

The role of chain branching and termination reactions in the inhibition and promotion of hydrogen-oxygen flames was studied numerically. Based on the results of sensitivity analysis, methods were proposed for estimating the effectiveness of flame inhibition and promotion based on the net rate of formation of hydrogen atoms and the burning velocity sensitivity coefficients to the branching rate constant. The effect of the heat release rate in recombination reactions involving inhibitors and promoters on the flame propagation velocity was studied.

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References

  1. J. Chariton and Z. Walta, “Oxydation von Phosphordampfen bei niedrigen Drucken,” Z. Physik, Bd 39, S. 547–556 (1926).

    Article  ADS  Google Scholar 

  2. V. N. Zabelin, A. A. Koval’skii, D. I. Kopp, and N. N. Semenov, “Ignition limits of 2H2 + O2 and 2CO + O2 mixtures,” Zh. Fiz., Khim., 1, No. 2. 263–280 (1930).

    Google Scholar 

  3. G. H. Gibson and C. N. Hinshelwood, “The homogeneous reaction between hydrogen and oxygen,” Proc. Roy. Soc. A, 119, 591–606 (1928).

    Article  ADS  Google Scholar 

  4. A. A. Kovalskii, “Die Verbrennungs Kinetic von Wasserstoff,” Z. Sowjetunion, 1, S. 595–596 (1932).

    Google Scholar 

  5. A. B. Nalbandyan and V. V. Voevodskii, Mechanism of Hydrogen Oxidation and Combustion [in Russian], Izd. Akad. Nauk SSSR, Moscow (1949).

    Google Scholar 

  6. V. V. Voevodskii, Physics and Chemistry of Elementary Chemical Processes [in Russian], Nauka, Moscow (1969).

    Google Scholar 

  7. J. Warnatz, U. Maas, and R. W. Dibble, Combustion, Springer, Berlin (1996).

    Google Scholar 

  8. N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity [in Russian], Izd. Akad. Nauk SSSR, Moscow (1958).

    Google Scholar 

  9. Ya. B. Zel’dovich, Theory of Combustion and Detonation of Gases [in Russian], Izd. Akad. Nauk SSSR, Moscow-Leningrad (1944).

    Google Scholar 

  10. Ya. B. Zel’dovich, and D. A. Frank-Kamenetskii, “The theory of thermal flame propagation,” Zh. Fiz. Khim., 12, No. 1, 100–105 (1938).

    Google Scholar 

  11. Ya. B. Zel’dovich, “Chain reactions in hot flames: approximate theory of flame velocity,” Kinet. Katal., 11, No. 3, 305–318 (1961).

    Google Scholar 

  12. V. N. Kondrat’ev and E. I. Kondrat’eva, “Catalytic recombination of active centers as applied to measurements of their concentration in the reaction zone,” Zh. Fiz. Khim., 20, No. 11. 1239–1247 (1946).

    Google Scholar 

  13. V. N. Panfilov, Yu. D. Tsvetkov, and V. V. Voevodskii, “Detection of hydrogen atoms in a low-pressure hydrogen flame using electromagnetic spin resonance,” Kinet. Katal., 1, No. 2, 333 (1960).

    Google Scholar 

  14. V. N. Panfilov, “Investigation of hydrogen atoms in a low-pressure hydrogen flame,” Kinet. Katal., 3, No. 5, 643–650 (1962).

    Google Scholar 

  15. V. N. Panfilov and V. V. Voevodskii, “Investigation of the interaction of hydrogen atoms with molecules of some compounds in a low-pressure hydrogen flame,” Kinet. Katal., 6, No. 4, 577–584 (1965).

    Google Scholar 

  16. O. P. Korobeinichev, V. M. Shvartsberg, S. B. Il’in, A. A. Chernov, and T. A. Bolshova, “Laminar flame structure in a low-pressure of premixed H2/O2/Ar mixture,” Combust., Explos., Shock Waves, 35, No. 3, 239–244 (1999).

    Article  Google Scholar 

  17. O. P. Korobeinichev, A. A. Chernov, and T. A. Bolshova, “Decay of organophosphorus compounds in flames IV: Decay of DIMP in a flame of H2 + O2 + Ar,” Combust. Flame, 123, No. 3, 412–420 (2000).

    Article  Google Scholar 

  18. O. P. Korobeinichev, T. A. Bolshova, V. M. Shvartsberg, and A. A. Chernov, “Inhibition and promotion of combustion by organophosphorus compounds added to flames of CH4 or H2 in O2 and Ar,” Combust. Flame, 125, Nos. 1–2, 744–751 (2001).

    Article  Google Scholar 

  19. O. P. Korobeinichev, I. V. Rybitskaya, A. G. Shmakov, A. A. Chernov, T. A. Bolshova, and V. M. Shvartsberg, “Inhibition of atmospheric-pressure H2/O2/N2 flames by trimethylphosphate over range of equivalence ratio,” Proc. Combust. Inst., 32, No. 2, 2591–2597 (2009).

    Article  Google Scholar 

  20. M. D. Rumminger, V. I. Babushok, and G. T. Linteris, “Temperature regions of optimal chemical inhibition of premixed flames,” Proc. Combust. Inst., 29, 329–336 (2002).

    Article  Google Scholar 

  21. V. V. Zamashchikov and V. A. Bunev, “Estimation of the efficiency of inhibitors acting on combustion of gases,” Combust., Explos., Shock Waves, 37, No. 4, 378–386 (2001).

    Article  Google Scholar 

  22. T. A. Bolshova and O. P. Korobeinichev, “Promotion and inhibition of a hydrogen-oxygen flame by the addition of trimethyl phosphate,” Combust., Explos., Shock Waves, 42, No. 5, 493–502 (2006).

    Article  Google Scholar 

  23. M. R. Zachariah and O. I. Smith, “Experimental and numerical studies of sulfur chemistry in H2/O2/SO2 flames,” Combust. Flame, 69, No. 2, 125–139 (1987).

    Article  Google Scholar 

  24. The Leeds Methane Oxidation Mechanism; http://garfield.chem.elte.hu/Combustion/methane.htm.

  25. N. M. Rubtsov, V. I. Chernysh, G. I. Tsvetkov, and B. S. Seplyarskii “Influence of Cr(CO)6 and Mo(CO)6 on the critical conditions for ignition and the velocities of flame propagation for the chain-branching hydrogen oxidation and propylene,” Mend. Commun., 16, No. 5, 282–284 (2006).

    Article  Google Scholar 

  26. M. D. Rumminger, D. Reinelt, V. Babushok, and G. T. Linteris, “Numerical study of the inhibition of premixed and diffusion flames by iron pentacarbonyl,” Combust. Flame, 116, Nos. 1–2, 207–219 (1999).

    Article  Google Scholar 

  27. T. M. Jayaweera, C. F. Melius, W. J. Pitz, C. K. Westbrook, O. P. Korobeinichev, V. M. Shvartsberg, A. G. Shmakov, and H. Curran, “Flame inhibition by organophosphorus-containing compounds over a range of equivalence ratios,” Combust. Flame, 140, Nos. 1–2, 103–115 (2005).

    Article  Google Scholar 

  28. Organophosphorus Compounds Effect on Flame Rates over a Range of Equivalence Ratios; https: //wwwpls.llnl.gov/?url=science_and_technology-chemistrycombustion-organophosphorus_over_range.

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Correspondence to O. P. Korobeinichev.

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Translated from Fizika Goreniya i Vzryva, Vol. 46, No. 2, pp. 26–35, March–April, 2010.

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Korobeinichev, O.P., Panfilov, V.N., Shvartsberg, V.M. et al. Chain-branching reactions in the processes of promotion and inhibition of hydrogen combustion. Combust Explos Shock Waves 46, 140–148 (2010). https://doi.org/10.1007/s10573-010-0022-8

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  • DOI: https://doi.org/10.1007/s10573-010-0022-8

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