Abstract
Novel insulation textiles have become very important as they can regulate temperature according to the ambient temperature. The use is made of Phase Change Materials (PCMs) to design a wide range of textiles for thermal management purposes. Recently, instead of using PCM-containing packages in clothing, such methods as PCM encapsulation have been proposed for the reduction of the product's final weight. In this research, for the first time, we used a eutectic mixture of Na2HPO4·12H2O and Na2CO3·10H2O as an inorganic PCM in the fabric's structure. The coating technique and silicone rubber were then applied for the preparation of a thermo-regulating cotton fabric. Thermo-physical effects related to the thermal stability of the treated fabric were then investigated by utilizing Differential Scanning Calorimetry (DSC) and Thermo Gravimetric Analysis (TGA). Fourier transform infrared spectroscopy (FT-IR), Field Emission Scanning Electron Microscope (FESEM) and EDS mapping were subsequently utilized to probe the samples microstructure. Subsequently, mechanical and physical qualities of the treated fabric were probed too. The results revealed that the time interval to reach a certain temperature was enhanced by 150% due using the inorganic eutectic PCM in the coated fabric structure. In addition, the DSC results revealed the 28.9 °C melting temperature as well as the latent heat of fusion of 14.9 J/g for the treated cotton fabric. Therefore, it is possible to use silicone rubber to hold PCMs on textile structures, without microencapsulation; also, the treated textile can be used as an effective smart thermal insulator.
Graphical Abstract

This is a preview of subscription content, access via your institution.













Notes
Latent heat storage.
References
Agyenim F, Hewitt N, Eames P, Smyth M (2010) A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS). Renew Sustain Energy Rev 14:615–628. https://doi.org/10.1016/j.rser.2009.10.015
Alehosseini E, Jafari SM (2020) Nanoencapsulation of phase change materials (PCMs) and their applications in various fields for energy storage and management. Adv Colloid Interface Sci 283:102226. https://doi.org/10.1016/j.cis.2020.102226
Borhani S, Etemad SG, Ravandi SAH (2011) Dynamic heat and moisture transfer in bulky PAN nanofiber mats. Heat Mass Transf 47:807–811. https://doi.org/10.1007/s00231-011-0767-y
Byung Chul S, Sang Done K, Won-Hoon P (1989) Phase separation and supercooling of a latent heat-storage material. Energy 14:921–930. https://doi.org/10.1016/0360-5442(89)90047-9
Chartoff RP, Sircar AK (2004) Thermal analysis of polymers. In: Encyclopedia of Polymer Science and Technology. Wiley, Inc., Hoboken, NJ, USA
Choi K, Cho G (2006) Development of phase change materials treated thermostatic fabric by screen printing method. Res J Text Appar 10:19–24. https://doi.org/10.1108/RJTA-10-02-2006-B003
Ciolacu D, Ciolacu F, Popa VI (2011) Amorphous cellulose—structure and characterization. Cellul Chem Technol 45:13–21
Duan Z, Zhang H, Sun L et al (2014) CaCl2·6H2O/Expanded graphite composite as form-stable phase change materials for thermal energy storage. J Therm Anal Calorim 115:111–117. https://doi.org/10.1007/s10973-013-3311-0
García-Romero A, Diarce G, Ibarretxe J et al (2012) Influence of the experimental conditions on the subcooling of Glauber’s salt when used as PCM. Sol Energy Mater Sol Cells 102:189–195. https://doi.org/10.1016/j.solmat.2012.03.003
Ghule A, Bhongale C, Chang H (2003) Monitoring dehydration and condensation processes of Na2HPO4 12H2O using thermo-Raman spectroscopy. Spectrochim Acta Part A Mol Biomol Spectrosc 59:1529–1539. https://doi.org/10.1016/S1386-1425(02)00395-5
Giro-Paloma J, Martínez M, Cabeza LF, Fernández AI (2016) Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): a review. Renew Sustain Energy Rev 53:1059–1075. https://doi.org/10.1016/j.rser.2015.09.040
Günther E, Hiebler S, Mehling H (2006) Determination of the heat storage capacity of PCM and PCM-objects as a function of temperature. In: Ecostock. pp 1–7
Guo Y, Li K, Hou C et al (2016) Fluoroalkylsilane-modified textile-based personal energy management device for multifunctional wearable applications. ACS Appl Mater Interfaces 8:4676–4683. https://doi.org/10.1021/acsami.5b11622
Hassabo AG, Mohamed AL, Wang H et al (2015) Metal salts rented in silica microcapsules as inorganic phase change materials for textile usage. Inorg Chem an Indian J 10:59–65
Hemmatian B, Heidarzadeh N, Fard GC, Maleknia L (2020) Fabrication of phase-change core/shell nanofibers based on a eutectic fatty acid mixture to control body temperature fluctuations. Mater Chem Phys 245:122738. https://doi.org/10.1016/j.matchemphys.2020.122738
Iqbal K, Sun D (2014) Development of thermo-regulating polypropylene fibre containing microencapsulated phase change materials. Renew Energy 71:473–479. https://doi.org/10.1016/j.renene.2014.05.063
Iqbal K, Sun D (2018) Synthesis of nanoencapsulated Glauber’s salt using PMMA shell and its application on cotton for thermoregulating effect. Cellulose 25:2103–2113. https://doi.org/10.1007/s10570-018-1692-8
Jamekhorshid A, Sadrameli SM, Farid M (2014) A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium. Renew Sustain Energy Rev 31:531–542. https://doi.org/10.1016/j.rser.2013.12.033
Jamil N, Kaur J, Pandey AK et al (2019) A review on nano enhanced phase change materials: an enhancement in thermal properties and specific heat capacity. J Adv Res Fluid Mech Therm Sci 57:110–120
Kazemi Z, Mortazavi SM (2014) A new method of application of hydrated salts on textiles to achieve thermoregulating properties. Thermochim Acta 589:56–62. https://doi.org/10.1016/j.tca.2014.05.015
Kim J, Cho G (2002) Thermal storage/release, durability, and temperature sensing properties of thermostatic fabrics treated with octadecane-containing microcapsules. Text Res J 72:1093–1098. https://doi.org/10.1177/004051750207201209
Lane GA (1986) Solar heat storage: Latent heat materials. Volume II. Technology. CRC, Inc.,Boca Raton, FL, United State
Liu Z, Chung DDL (2001) Calorimetric evaluation of phase change materials for use as thermal interface materials. Thermochim Acta 366:135–147. https://doi.org/10.1016/S0040-6031(00)00716-4
Liu Y, Yang Y (2017) Preparation and thermal properties of Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrate salt as a novel phase change material for energy storage. Appl Therm Eng 112:606–609. https://doi.org/10.1016/j.applthermaleng.2016.10.146
Liu Y, Yang Y (2018) Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: the influence of chemical structures of expanded graphite oxide. Renew Energy 115:734–740. https://doi.org/10.1016/j.renene.2017.08.097
Liu C, Rao Z, Zhao J et al (2015) Review on nanoencapsulated phase change materials: Preparation, characterization and heat transfer enhancement. Nano Energy 13:814–826. https://doi.org/10.1016/j.nanoen.2015.02.016
Mehling H, Cabeza LF (2008) Heat and cold storage with PCM, 1st edn. Springer-Verlag, Berlin Heidelberg
Milián YE, Gutiérrez A, Grágeda M, Ushak S (2017) A review on encapsulation techniques for inorganic phase change materials and the influence on their thermophysical properties. Renew Sustain Energy Rev 73:983–999. https://doi.org/10.1016/j.rser.2017.01.159
Mohamed SA, Al-Sulaiman FA, Ibrahim NI et al (2017) A review on current status and challenges of inorganic phase change materials for thermal energy storage systems. Renew Sustain Energy Rev 70:1072–1089. https://doi.org/10.1016/j.rser.2016.12.012
Mondal S (2008) Phase change materials for smart textiles - an overview. Appl Therm Eng 28:1536–1550. https://doi.org/10.1016/j.applthermaleng.2007.08.009
Nakamoto K (2008) Infrared and Raman spectra of inorganic and coordination compounds: Part B: applications in coordination, organometallic, and bioinorganic chemistry. Wiley, United Kingdom
Nazir H, Batool M, Bolivar Osorio FJ et al (2019) Recent developments in phase change materials for energy storage applications: a review. Int J Heat Mass Transf 129:491–523. https://doi.org/10.1016/j.ijheatmasstransfer.2018.09.126
Okubo N (1985) Thermal analysis of silicon rubber. In: Application Brief TA No.18, SII NanoTechnology Inc. Tokyo, pp 2–3
Pause BH (2005) Material made from a silicone rubber,production process, and application
Pause BH (2009a) Material made from a silicone rubber, production process, and application
Pause BH (2009b) Fire-resistant cooling suit
Pavia DL, Lampman GM, Kriz GS, Vyvyan JA (2014) Introduction to spectroscopy. Cengage Learning
Rathod MK, Banerjee J (2013) Thermal stability of phase change materials used in latent heat energy storage systems. A review. Renew Sustain Energy Rev 18:246–258. https://doi.org/10.1016/j.rser.2012.10.022
Salaün F, Devaux E, Bourbigot S, Rumeau P (2008) Development of a precipitation method intended for the entrapment of hydrated salt. Carbohydr Polym 73:231–240. https://doi.org/10.1016/j.carbpol.2007.11.020
Salaün F, Devaux E, Bourbigot S, Rumeau P (2010) Influence of the solvent on the microencapsulation of an hydrated salt. Carbohydr Polym 79:964–974. https://doi.org/10.1016/j.carbpol.2009.10.027
Sánchez P, Sánchez-Fernandez MV, Romero A et al (2010) Development of thermo-regulating textiles using paraffin wax microcapsules. Thermochim Acta 498:16–21. https://doi.org/10.1016/j.tca.2009.09.005
Sanchez-Silva L, Sanchez P, Rodríguez JF (2011) Effective method of microcapsules production for smart fabrics. In: Bernardes MA dos S (ed) Developments in Heat Transfer. InTech, London, pp 650–666
Saraç EG, Öner E, Kahraman MV (2019) Microencapsulated organic coconut oil as a natural phase change material for thermo-regulating cellulosic fabrics. Cellulose 26:8939–8950. https://doi.org/10.1007/s10570-019-02701-9
Sharma A, Tyagi VV, Chen CR, Buddhi D (2009) Review on thermal energy storage with phase change materials and applications. Renew Sustain Energy Rev 13:318–345. https://doi.org/10.1016/j.rser.2007.10.005
Shin Y, Yoo D-I, Son K (2005) Development of thermoregulating textile materials with microencapsulated phase change materials (PCM). IV. Performance properties and hand of fabrics treated with PCM microcapsules. J Appl Polym Sci 97:910–915. https://doi.org/10.1002/app.21846
Su C, Suarez DL (1997) In situ infrared speciation of adsorbed carbonate on aluminum and iron oxides. Clays Clay Miner 45:814–825. https://doi.org/10.1346/CCMN.1997.0450605
Su W, Darkwa J, Kokogiannakis G (2015) Review of solid–liquid phase change materials and their encapsulation technologies. Renew Sustain Energy Rev 48:373–391. https://doi.org/10.1016/j.rser.2015.04.044
Xie N, Huang Z, Luo Z et al (2017) Inorganic salt hydrate for thermal energy storage. Appl Sci 7:1317. https://doi.org/10.3390/app7121317
Yoo H, Lim J, Kim E (2012) Effects of the number and position of phase-change material-treated fabrics on the thermo-regulating properties of phase-change material garments. Text Res J 83:671–682. https://doi.org/10.1177/0040517512461700
Zhang H, Wang Z, Dai J (1995) A study of the thermodynamic properties and dehydration reaction kinetics of some salt-hydrates. J Therm Anal 45:109–115. https://doi.org/10.1007/BF02548670
Funding
This work was supported by Isfahan University of Technology.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflicts of interest
The authors have not disclosed any competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Kazemi, Z., Mortazavi, S.M. & Shahmoradi Ghaheh, F. Developing a novel thermo-regulating cotton fabric using inorganic eutectic phase change material. Cellulose 30, 1287–1303 (2023). https://doi.org/10.1007/s10570-022-04919-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-022-04919-6
Keywords
- Smart textile
- Thermo-regulating fabric
- Latent Heat storage
- Inorganic eutectic PCMs
- Cotton