Abstract
C6-Fluorocarbon-dendrimer has been applied to the cotton knit fabric to develop oil–water repellent, oil–water separation, acid-resistant, self-cleaning, UV-resistant, and antibacterial properties. The C6-Fluorocarbon (FC)-dendrimer-coated 100% cotton single jersey knitted fabric samples were prepared using the “pad-dry-cure” method. The 90 g/L and 100 g/L FC-dendrimer-treated cotton fabrics showed excellent water repellency and oil–water separation as well as good self-cleaning performance. However, air permeability and heat conductivity were reduced by 13%, 15%, and 40%, 54%, for 90 g/L and 100 g/L FC-dendrimer-treated cotton fabrics compared to untreated fabrics. The presence of FC-dendrimer in the treated fabric was confirmed by FTIR, SEM, EDX, and XRD analyses. SEM analysis was employed to study the morphology of deposited FC-dendrimer particles on the fabric surface. TGA and DTA evaluated thermal performance. The FC-dendrimer-treated fabric also showed acid resistance, self-cleaning performance, and UV resistance attribute. In addition, Bacterial population growth appears to be less in the FC-dendrimer-treated sample than in the untreated sample. Overall, the result suggests that FC-dendrimer can be a valuable ingredient in the manufacture of multifunctional products.
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AATCC Test Method 124-2018t (2018) Smoothness appearance of fabrics after repeated home laundering. AATCC technical manual, Research Triangle Park, NC 27709, USA, pp 195–198
AATCC Test Method 127-2008 (2009) Water resistance: hydrostatic pressure test. AATCC technical manual, Research Triangle Park, NC 27709, USA, pp 201–202
AATCC Test Method TM 22-2005 (2009) Water repellency: spray test. AATCC technical manual, Research Triangle Park, NC 27709, USA, pp 67–69
AATCC Test Method: TM 147-2004 (2010) Determination of zone of inhibition by qualitative method. AATCC technical manual, Research Triangle Park, NC 27709, USA, 85 (2010), pp 251–252
AATCC Test Method: TM 183-2004 (2010) Transmittance or blocking of erythemally weighted ultraviolet radiation through fabric, in: AATCC technical manual. AATCC technical manual. Research Triangle Park, NC 27709, USA, pp 318–319
Abo-Shosha MH, El-Hilw ZH, Aly AA, Amr A, Nagdy ASIE (2008) Paraffin wax emulsion as water repellent for cotton/polyester blended fabric. J Ind Text 37(4):315–325
Ajgaonkar DB (1998) Knitting technology. Universal Publishing Corporation, Bombay, pp 2–3
Akbari S, Kozłowski RM (2019) A review of application of amine-terminated dendritic materials in textile engineering. J Text Inst 110(3):460–467
Altınışık A, Bozacı E, Akar E, Seki Y, Yurdakoc K, Demir A, Özdogan E (2013) Development of antimicrobial cotton fabric using bionanocomposites. Cellulose 20:3111–3121
ASTM D4966-98 (1989) Standard test method for abrasion resistance of textile fabrics (Martindale Abrasion tester method). ASTM International, West Conshohocken
ASTM D 3786-87 (1987) Test method for hydraulic or pneumatic bursting strength of textile fabrics-diaphragm bursting strength tester method. American Society for Testing Materials, West Conshohocken
ASTM D3776-96 (2002) Standard test methods for mass per unit area (weight) of fabric. ASTM International, West Conshohocken
Atav R, Bariş B (2016) Dendrimer technology for water and oil repellent cotton textiles. AATCC J Res 3(2):16–24
Attia NF, Moussa M, Sheta AM, Taha R, Gamal H (2017) Synthesis of effective multifunctional textile based on silica nanoparticles. Prog Org Coat 106:41–49
Baig U, Matin A, Gondal MA, Zubair SM (2019) Facile fabrication of superhydrophobic, superoleophilic photocatalytic membrane for efficient oil-water separation and removal of hazardous organic pollutants. J Clean Prod 208:904–915
Behera BK, Hari PK (2010) Woven textile structure: theory and applications. Elsevier, Amsterdam, pp 3–30
Beumer R, Bloomfield S, Exner M, Fara G, Nath K, Scott E (2000) Microbial resistance and biocides: a review. International Forum on Home Hygiene (IFH). In: International scientific forum on home hygiene, 2000
BS 2544: 1954 (1954) Determination of thickness of textile fabric. In: British standard handbook, vol 11, p 174
BS 5636 (1990) Method of test for the determination of the permeability of fabrics to air. British Standards Institute, Berkshire
BS 7209 (1990) Specification for water vapor permeable apparel fabrics. British Standards Institute, Berkshire
Cao C, Cheng J (2018) Fabrication of robust surfaces with special wettability on porous copper substrates for various oil/water separations. Chem Eng J 347:585–594
Cerne L, Simoncic B (2004) Influence of repellent finishing on the surface free energy of cellulosic textile substrates. Text Res J 74(5):426–432
Chinta SK, Satish D (2014) Studies in waterproof breathable textiles. Int J Recent Dev Eng Technol 3:16–20
Chowdhury KP (2018a) Impact of different water repellent finishes on cotton double jersey fabrics. J Text Sci Technol 4(3):85–99
Chowdhury KP (2018b) Process intensification of fluorocarbon-free and fluorocarbon-based water repellent finishes on cotton knit fabrics. J Text Eng Fash Technol 4(3):232–240
Chung C, Lee M, Choe EK (2004) Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr Polym 58:417–420
Colleoni C, Massafra MR, Migani V, Rosace G (2011) Dendrimer finishing influence on CO/PES blended fabrics color assessment. J Appl Polym Sci 120:2122–2129
Crews PC, Clark DJ (1990) Evaluating UV absorbers and antioxidants for topical treatment of upholstery fabrics. Text Res J 60(3):172–179
Danish Environmental Protection Agency, More environmentally friendly alternatives to PFOS compounds and PFOA, March 2005
Dashairya L, Sahu A, Saha P (2019) Stearic acid treated polypyrrole-encapsulated melamine formaldehyde superhydrophobic sponge for oil recovery. Adv Compos Hybrid Mater 2(1):70–82
De P, Sankhe MD, Chaudhari SS, Mathur MR (2005) UV-resist, water-repellent breathable fabric as protective textiles. J Ind Text 34:209–222
Dong C, Lu Z, Zhang F, Zhu P, Zhang L, Sui S (2015) Preparation and properties of cotton fabrics treated with a novel polysiloxane water repellent and flame retardant. Mater Lett 152:276–279
Flynn JH (2002) Applications to polymers and plastics. In: Handbook of thermal analysis and calorimetry. https://www.sciencedirect.com/topics/chemistry/polysiloxane
Forsberg K, Van den Borre A, Iii NH, Zeigler JP (2014) Quick selection guide to chemical protective clothing, 6th edn. Wiley, Hoboken
Gal’braikh LS (2005) Modified fibre and film materials. Fibre Chem 37:338–345
Ghosh S, Yadav S, Vasanthan N, Sekosan G (2010) A study of antimicrobial property of textile fabric treated with modified dendrimers. J Appl Polym Sci 115:716–722
Guo Z, Liu W, Su B-L (2011) Superhydrophobic surfaces: from natural to biomimetic to functional. J Colloid Interf Sci 353:335–355
Gupta S (2002) VK Kapoor-fundamental of mathematical statistics. Sultan Chand and Sons, Educational Publishers, New Delhi
Haynes WM (2017) CRC handbook of chemistry and physics, vol 2016–2017, 97th edn. CRC Press, Boca Raton
Jain AK, Tesema AF, Haile A (2018) Development of multifunctional cotton using fluorocarbon resin. J Eng Fibers Fabr 1:1–8
Jenkins R, Snyder RL (1996) Introduction to X-ray powder diffractometry. Wiley, New York
Jeyasubramanian K, Hikku G, Preethi A, Benitha V, Selvakumar N (2016) Fabrication of water repellent cotton fabric by coating nano particle impregnated hydrophobic additives and its characterization. J Ind Eng Chem 37:180–189
Kasturiya N, Bhargava G (2003) Liquid repellency and durability assessment: a quick technique. J Ind Text 32:187–222
Khoddami A, Gong H, Ghadimi G (2012) Effect of wool surface modification on fluorocarbon chain re-orientation. Fiber Polym 13:28–37
Khoddami A, Bazanjani S, Gong R (2015) Investigating the effects of different repellent agents on the performance of novel polyester/wool blended fabrics. J Eng Fib Fabr 10:137–146
Krishnan S (1991) Technology of breathable coatings. J Coat Fabr 21:71–74
Lee S, Cho J-S, Cho G (1999) Antimicrobial and blood repellent finishes for cotton and nonwoven fabrics based on chitosan and fluoropolymers. Text Res J 69(2):104–112
Li J, Wang G, Meng Q, Ding C, Jiang H, Fang Y (2014) A biomimetic nano hybrid coating based on the lotus effect and its anti-biofouling behaviors. Appl Surf Sci 315:407–414
Lidija C, Simoncic B (2008) The use of Zisman model in determining the critical surface tension of the water and oil repellent finished textiles. Tekstilec 51(4/6):107–121
Lin J, Cai Y, Wang X, Ding B, Yu J, Wang M (2011) Fabrication of biomimetic superhydrophobic surfaces inspired by lotus leaf and silver ragwort leaf. Nanoscale 3:1258–1262
Majumdar A, Gupta D, Gupta S (eds) (2020) Functional textiles and clothing. Springer, Singapore
Midha VK, Vashish R, Midha V (2014) Durability of fluoropolymer and antibacterial finishes on woven surgical gown fabrics. Fash Text 1:12
Namligoz ES, Bahtiyari MI, Hosaf E, Coban S (2009) Performance comparison of new (dendrimer, nanoproduct) and conventional water, oil and stain repellents. Fibres Text East Eur 17:76–81
Omae K, Takebayashi T, Ishizuka C, Uemura T (1998) Toxicity of silicon compounds in semiconductor industries Hiroshi NAKASHIMA. J Occup Health 40:270–275
Pande S, Crooks RM (2011) Analysis of poly (amidoamine) dendrimer structure by UV–Vis spectroscopy. Langmuir 27:9609–9613
Roey MV (1992) Water-resistant breathable fabrics. J Coat Fabr 22:20–31
Russell AD, Chopra I (1996) Understanding antibacterial action and resistance. Ellis Horwood Limited, London
Sayed U, Dabhi P (2014) Finishing of textiles with fluorocarbons. In: Williams J (ed) Waterproof and water repellent. Textiles and clothing. Elsevier, Amsterdam, pp 139–152
Schindler WD, Hauser PJ (2004) Chemical finishing of textiles. Woodhead Publishing, Cambridge, pp 74–84
Shekar RI, Yadav A, Kasturiya N, Raj H (1999) Studies on combined flame-retardant and water-repellent treatments on cotton drill fabric. Indian J Fibre Text 24:197–207
Shekar RI, Kasturiya N, Raj H, Mathur G (2001) Studies on effect of water repellent treatment on flame retardant properties of fabric. J Ind Text 30:222–254
Siddiqui AR, Maurya R, Balani K (2017) Superhydrophobic self-floating carbon nanofiber coating for efficient gravity-directed oil/water separation. J Mater Chem A 5:2936–2946
Singh AK, Singh JK (2016) Fabrication of zirconia based durable superhydrophobic–superoleophilic fabrics using non fluorinated materials for oil–water separation and water purification. RSC Adv 6:103632–103640
Skin Cancer Foundation (2015). The skin cancer foundation shares essential sun safety tips for outdoor winter sports. http://www.skincancer.org/media-and-press/press-release-2015/winter-sports
Sun D, Wang W, Yu D (2017) Highly hydrophobic cotton fabrics prepared with fluorine-free functionalized silsesquioxanes. Cellulose 24:4519–4531
Tomalia DA, Baker H, Dewald J, Hall M, Kallos G, Martin S, Smith P (1985) A new class of polymers: starburst-dendritic macromolecules. Polym J 17(1):117–132
United States Environmental Protection Agency (2004) A guide to the UV Index. https://www.epa.gov/sites/production/files/documents/uviguide.pdf
Vigneswaran C, Chandrasekaran K, Senthilkumar P (2009) Effect of thermal conductivity behavior of jute/cotton blended knitted fabrics. J Ind Text 38:289–307
Wang C-X, Mao Li, Jiang G-W, Fang K-J, Tian A (2007) Surface modification with silicon sol on cotton fabrics for water-repellent finishing. Res J Text Appl 11:27–34
Wang H, Xue Y, Ding J, Feng L, Wang X, Lin T (2011) Durable, self-healing superhydrophobic and superoleophobic surfaces from fluorinated-decyl polyhedral oligomeric silsesquioxane and hydrolyzed fluorinated alkyl silane. Angew Chem Int Ed 50:11433–11436
Wang Z, Wang Y, Liu G (2016) Rapid and efficient separation of oil from oil-in-water emulsions using a Janus cotton fabric. Angew Chem Int Ed 55:1291–1294
Wang H, Song X, Xu L, Li X, Wang J, Zhao Y, Cai Z (2018) Fabrication of acid-resistant fabrics with fluoropolymer/SiO2 nanocomposites for the application of protective clothing. J Ind Text 47:727–740
Windisch B, Vogtle F, Gestermann S, Hesse R, Schwierz H (2000) Functional dendrimers. Prog Polym Sci 25:987–1041
Xu B, Cai Z, Wang W, Ge F (2010) Preparation of superhydrophobic cotton fabrics based on SiO2 nanoparticles and ZnO nanorod arrays with subsequent hydrophobic modification. Surf Coat Technol 204:1556–1561
Yang M, Jiang C, Liu W, Liang L, Pi K (2019) A less harmful system of preparing robust fabrics for integrated self-cleaning, oil-water separation and water purification. Environ Pollut 255:1–9
Ye D, Farriol X (2005) Improving accessibility and reactivity of celluloses of annual plants for the synthesis of methylcellulose. Cellulose 12:507–515
Yoshida N, Takeuchi M, Okura T, Monma H, Wakamura M, Ohsaki H, Watanabe T (2006) Super-hydrophobic photocatalytic coatings utilizing apatite-based photocatalyst. Thin Solid Films 502(1–2):108–111
Yuan S-J, Zhang J-J, Fan H-X, Dai X-H (2018) Facile and sustainable shear mixing/carbonization approach for upcycling of carton into superhydrophobic coating for efficient oil-water separation. J Clean Prod 196:644–652
Zhou H, Wang H, Niu H, Gestos A, Lin T (2013) Robust, self-healing superamphiphobic fabrics prepared by two-step coating of fluoro-containing polymer, fluoroalkylsilane, and modified silica nanoparticles. Adv Funct Mater 23:1664–1670
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Mondal, M.I.H., Saha, J. Fabrication of C6-Fluorocarbon-dendrimer-based superhydrophobic cotton fabrics for multifunctional aspects. Cellulose 30, 639–663 (2023). https://doi.org/10.1007/s10570-022-04881-3
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DOI: https://doi.org/10.1007/s10570-022-04881-3