Abstract
Wearable devices are developed rapidly and promising to change the daily life of human beings. However, elastomer- or hydrogel-based electronics need to be stuck to the skin, which may make user feel uncomfortable. Textile electronics can be fixed on the outside of the clothes, not contacting with skin directly. Herein, we prepared a versatile polypyrrole/cotton fabric (PCF) with increasing–decreasing resistance variation during stretching because of the structure changes of the knitted yarn loops. The PCF exhibits a fast response time (110 ms), great durability (10,000 cycles), and excellent monitoring for the bending of back, finger, wrist, and knee. As pyrrole dosage rises, polypyrrole granules accumulate into bigger ones, and form membrane on cotton fibers ultimately. PCF shows a hydrophobicity with contact angle over 140° and an electrothermal temperature of 80.0 °C at 8 V, maintaining 62.8 °C at 40% strain. With dominant diffusion-controlled process, PCF performs gravimetric capacitances of 189.3 F g−1 at 5 mV s−1 and 277.8 F g−1 at 0.46 A g−1, respectively.
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Alhashmi Alamer F, Badawi NM, Alodhayb A, Okasha RM, Kattan NA (2019) Effect of dopant on the conductivity and stability of three different cotton fabrics impregnated with PEDOT:PSS. Cellulose 27(1):531–543. https://doi.org/10.1007/s10570-019-02787-1
Bonacchini GE, Omenetto FG (2021) Reconfigurable microwave metadevices based on organic electrochemical transistors. Nature Electron 4(6):424–428. https://doi.org/10.1038/s41928-021-00590-0
Chen J, Zhang J, Hu J, Luo N, Sun F, Venkatesan H et al (2021) Ultrafast-response/recovery flexible piezoresistive sensors with dna-like double helix yarns for epidermal pulse monitoring. Adv Mater 34(2):2104313. https://doi.org/10.1002/adma.202104313
Cheng B, Wu P (2021) Recycled iontronic from discarded chewed gum for personalized healthcare monitoring and intelligent information encryption. ACS Appl Mater Interfaces 13(5):6731–6738. https://doi.org/10.1021/acsami.1c00402
Ge G, Wang Q, Zhang YZ, Alshareef HN, Dong X (2021) 3D printing of hydrogels for stretchable ionotronic devices. Adv Funct Mater 31(52):2107437. https://doi.org/10.1002/adfm.202107437
Horev YD, Maity A, Zheng Y, Milyutin Y, Khatib M, Yuan M et al (2021) Stretchable and highly permeable nanofibrous sensors for detecting complex human body motion. Adv Mater 33(41):2102488. https://doi.org/10.1002/adma.202102488
Islam GMN, Ali A, Collie S (2020) Textile sensors for wearable applications: a comprehensive review. Cellulose 27(11):6103–6131. https://doi.org/10.1007/s10570-020-03215-5
Jan T, Ahmad Rizvi M, Moosvi SK, Najar MH, Husain Mir S, Peerzada GM (2021) A switching-type positive temperature coefficient behavior exhibited by PPy/(PhSe)2 nanocomposite prepared by chemical oxidative polymerization. ACS Omega 6(11):7413–7421. https://doi.org/10.1021/acsomega.0c05799
Kim KH, Nguyen TM, Ha SH, Choi EJ, Kim Y, Kim WG et al (2020) M13 bacteriophage-assisted morphological engineering of crack-based sensors for highly sensitive and wide linear range strain sensing. ACS Appl Mater Interfaces 12(40):45590–45601. https://doi.org/10.1021/acsami.0c13307
Lee YG, Lee J, An GH (2021) Surface engineering of carbon via coupled porosity tuning and heteroatom-doping for high-performance flexible fibrous supercapacitors. Adv Funct Mater 31(48):2104256. https://doi.org/10.1002/adfm.202104256
Li X, Yuan L, Liu R, He H, Hao J, Lu Y et al (2021) Engineering textile electrode and bacterial cellulose nanofiber reinforced hydrogel electrolyte to enable high-performance flexible all-solid-state supercapacitors. Adv Energy Mater 11(12):2003010. https://doi.org/10.1002/aenm.202003010
Liu Q, Qiu J, Yang C, Zang L, Zhang G, Sakai E et al (2021) Robust quasi-solid-state integrated asymmetric flexible supercapacitors with interchangeable positive and negative electrode based on all-conducting-polymer electrodes. J Alloys Compd 887:161362. https://doi.org/10.1016/j.jallcom.2021.161362
Ma J, Pu H, He P, Zhao Q, Pan S, Wang Y et al (2021) Robust cellulose-carbon nanotube conductive fibers for electrical heating and humidity sensing. Cellulose 28(12):7877–7891. https://doi.org/10.1007/s10570-021-04026-y
Mao Y, Li Y, Xie J, Liu H, Guo C, Hu W (2021) Triboelectric nanogenerator/supercapacitor in-one self-powered textile based on PTFE yarn wrapped PDMS/MnO2NW hybrid elastomer. Nano Energy 84:105918. https://doi.org/10.1016/j.nanoen.2021.105918
Naskar P, Maiti A, Chakraborty P, Kundu D, Biswas B, Banerjee A (2021) Chemical supercapacitors: a review focusing on metallic compounds and conducting polymers. J Mater Chem A 9(4):1970–2017. https://doi.org/10.1039/d0ta09655e
Park TH, Yu S, Koo M, Kim H, Kim EH, Park J-E et al (2019) Shape-adaptable 2D titanium carbide (MXene) heater. ACS Nano 13(6):6835–6844. https://doi.org/10.1021/acsnano.9b01602
Ren J, Shen M, Li Z, Yang C, Liang Y, Wang H-E et al (2021) Towards high-performance all-solid-state asymmetric supercapacitors: a hierarchical doughnut-like Ni3S2@PPy core−shell heterostructure on nickel foam electrode and density functional theory calculations. J Power Sources 501:230003. https://doi.org/10.1016/j.jpowsour.2021.230003
Sun H, Chen D, Ye C, Li X, Dai D, Yuan Q et al (2018) Large-area self-assembled reduced graphene oxide/electrochemically exfoliated graphene hybrid films for transparent electrothermal heaters. Appl Surf Sci 435:809–814. https://doi.org/10.1016/j.apsusc.2017.11.182
Tian T, Wei X, Elhassan A, Yu J, Li Z, Ding B (2021) Highly flexible, efficient, and wearable infrared radiation heating carbon fabric. Chem Eng J 417:128114. https://doi.org/10.1016/j.cej.2020.128114
Vaghasiya JV, Mayorga-Martinez CC, Pumera M (2021) Smart energy bricks: Ti3C2@polymer electrochemical energy storage inside bricks by 3D printing. Adv Funct Mater 31(48):2106990. https://doi.org/10.1002/adfm.202106990
Vannathan AA, Maity S, Kella T, Shee D, Das PP, Mal SS (2020) In situ vanadophosphomolybdate impregnated into conducting polypyrrole for supercapacitor. Electrochim Acta 364:137286. https://doi.org/10.1016/j.electacta.2020.137286
Wang B, Cheng H, Zhu J, Yuan Y, Wang C (2020) A flexible and stretchable polypyrrole/knitted cotton for electrothermal heater. Org Electron 85:105819. https://doi.org/10.1016/j.orgel.2020.105819
Wang B, Dai L, Hunter LA, Zhang L, Yang G, Chen J et al (2021a) A multifunctional nanocellulose-based hydrogel for strain sensing and self-powering applications. Carbohydr Polym 268:118210. https://doi.org/10.1016/j.carbpol.2021.118210
Wang Y, Du Z, Xiao J, Cen W, Yuan S (2021b) Polypyrrole-encapsulated Fe2O3 nanotube arrays on a carbon cloth support: achieving synergistic effect for enhanced supercapacitor performance. Electrochim Acta 386:138486. https://doi.org/10.1016/j.electacta.2021.138486
Wang B, Peng J, Yang K, Cheng H, Yin Y, Wang C (2022) Multifunctional textile electronic with sensing, energy storing, and electrothermal heating capabilities. ACS Appl Mater Interfaces 14(19):22497–22509. https://doi.org/10.1021/acsami.2c06701
Yang S, Sun L, An X, Qian X (2020) Construction of flexible electrodes based on ternary polypyrrole@cobalt oxyhydroxide/cellulose fiber composite for supercapacitor. Carbohydr Polym 229:115455. https://doi.org/10.1016/j.carbpol.2019.115455
Yang J, Cao J, Peng Y, Bissett M, Kinloch IA, Dryfe RAW (2021) Unlocking the energy storage potential of polypyrrole via electrochemical graphene oxide for high performance zinc-ion hybrid supercapacitors. J Power Sources 516:230663. https://doi.org/10.1016/j.jpowsour.2021.230663
Yue T, Douka AI, Qi K, Qiu Y, Guo X, Xia BY (2021) Flexible and hollow polypyrrole foam with high loading of metal–organic framework nanowires for wearable supercapacitors. J Mater Chem A 9(38):21799–21806. https://doi.org/10.1039/D1TA05330B
Zhang C, Tian J, Rao W, Guo B, Fan L, Xu W et al (2019) Polypyrrole@metal-organic framework (UIO-66)@cotton fabric electrodes for flexible supercapacitors. Cellulose 26(5):3387–3399. https://doi.org/10.1007/s10570-019-02321-3
Zhang L, Zhang S, Wang C, Zhou Q, Zhang H, Pan GB (2021) Highly sensitive capacitive flexible pressure sensor based on a high-permittivity MXene nanocomposite and 3D network electrode for wearable electronics. ACS Sensors 6(7):2630–2641. https://doi.org/10.1021/acssensors.1c00484
Zhao XF, Wen XH, Zhong SL, Liu MY, Liu YH, Yu XB et al (2021a) Hollow MXene sphere-based flexible e-skin for multiplex tactile detection. ACS Appl Mater Interfaces 13(38):45924–45934. https://doi.org/10.1021/acsami.1c06993
Zhao Z, Liu Q, Zang L, You H, Zhang J, Wang X et al (2021b) In situ growth of submicron polypyrrole on NiTi alloy wire as electrodes for recoverable and flexible quasi-solid-state supercapacitors. J Alloys Compd 888:161646. https://doi.org/10.1016/j.jallcom.2021.161646
Zhu T, Cheng Y, Cao C, Mao J, Li L, Huang J et al (2020) A semi-interpenetrating network ionic hydrogel for strain sensing with high sensitivity, large strain range, and stable cycle performance. Chem Eng J 385:123912. https://doi.org/10.1016/j.cej.2019.123912
Zhuang Y, Niu Q, Wu W, Yan D, Huang J, Peng S et al (2021) Enhanced supercapacitive properties of hydrohausmannite by in-situ polymerization of polypyrrole. Electrochim Acta 376:137989. https://doi.org/10.1016/j.electacta.2021.137989
Acknowledgments
This work was supported by the National Natural Science Foundation of China (21975107), Natural Science Foundation of Jiangsu Province (SBK2019020945), and China Scholarship Council (No. 202006790090).
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Conceptualization: BW; Methodology: BW; Validation: BW, JP, WH; Formal analysis: BW, JP, WH, YY, CW; Investigation: BW, JP; Data Curation: BW, CW; Writing-Original Draft: BW; Visualization: BW; Funding acquisition: BW, YY, CW; Writing-Review & Editing: YY, CW; Supervision: CW; Project administration: CW.
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Wang, B., Peng, J., Han, W. et al. Stretchable and conductive cotton-based fabric for strain sensing, electrothermal heating, and energy storing. Cellulose 29, 7989–8000 (2022). https://doi.org/10.1007/s10570-022-04736-x
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DOI: https://doi.org/10.1007/s10570-022-04736-x