Abstract
The development of eco-friendly corrosion inhibitors is a subject of several investigations, especially natural polymers. Aimed at suppressing the corrosion of L80 steel in 1 mol/L hydrochloric acid (HCl), a novel natural polymer inhibitor was developed based on xanthan gum (XG) and β-Cyclodextrin (β-CD) in this work. The corrosion inhibition effect of β-cyclodextrin modified xanthan gum (β-CD-XG) on L80 steel was evaluated by electrochemical methods, and surface analysis technology. Adsorption isotherm studies, Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS) were used to explore the corrosion inhibition mechanism of β-CD-XG on L80 steel. The results suggested that β-CD-XG was classified as a mixed-type inhibitor, and mainly suppressed the anode metal dissolution by a tight adsorption film. The formation of the film was attributed to the chemisorption of –OH, –COO-, –CH2–O–, and –CH2–O–CH2– groups on the surface of L80 steel, which conformed to the Langmuir adsorption model. The experimental results illustrated that the maximum corrosion inhibition efficiency of 94.74% was acquired at 200 mg/L β-CD-XG at 293 K.
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Acknowledgments
This work was financially supported by the National Natural Science Foundation of China (U1662106), and Open Fund (PLN201813) of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University).
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Yixuan Cao: Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Project administration, Software, Validation, Visualization, Writing—original draft, Writing—review & editing. Changjun Zou: Conceptualization, Funding acquisition, Resources, Supervision, Validation. Chengjun Wang: Data curation, Methodology, Project administration, Software. Hao Liang: Supervision, Writing—review & editing. Shuai Lin: Supervision, Writing—review & editing. Ya Liao: Supervision, Software. Lihong Shi: Supervision.
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Cao, Y., Zou, C., Wang, C. et al. β-cyclodextrin modified xanthan gum as an eco-friendly corrosion inhibitor for L80 steel in 1 M HCl. Cellulose 28, 11133–11152 (2021). https://doi.org/10.1007/s10570-021-04240-8
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DOI: https://doi.org/10.1007/s10570-021-04240-8