Abstract
Improving the printability of paper is still a relevant challenge, despite the fast development of digital communications. While it is well-known that cationic starches enhance ink density, their commercial paper-grade forms are limited to ethers with low degree of substitution. This work addresses the underexplored potential of highly substituted cationic starch for paper coating and its combination with tri-block polymers, namely Pluronics (P123 and F127), taking advantage of their supramolecular interactions with amylose chains. For that purpose, cationic starch ether and ester (starch betainate), both with a degree of substitution of 0.3, were synthesized by alkaline etherification and by transesterification, respectively. Paper without any surface treatment was subjected to one-side bar coating with suspensions encompassing those products and Pluronics, besides other common components. Black, cyan, yellow and magenta inks were printed on all coated papers through an inkjet printer. Key properties of printing quality such as the gamut area, gamut volume, optical density, print-through, inter-color bleed and circularity were measured in a controlled temperature-humidity environment. For instance, a formulation with cationic starch (ether/ester) and P123 improved the gamut area by 16–18% in comparison to native starch-coated paper sheets. Interestingly, the individual assessment of each component showed that cationic starch ether, starch betainate and P123 only improved the gamut area by 5.6%, 8.9% and 6.8%, respectively. Finally, but not less importantly, starch betainate was found to quench optical brightening agents to a lesser extent than cationic starch ethers.
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References
Alexandridis P, Holzwarthf JF, Hatton TA (1994) Micellization of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymers in aqueous solutions: thermodynamics of copolymer association. Macromolecules 27:2414–2425
Auzély-Velty R, Rinaudo M (2003) Synthesis of starch derivatives with labile cationic groups. Int J Biol Macromol 31:123–129. https://doi.org/10.1016/S0141-8130(02)00072-7
Baptista JGC, Rodrigues SPJ, Matsushita AFY, Vitorino C, Maria TMR, Burrows HD, Pais AACC, Valente AJM (2016) Does poly(vinyl alcohol) act as an amphiphilic polymer? an interaction study with simvastatin. J Mol Liq 222:287–294. https://doi.org/10.1016/j.molliq.2016.07.025
Bendoraitiene J, Lekniute-Kyzike E, Rutkaite R (2018) Biodegradation of cross-linked and cationic starches. Int J Biol Macromol 119:345–351. https://doi.org/10.1016/j.ijbiomac.2018.07.155
Bollström R, Tobjörk D, Dolietis P, Salminen P, Preston J, Österbacka R, Toivakka M (2013) Printability of functional inks on multilayer curtain coated paper. Chem Eng Process 68:13–20. https://doi.org/10.1016/j.cep.2012.07.007
Gao J, Luo Z, Fu X, Luo F, Peng Z (2012) Effect of enzymatic pretreatment on the synthesis and properties of phosphorylated amphoteric starch. Carbohydr Polym 88:917–925. https://doi.org/10.1016/j.carbpol.2012.01.034
Gigac J, Stankovská M, Opálená E, Pažitný A (2016a) The effect of pigments and binders on inkjet print quality. Wood Res 61:215–226
Gigac J, Stankovska M, Pazitny A (2016b) Influence of the coating formulations and base papers on inkjet printability. Wood Res 61:915–926
Granö H, Yli-Kauhaluoma J, Suortti T, Käki J, Nurmi K (2000) Preparation of starch betainate: a novel cationic starch derivative. Carbohydr Polym 41:277–283
Haack V, Heinze T, Oelmeyer G, Kulicke WM (2002) Starch derivatives of high degree of functionalization, synthesis and flocculation behavior of cationic starch polyelectrolytes. Macromol Mater Eng 287:495–502
He Z, Alexandridis P (2018) Micellization thermodynamics of Pluronic P123 (EO20PO70EO20) amphiphilic block copolymer in aqueous ethylammonium nitrate (EAN) solutions. Polymers 10:32. https://doi.org/10.3390/polym10010032
Hebeish A, Higazy A, El-Shafei A, Sharaf S (2010) Synthesis of carboxymethyl cellulose (CMC) and starch-based hybrids and their applications in flocculation and sizing. Carbohydr Polym 79:60–69. https://doi.org/10.1016/j.carbpol.2009.07.022
Hu G, Fu S, Chu F, Lin M (2017) Relationship between paper whiteness and color reproduction in inkjet printing. BioResources 12:4854–4866. https://doi.org/10.15376/biores.12.3.4854-4866
Huber KC, BeMiller JN (2001) Location of sites of reaction within starch granules. Cereal Chem 78:173–180. https://doi.org/10.1094/CCHEM.2001.78.2.173
Kasmani JE, Mahdavi S, Alizadeh A, Nemati M, Samariha A (2013) Physical properties and printability characteristics of mechanical printing paper with LWC. BioResources 8:3646–3656. https://doi.org/10.15376/biores.8.3.3646-3656
Lamminmäki TT, Kettle JP, Gane PAC (2011) Absorption and adsorption of dye-based inkjet inks by coating layer components and the implications for print quality. Colloid Surf A 380:79–88. https://doi.org/10.1016/j.colsurfa.2011.02.015
Lee HL, Shin JY, Koh CH, Ryu H, Lee DJ, Sohn C (2002) Surface sizing with cationic starch: its effect on paper quality and the papermaking process. Tappi J 1:34–40
Liu X, Wu D, Turgman-Cohen S, Genzer J, Theyson TW, Rojas OJ (2010) Adsorption of a nonionic symmetric triblock copolymer on surfaces with different hydrophobicity. Langmuir 26:9565–9574. https://doi.org/10.1021/la100156a
Liu X, Vesterinen AH, Genzer J, Seppälä JV, Rojas OJ (2011) Adsorption of PEO-PPO-PEO triblock copolymers with end-capped cationic chains of poly(2-dimethylaminoethyl methacrylate). Langmuir 27:9769–9780. https://doi.org/10.1021/la201596x
Lourenço AF, Gamelas JAF, Sarmento P, Ferreira PJT (2020) Cellulose micro and nanofibrils as coating agent for improved printability in office papers. Cellulose 27(10):6001–6010. https://doi.org/10.1007/s10570-020-03184-9
Mujawar LH, Van Amerongen A, Norde W (2015) Influence of Pluronic F127 on the distribution and functionality of inkjet-printed biomolecules in porous nitrocellulose substrates. Talanta 131:541–547. https://doi.org/10.1016/j.talanta.2014.08.001
Niegelhell K, Chemelli A, Hobisch J, Griesser T, Reiter H, Hirn U, Spirk S (2018) Interaction of industrially relevant cationic starches with cellulose. Carbohydr Polym 179:290–296. https://doi.org/10.1016/j.carbpol.2017.10.003
Petkova-Olsson Y, Ullsten H, Järnström L (2016) Thermosensitive silica-pluronic-starch model coating dispersion-part I: the effect of Pluronic block copolymer adsorption on the colloidal stability and rheology. Colloid Surf A 506:245–253. https://doi.org/10.1016/j.colsurfa.2016.06.032
Petkova-Olsson Y, Altun S, Ullsten H, Järnström L (2017) Temperature effect on the complex formation between Pluronic F127 and starch. Carbohydr Polym 166:264–270. https://doi.org/10.1016/j.carbpol.2017.02.012
Sharma M, Aguado R, Murtinho D, Valente AJM, de Sousa APM, Ferreira PJT (2020) A review on cationic starch and nanocellulose as paper coating components. Int J Biol Macromol 162:578–598. https://doi.org/10.1016/j.ijbiomac.2020.06.131
Sharma M, Aguado R, Murtinho D, Valente AJM, Ferreira PJT (2021) Novel approach on the synthesis of starch betainate by transesterification. Int J Biol Macromol 182:1681–1689. https://doi.org/10.1016/j.ijbiomac.2021.05.175
Shi H, Liu H, Ni Y, Yuan Z, Zou X, Zhou Y (2012) Review: Use of optical brightening agents (OBAs) in the production of paper containing high-yield pulps. BioResources 7:2582–2591. https://doi.org/10.15376/biores.7.2.2582-2591
Sousa S, Mendes de Sousa A, Reis B, Ramos A (2014) Influence of binders on inkjet print quality. Mater Sci 20:55–60. https://doi.org/10.5755/j01.ms.20.1.1998
Stankovská M, Gigac J, Letko M, Opálená E (2014) The effect of surface sizing on paper wettability and on properties of inkjet prints. Wood Res 59:67–76
Thapa RK, Cazzador F, Grønlien KG, Tønnesen HH (2020) Effect of curcumin and cosolvents on the micellization of Pluronic F127 in aqueous solution. Colloid Surf B 195:111250. https://doi.org/10.1016/j.colsurfb.2020.111250
Wang S, Cheng Q (2009) A novel process to isolate fibrils from cellulose fibers by high-intensity ultrasonication, Part 1: process optimization. J Appl Polym Sci 113:1270–1275
Funding
This work was carried out under the Project inpactus -innovative products and technologies from eucalyptus, Project N.º 21874 funded by Portugal 2020 through European Regional Development Fund (ERDF) in the frame of COMPETE 2020 nº246/AXIS II/2017. Authors would like to thank the Coimbra Chemical Centre, which is supported by the Fundação para a Ciência e a Tecnologia (FCT), through the projects UID/QUI/00313/2020 and COMPETE. Authors would also like to thank the CIEPQPF—Strategic Research Centre Project UIDB/00102/2020, funded by the Fundação para a Ciência e Tecnologia (FCT). M.S. acknowledges the PhD grant BDE 03|POCI-01-0247-FEDER-021874. R.A. acknowledges the post-doc grant BPD 02|POCI-01-0247-FEDER-021874.
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Sharma, M., Aguado, R., Murtinho, D. et al. Synergetic effect of cationic starch (ether/ester) and Pluronics for improving inkjet printing quality of office papers. Cellulose 28, 10609–10624 (2021). https://doi.org/10.1007/s10570-021-04206-w
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DOI: https://doi.org/10.1007/s10570-021-04206-w