Abstract
Near-neutral bleaching of cotton fabrics at low temperature is of great importance for saving energy and ecological friendliness in textile industry. In this work, glycerol triacetate (GT) was investigated as an activator of hydrogen peroxide (H2O2) for low temperature bleaching of cotton knitted fabrics, and satisfactory whiteness was obtained. The bleaching properties of H2O2/GT system for cotton was assessed by the CIE whiteness index (WI), H2O2 decomposition rate, concentration of generated peracetic acid and bursting strength. Possible factors affecting the properties of cotton bleached by H2O2/GT bleaching system were discussed in detail. At 60 °C, adding only 10 mmol/L GT to the hydrogen peroxide solution (60 mmol/L) to bleach cotton knitted fabrics for 60 min, the WI was significantly increased from 52.09 to 68.92. By using benzenepentacarboxylic acid as a fluorescent probe for hydroxyl radical (HO·) detection, it was found that GT could clearly promote HO· generation and its concentration closely related to the WI of cotton fabric. Furthermore, the bleaching mechanism of H2O2/GT system was proposed by exploring the relationship between WI and HO· concentration. GT as a bleach activator has more economical benefits and better water solubility than tetraacetylethylenediamine. The H2O2/GT system may provide a cost-effective and environmentally friendly bleaching approach of cotton as alternative to conventional alkaline high-temperature bleaching.
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References
Abdel-Halim ES, Al-Deyab SS (2013) One-step bleaching process for cotton fabrics using activated hydrogen peroxide. Carbohydr Polym 92(2):1844–1849. https://doi.org/10.1016/j.carbpol.2012.11.045
Bashar MM, Siddiquee MAB, Khan MA (2015) Preparation of cotton knitted fabric by gamma radiation: a new approach. Carbohydr Polym 120:92–101. https://doi.org/10.1016/j.carbpol.2014.11.023
Bianchetti GO, Devlin CL, Seddon KR (2015) Bleaching systems in domestic laundry detergents: a review. RSC Adv 5(80):65365–65384. https://doi.org/10.1039/c5ra05328e
Cai JY, Evans DJ, Smith SM (2001) Bleaching of with TAED and NOBS activated peroxide systems. AATCC Rev 1(12):31–34
Chen W, Wang L, Wang D, Zhang J, Sun C, Xu C (2016) Recognizing a limitation of the TBLC-activated peroxide system on low-temperature cotton bleaching. Carbohydr Polym 140:1–5. https://doi.org/10.1016/j.carbpol.2015.12.013
Fei X, Yao J, Du J, Sun C, Xiang Z, Xu C (2015) Analysis of factors affecting the performance of activated peroxide systems on bleaching of cotton fabric. Cellulose 22(2):1379–1388. https://doi.org/10.1007/s10570-015-0550-1
Hashem M, El-Bisi M, Sharaf S, Refaie R (2010) Pre-cationization of cotton fabrics: an effective alternative tool for activation of hydrogen peroxide bleaching process. Carbohydr Polym 79(3):533–540. https://doi.org/10.1016/j.carbpol.2009.08.038
Hebeish A, Hashem M, Shaker N, Ramadan M, El-Sadek B, Hady MA (2009) New development for combined bioscouring and bleaching of cotton-based fabrics. Carbohydr Polym 78(4):961–972. https://doi.org/10.1016/j.carbpol.2009.07.019
Hofmann JR, Just G, Pritzkow W, Schmidt H (1992) Bleaching activators and the mechanism of bleaching activation. J Prak Chem Chem Ztg 334(4):293–297. https://doi.org/10.1002/prac.19923340402
Lee JJ, Hinks D, Lim SH, Hauser P (2010) Hydrolytic stability of a series of lactam-based cationic bleach activators and their impact on cellulose peroxide bleaching. Cellulose 17(3):671–678. https://doi.org/10.1007/s10570-009-9390-1
Li Q, Ni L, Wang J, Quan H, Zhou Y (2020) Establishing an ultrasound-assisted activated peroxide system for efficient and sustainable scouring-bleaching of cotton/spandex fabric. Ultrason Sonochem 68C:105220. https://doi.org/10.1016/j.ultsonch.2020.105220
Lim SH, Lee JJ, Hinks D, Hauser P (2006) Bleaching of cotton with activated peroxide systems. Coloration Technol 121(2):89–95. https://doi.org/10.1111/j.1478-4408.2005.tb00258.x
Liu K, Zhang X, Yan K (2017) Low-temperature bleaching of cotton knitting fabric with H2O2/PAG system. Cellulose 24(3):1555–1561. https://doi.org/10.1007/s10570-016-1167-8
Liu K, Zhang X, Yan K (2018) Bleaching of cotton fabric with tetraacetylhydrazine as bleach activator for H2O2. Carbohydr Polym 188:221–227. https://doi.org/10.1016/j.carbpol.2018.01.111
Long X, Xu C, Du J, Fu S (2013) The TAED/H2O2/NaHCO3 system as an approach to low-temperature and near-neutral pH bleaching of cotton. Carbohydr Polym 95(1):107–113. https://doi.org/10.1016/j.carbpol.2013.02.061
Luo X, Shao D, Xu C, Wang Q, Gao W (2019) An eco-friendly way to whiten yellowish anti-wrinkle cotton fabrics using TBCC-activated peroxide low-temperature post-bleaching. Cellulose 26(5):3575–3588. https://doi.org/10.1007/s10570-019-02316-0
Neal JM( (1998) Oxygen bleaching systems in domestic laundry. J Surfactants Deterg 1(2):253–261. https://doi.org/10.1007/s11743-998-0029-z
Shao J, Huang Y, Wang Z, Liu J (2010) Cold pad–batch bleaching of cotton fabrics with a TAED/H2O2 activating system. Color Technol 126(2):103–108. https://doi.org/10.1111/j.1478-4408.2010.00234.x
Si F, Yan K, Zhang X (2014a) Study on H2O2/TAED and H2O2/TBCC bleaching mechanism related to hydroxyl radical with a fluorescent probe. Carbohydr Polym 103:581–586. https://doi.org/10.1016/j.carbpol.2013.12.052
Si F, Zhang X, Yan K (2014b) The quantitative detection of HO center dot generated in a high temperature H2O2 bleaching system with a novel fluorescent probe benzenepentacarboxylic acid. RSC Adv 4(12):5860–5866. https://doi.org/10.1039/c3ra45975f
Sun D, Stylios GK (2004) Effect of low temperature plasma treatment on the scouring and dyeing of natural fabrics. Text Res J 74(9):751–756. https://doi.org/10.1177/004051750407400901
Wakelyn PJ, Bertoniere NR, French AD, Thibodeaux DP, Triplett BA, Rousselle MA, Goynes WR, Edwards JV, Hunter L, Mcalister DD (2007) Chemical composition of cotton. In: Cotton fiber chemistry and technology. p 15. https://doi.org/10.1201/9781420045888
Xu C, Long X, Du J, Fu S (2013) A critical reinvestigation of the TAED-activated peroxide system for low-temperature bleaching of cotton. Carbohydr Polym 92(1):249–253. https://doi.org/10.1016/j.carbpol.2012.08.088
Xu C, Hinks D, Sun C, Wei Q (2015) Establishment of an activated peroxide system for low-temperature cotton bleaching using N-4-(triethylammoniomethyl)benzoyl butyrolactam chloride. Carbohydr Polym 119:71–77. https://doi.org/10.1016/j.carbpol.2014.11.054
Zeronian SH, Inglesby MK (1995) Bleaching of cellulose by hydrogen peroxide. Cellulose 2(4):265–272. https://doi.org/10.1007/BF00811817
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This work was financially supported by the National Key R&D Program of China (2017YFB0309200), Fundamental Research Funds for the Central Universities (JUSRP51717A) and International Joint Research Laboratory for Eco- textile Technology at Jiangnan University.
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Zhou, Y., Zheng, G., Zhang, J. et al. An eco-friendly approach to low-temperature and near-neutral bleaching of cotton knitted fabrics using glycerol triacetate as an activator. Cellulose 28, 8129–8138 (2021). https://doi.org/10.1007/s10570-021-04030-2
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DOI: https://doi.org/10.1007/s10570-021-04030-2