Abstract
Ag/fluorine-containing polyacrylate latex was successfully synthesized via Pickering emulsion polymerization using Ag/poly(2-dimethylaminoethyl methacrylate-co-hexafluorobutyl acrylate) (Ag/P(DMAEMA-co-HFBA)) hybrid micelles as particle emulsifiers. The influences of introducing the Ag nanoparticles (NPs) component and the concentration of Ag/P(DMAEMA-co-HFBA) hybrid micelles on emulsion polymerization and finished cotton fabric properties were studied. The results showed that the Ag/fluorine-containing polyacrylate latex had a higher conversion, smaller particle size than the fluorine-containing polyacrylate latex using P(DMAEMA-co-HFBA) micelles as emulsifiers, indicating the positive effect of Ag NPs on emulsion polymerization. And thermogravimetric analysis (TGA) proved that Ag NPs improved the thermal stability of the latex film. Moreover, the surface of the cotton fabric finished by Ag/fluorine-containing polyacrylate latex showed more rough morphology, better hydrophobicity and excellent antibacterial activity owing to the synergistic effect of the cationic fluorine-containing polyacrylate compounds and Ag nanoparticles. Meanwhile, the presence of Ag NPs also improved the tensile strength of the finished cotton fabric, but reduced slightly the whiteness. When the concentration of Ag/P(DMAEMA-co-HFBA) hybrid micelle emulsifier was 8 mg/mL, the Ag/fluorine-containing polyacrylate latex particles presented regular raspberry-shaped with an average diameter of 120 nm, and the water/oil contact angles of finished cotton fabric attained 145° and 90°, respectively. In addition, the finished cotton fabric exhibited excellent antibacterial properties against both S. aureus and E. coli as the concentration of Ag/P(DMAEMA-co-HFBA) hybrid micelles was 12 mg/mL. The mechanism for the formation of Ag/fluorine-containing polyacrylate latex was proposed.
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Bagratashvili VN, Rybaltovsky AO, Minaev NV, Timashev PS, Firsov VV, Yusupov VI (2010) Laser-induced atomic assembling of periodic layered nanostructures of silver nanoparticles in fluoro-polymer film matrix. Laser Phys Lett 7:401–404
Brandelli A, Ritter AC, Veras FF (2017) Antimicrobial activities of metal nanoparticles. Metal Nanoparticles in Pharma pp 337–363
Cai P, Bai N, Xu L, Tan C, Li Q (2015) Fabrication of superhydrophobic wood surface with enhanced environmental adaptability through a solution-immersion process. Surf Coat Tech 277:262–269
Campoy-Quiles M, Ferenczi T, Agostinelli T, Etchegoin PG, Kim Y, Anthopoulos TD, Stavrinou PN, Bradley DDC, Nelson J (2008) Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends. Nat Mater 7:158–164
Elshaarawy RFM, Seif GA, El-Naggar ME, Mostafa TB, El-Sawi EA (2019) In-situ and ex-situ synthesis of poly-(imidazolium vanillyl)-grafted chitosan/silver nanobiocomposites for safe antibacterial finishing of cotton fabrics. Eur Polym J 116:210–221
Fakhri A, Tahami S, Naji M (2017) Synthesis and characterization of core-shell bimetallic nanoparticles for synergistic antimicrobial effect studies in combination with doxycycline on burn specific pathogens. J Photoch Photobio B 169:21–26
Gao S, Nakane K, Ohgoshi A, Isaji T, Ozawa M (2017) Development of superamphiphobic alumina nanofiber mats using trimethoxysilane with a short perfluoroalkyl chain. Text Res J 88:1803–1811
Gul DS, Ogutcu H, Hayvali Z (2020) Investigation of photophysical behaviours and antimicrobial activity of novel benzo-15-crown-5 substituted coumarin and chromone derivatives. J Mol Struct 1204:127569. https://doi.org/10.1016/j.molstruc.2019
Huang X, Zhou F, Yang T, Yin S, Tang C, Yang X (2019) Fabrication and characterization of Pickering High Internal Phase Emulsions (HIPEs) stabilized by chitosan-caseinophosphopeptides nanocomplexes as oral delivery vehicles. Food Hydrocolloid 93:34–45
Iafisco M, Palazzo B, Ito T, Otsuka M, Senna M, Delgado-Lopez JM, Gomez-Morales J, Tampieri A, Prat M, Rimondini L (2012) Preparation of core-shell poly(L-lactic) acid-nanocrystalline apatite hollow microspheres for bone repairing applications. J Mater Sci-Mater M 23:2659–2669
Jiao W (2016) Facile synthesis of silver nanoparticles deposited on a calcium silicate hydrate composite as an efficient bactericidal agent. Rsc Adv 6:112931–112938
Kang E-k, Jung GY, Jung SH, Lee BM (2018) Synthesis and surface active properties of novel anionic surfactants with two short fluoroalkyl groups. J Ind Eng Chem 61:216–226
Lei L, Zhang Q, Shi S, Zhu SP (2016) High internal phase emulsion with double emulsion morphology and their templated porous polymer systems. J Colloid Interf Sci 483:232–240
Li J, Cheng Y, Lee H, Wang C, Chiu C, Suen M (2020) Synthesis and properties of castor oil-based polyurethane containing short fluorinated segment. J Appl Polym Sci. https://doi.org/10.1002/app.49062
Li S, Huang J, Ge M, Li S, Xing T, Chen G, Liu Y, Zhang K, Al-Deyab SS, Lai YK (2015) Controlled grafting superhydrophobic cellulose surface with environmentally-friendly short fluoroalkyl chains by ATRP. Mater Design 85:815–822
Lin H, Wang Y, Gan Y, Hou H, Yin J, Jiang X (2015) Simultaneous formation of a self-wrinkled surface and silver nanoparticles on a functional photocuring coating. Langmuir 31:11800–11808
Mi L, Jiang S (2012) Synchronizing nonfouling and antimicrobial properties in a zwitterionic hydrogel. Biomaterials 33:8928–8933
Morse AJ, Armes SP, Thompson KL, Dupin D, Fielding LA, Mills P, Swart R (2013) Novel Pickering emulsifiers based on pH-responsive poly(2-(diethylamino) ethyl methacrylate) latexes. Langmuir 29:5466–5475
Namen F, Galan J, de Oliveira JF, Cabreira RD, Silva FCE, Souz AB, de Deus G (2008) Surface properties of dental polymers: measurements of contact angles, roughness and fluoride release. Mater Res-Ibero-Am J 11:239–243
Nasab NK, Sabouri Z, Ghazal S, Darroudi M (2020) Green-based synthesis of mixed-phase silver nanoparticles as an effective photocatalyst and investigation of their antibacterial properties. J Mol Struct. https://doi.org/10.1016/j.molstruc.2019.127411
Nowak W, Podsiadlo H (2017) Wettability of the imprinted biodegradable film surface. Przem Chem 96:2272–2274
Rybaltovskii AO, Gerasimova VI, Minaev NV, Sokolov VI, Timashev PS, Troitskaya EA, Firsov VV, Yusupov VI, Bagratashvili VN (2010) Laser-induced formation of structures of silver nanoparticles in fluoracrylate films impregnated with Ag(hfac)COD molecules. Nanotechnol Russ 1203:435–445
Sadeghi-Kiakhani M, Tehrani-Bagha AR, Gharanjig K, Hashemi E (2019) Use of pomegranate peels and walnut green husks as the green antimicrobial agents to reduce the consumption of inorganic nanoparticles on wool yarns. J Clean Prod 231:1463–1473
Verplanck N, Coffinier Y, Thomy V, Boukherroub R (2007) Wettability switching techniques on superhydrophobic surfaces. Nanoscale Res Lett 2:577–596
Xu B, Feng C, Lv Y, Lin S, Lu G, Huang X (2020) Biomimetic asymmetric polymer brush coatings bearing fencelike conformation exhibit superior protection and antifouling performance. ACS Appl Mater Inter 12:1588–1596
Xu W, An Q, Hao L, Huang L (2012) Synthesis, film morphology, and performance of cationic fluorinated polyacrylate emulsion with core-shell structure. J Appl Polym Sci 125:2376–2383
Ye H, Zhu L, Li W, Jiang G, Liu H, Chen H (2017) Anchoring CeO2 nanoparticles on monodispersed SiO2 spheres to construct hydrophobic polymer coating with enhanced UV absorption ability. Chem Eng J 321:268–276
Zhang B, Zhang Z, Kapar S, Ataeian P, Bernardes JD, Berry R, Zhao W, Zhou GF, Tam KC (2019) Microencapsulation of phase change materials with polystyrene/cellulose nanocrystal hybrid shell via Pickering emulsion polymerization. ACS Sustain Chem Eng 7:17756–17767
Zhang K, Wu W, Meng H, Guo K, Chen JF (2009) Pickering emulsion polymerization: Preparation of polystyrene/nano-SiO2 composite microspheres with core-shell structure. Powder Technol 190:393–400
Zhou J, Chen X, Duan H, Ma J (2017a) Fluorosilicone modified polyacrylate emulsifier-free latex: Synthesis, properties, and application in fabric finishing. Fiber Polym 18:625–632
Zhou J, Chen X, Ma J (2017b) Synthesis of cationic fluorinated polyacrylate copolymer by RAFT emulsifier-free emulsion polymerization and its application as waterborne textile finishing agent. Dyes Pigments 139:102–109
Zhou J, Yao H, He R (2018) Synthesis of fluorinated polyacrylate surfactant-free core-shell latex by RAFT-mediated polymerization-induced self-assembly: Effects of the concentration of hexafluorobutyl acrylate. Adv Polym Tech 37:3804–3812
Zhou J, Li Y, Li H, Yao H (2019) Cellulose nanocrystals/fluorinated polyacrylate soap-free emulsion prepared via RAFT-assisted Pickering emulsion polymerization. Colloid Surface B 177:321–328
Zhou J, Zha X (2019) Synthesis and Pickering emulsifier performance of Ag/poly((2-dimethylamino)ethyl methacrylate) -co-poly(hexafluorobutyl acrylate) amphiphilic random copolymer hybrid micelles. React Funct Polym 137:46–56
Zhou J, Chen X, Ma J (2016) Cationic fluorinated polyacrylate emulsifier-free emulsion mediated by poly(2-(dimethylamino) ethyl methacrylate)-b-poly (hexafluorobutyl acrylate) trithiocarbonate via ab initio RAFT emulsion polymerization. Prog Org Coat 100:86–93
Zou S, Liu H, Yang Y, Wei Z, Wang C (2013) Multihollow nanocomposite microspheres with tunable pore structures by templating Pickering double emulsions. React Funct Polym 73:1231–1241
Acknowledgments
This work was supported by Science and Technology Plan of Xi’an City (No. 2019216514GXRC001CG002- GXYD1.3), National Natural Science Foundation of China (Nos. 21978162 and 21206088), National Demonstration Center for Experimental Light Chemistry Engineering Education Open Project (No. 2018QGSJ02-15), and Key Research and Development Project in Shaanxi Province of China (No. 2019ZDLNY01-05-02).
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Zhou, J., Wang, L., Zha, X. et al. Synthesis of Ag/fluorine-containing polyacrylate latex stabilized by Ag nanoparticle hybrid amphiphilic random copolymer micelles via Pickering emulsion polymerization and its application on fabric finishing. Cellulose 27, 9123–9134 (2020). https://doi.org/10.1007/s10570-020-03403-3
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DOI: https://doi.org/10.1007/s10570-020-03403-3