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Bio-inspired cotton fabric with superhydrophobicity for high-efficiency self-cleaning and oil/water separation

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Abstract

In this paper, a facile and efficient approach to robust and durable superhydrophobic cotton fabric was presented via in situ CuO deposition and stearic acid (STA) coating. The combined effects of both rough structure and low surface energy endowed cotton fabric (Cot) with superhydrophobicity, water repellency, and self-cleaning property. Moreover, the as-prepared fabric (Cot–CuO–STA) could keep its robust superhydrophobicity under harsh environmental conditions of acidic, alkaline and salt solutions, high temperature, mechanical abrasion and washing. Importantly, the obtained Cot–CuO–STA with WCA of 156.5° had great potential in oil/water separation with high separation efficiency of up to 98.7% for various oils (dichloromethane, trichloromethane, soybean oil, and n-heptane). Further, fascinating permeate flux (more than 1800 L.m−2.h−1) and remarkable recyclability made Cot–CuO–STA a promising application in oil-contaminated water treatment and marine spilt oil cleanup.

Graphic abstract

Robust and durable superhydrophobic cotton fabric was fabricated for oil/water separation via a facile and efficient route. The resultant fabric exhibited remarkable separation efficiency for different kinds of oils, fascinating permeate flux, and excellent recyclability.

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References

  • Cai J, Wang T, Hao W, Ling H, Hang T, Chung YW, Li M (2019) Fabrication of superamphiphobic Cu surfaces using hierarchical surface morphology and fluorocarbon attachment facilitated by plasma activation. Appl Surf Sci 464:140–145

    CAS  Google Scholar 

  • Chen S, Li X, Li Y, Sun J (2015) Intumescent flame-retardant and self-healing superhydrophobic coatings on cotton fabric. ACS Nano 9(4):4070–4076

    CAS  PubMed  Google Scholar 

  • Chen Y, Meng J, Zhu Z, Zhang F, Wang L, Gu Z, Jiang L, Wang S (2018) Controlled growth of patterned conducting polymer microsuckers on superhydrophobic micropillar-structured templates. Adv Funct Mater 28:1800240

    Google Scholar 

  • Cheng Y, Zhu T, Li S, Huang J, Mao J, Yang H, Gao S, Chen Z, Lai Y (2019) A novel strategy for fabricating robust superhydrophobic fabrics by environmentally-friendly enzyme etching. Chem Eng J 355:290–298

    CAS  Google Scholar 

  • Dong XL, Gao SW, Huang JY, Li SH, Zhu TX, Cheng Y, Zhao Y, Chen Z, Lai YK (2019) A self-roughened and biodegradable superhydrophobic coating with UV shielding, solar induced self-healing and versatile oil-water separation ability. J Mater Chem A 7:2122–2128

    CAS  Google Scholar 

  • El-Nahhal IM, Elmanama AA, Amara N, Qodih FS, Selmane M, Chehimi MM (2018) The efficacy of surfactants in stabilizing coating of nano-structured CuO particles onto the surface of cotton fibers and their antimicrobial activity. Mater Chem Phys 215:221–228

    CAS  Google Scholar 

  • Ethiraj AS, Kang DJ (2012) Synthesis and characterization of CuO nanowires by a simple wet chemical method. Nanoscale Res Lett 7(1):70

    PubMed  PubMed Central  Google Scholar 

  • Farhadi S, Farzaneh M, Kulinich SA (2011) Anti-icing performance of superhydrophobic surfaces. Appl Surf Sci 257(14):6264–6269

    CAS  Google Scholar 

  • Fisher MC, Hawkins NJ, Sanglard D, Gurr SJ (2018) Worldwide emergence of resistance to antifungal drugs challenges human health and food security. Science 360:739–742

    CAS  PubMed  Google Scholar 

  • Foorginezhad S, Zerafat MM (2019) Fabrication of superhydrophobic coatings with self-cleaning properties on cotton fabric based on octa vinyl polyhedral oligomeric silsesquioxane/polydimethylsiloxane (OV-POSS/PDMS) nanocomposite. J Colloid Interface Sci 540:78–87

    CAS  PubMed  Google Scholar 

  • Gao SW, Dong XL, Huang JY, Li SH, Li YW, Chen Z, Lai YK (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation. Chem Eng J 333:621–629

    CAS  Google Scholar 

  • Ge MZ, Cao CY, Liang FH, Liu R, Zhang Y, Zhang W, Zhu TX, Yi B, Tang YX, Lai YK (2020) A ‘‘PDMS-in-water’’ emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature. Nanoscale Horiz 5:65–73

    CAS  Google Scholar 

  • Gelebart AH, Mulder DJ, Varga M, Konya A, Vantomme G, Meijer EW, Selinger RLB, Broer DJ (2017) Making waves in a photoactive polymer film. Nature 546:632

    CAS  PubMed  PubMed Central  Google Scholar 

  • Hou K, Zeng Y, Zhou C, Chen J, Wen X, Xu S, Cheng J, Pi P (2018) Facile generation of robust POSS-based superhydrophobic fabrics via thiol-ene click chemistry. Chem Eng J 332:150–159

    CAS  Google Scholar 

  • Jia S, Chen H, Luo S, Qing Y, Deng S, Yan N, Wu Y (2018) One-step approach to prepare superhydrophobic wood with enhanced mechanical and chemical durability: driving of alkali. Appl Surf Sci 455:115–122

    CAS  Google Scholar 

  • Kliche G, Popovic ZV (1990) Far-infrared spectroscopic investigations on CuO. Phys Rev B 42(16):10060

    CAS  Google Scholar 

  • Kong L, Chen X, Yu L, Wu Z, Zhang P (2015) Superhydrophobic cuprous oxide nanostructures on phosphor-copper meshes and their oil–water separation and oil spill cleanup. ACS Appl Mater Inter 7(4):2616–2625

    CAS  Google Scholar 

  • Li Q, Guo Z (2019) Lubricant-infused slippery surfaces: Facile fabrication, unique liquid repellence and antireflective properties. J Colloid Interface Sci 536:507–515

    CAS  PubMed  Google Scholar 

  • Lin D, Zeng X, Li H, Lai X, Wu T (2019) One-pot fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via sol-gel reaction. J Colloid Interface Sci 533:198–206

    CAS  PubMed  Google Scholar 

  • Liu G, Wang W, Yu D (2019a) Robust and self-healing superhydrophobic cotton fabric via UV induced click chemistry for oil/water separation. Cellulose 26(5):3529–3541

    CAS  Google Scholar 

  • Liu R, Dai J, Ma L, Chen J, Shi X, Du Y, Li Z, Deng H (2019b) Low-temperature plasma treatment-assisted layer-by-layer self-assembly for the modification of nanofibrous mats. J Colloid Interface Sci 540:535–543

    CAS  PubMed  Google Scholar 

  • Liu Y, Fu K, Liu J, Tian Y, Zhang H, Wang R, Zhang B, Zhang H, Zhou F, Zhang Q (2019c) Design and preparation of a multi-fluorination organic superhydrophobic coating with high mechanical robustness and icing delay ability. Appl Surf Sci 497:143663

    CAS  Google Scholar 

  • Liu Y, Moevius L, Xu X, Qian T, Yeomans JM, Wang Z (2014) Pancake bouncing on superhydrophobic surfaces. Nat Phys 10:515

    CAS  PubMed  PubMed Central  Google Scholar 

  • Liu Z, Lin Z, Zhou L, Yang Z, Chen D, Zhang C (2018) High-performance planar perovskite solar cells using low temperature, solution–combustion-based ickel oxide hole transporting layer with efficiency exceeding 20%. Adv Energy Mater 8:1703432

    Google Scholar 

  • Lu X, Wang C, Wei Y (2009) One-dimensional composite nanomaterials: synthesis by electrospinning and their applications. Small 5(21):2349–2370

    CAS  PubMed  Google Scholar 

  • Lvov Y, Wang W, Zhang L, Fakhrullin R (2016) Halloysite clay nanotubes for loading and sustained release of functional compounds. Adv Mater 28:1227–1250

    CAS  PubMed  Google Scholar 

  • Nanda D, Sahoo A, Kumar A, Bhushan B (2019) Facile approach to develop durable and reusable superhydrophobic/superoleophilic coatings for steel mesh surfaces. J Colloid Interface Sci 535:50–57

    CAS  PubMed  Google Scholar 

  • Peng C, Chen Z, Tiwari MK (2018) All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance. Nat Mater 17:355

    CAS  PubMed  Google Scholar 

  • Perelshtein I, Applerot G, Perkas N, Wehrschuetz-Sigl E, Hasmann A, Guebitz G, Gedanken A (2009) CuO–cotton nanocomposite: formation, morphology, and antibacterial activity. Surf Coat Tech 204(1–2):54–57

    CAS  Google Scholar 

  • Pokroy B, Kang S, Mahadevan L, Aizenberg J (2009) Self-organization of a mesoscale bristle into ordered, hierarchical helical assemblies. Science 323:237–240

    CAS  PubMed  Google Scholar 

  • Qing Y, Long C, An K, Hu C, Liu C (2019) Sandpaper as template for a robust superhydrophobic surface with self-cleaning and anti-snow/icing performances. J Colloid Interface Sci 548:224–232

    CAS  PubMed  Google Scholar 

  • Ren T, Yang M, Wang K, Zhang Y, He J (2018) CuO nanoparticles-containing highly transparent and superhydrophobic coatings with extremely low bacterial adhesion and excellent bactericidal property. ACS Appl Mater Inter 10(30):25717–25725

    CAS  Google Scholar 

  • Rezaie AB, Montazer M, Rad MM (2018) Environmentally friendly low cost approach for nano copper oxide functionalization of cotton designed for antibacterial and photocatalytic applications. J Clean Prod 204:425–436

    Google Scholar 

  • Riaz S, Ashraf M, Hussain T, Hussain MT, Younus A (2019) Fabrication of robust multifaceted textiles by application of functionalized TiO2 nanoparticles. Colloid Surface A 581:123799

    CAS  Google Scholar 

  • Tang S, Zhang Y, Sana H, Hu J (2019) Hydrophobic surface contained Ca and/or Ce myristate fabricated on AZ31 by one-step electrodeposition for corrosion protection in NaCl. Appl Surf Sci 496:143627

    CAS  Google Scholar 

  • Wang B, Liang W, Guo Z, Liu W (2015) Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chem Soc Rev 44:336–361

    PubMed  Google Scholar 

  • Xue C, Fan Q, Guo X, An Q, Jia S (2019) Fabrication of superhydrophobic cotton fabrics by grafting of POSS-based polymers on fibers. Appl Surf Sci 465:241–248

    CAS  Google Scholar 

  • Yan B, Zhou Q, Zhu X, Guo J, Mia MS, Yan X, Chen G, Xing T (2019) A superhydrophobic bionic coating on silk fabric with flame retardancy and UV shielding ability. Appl Surf Sci 483:929–939

    CAS  Google Scholar 

  • Yang M, Liu W, Jiang C, Xie Y, Shi H, Zhang F, Wang Z (2019) Facile construction of robust superhydrophobic cotton textiles for effective UV protection, self-cleaning and oil-water separation. Colloid Surface A 570:172–181

    CAS  Google Scholar 

  • Yang M, Liu W, Liang L, Jiang C, Liu C, Xie Y, Shi H, Zhang F, Pi K (2020) A mild strategy to construct superhydrophobic cotton with dual self-cleaning and oil–water separation abilities based on TiO2 and POSS via thiol-ene click reaction. Cellulose pp 1–11

  • Yang Y, Li X, Zheng X, Chen Z, Zhou Q, Chen Y (2018) 3D-printed biomimetic super-hydrophobic structure for microdroplet manipulation and oil/water separation. Adv Mater 309:1704912

    Google Scholar 

  • Zhang J, Seeger S (2011) Polyester materials with superwetting silicone nanofilaments for oil/water separation and selective oil absorption. Adv Funct Mater 21:4699–4704

    CAS  Google Scholar 

  • Zhang S, Liu H, Yang S, Yang S, Shi X, Zhang D, Shan C, Mi L, Liu C, Shen C, Guo Z (2019a) Ultrasensitive and highly compressible piezoresistive sensor based on polyurethane sponge coated with a cracked cellulose nanofibril/silver nanowire layer. ACS Appl Mater Inter 11:10922–10932

    CAS  Google Scholar 

  • Zhang X, Liu Z, Li Y, Wang C, Zhu Y, Wang H, Wang J (2019b) Robust superhydrophobic epoxy composite coating prepared by dual interfacial enhancement. Chem Eng J 371:276–285

    CAS  Google Scholar 

  • Zhao Y, Xing C, Zhang Z, Yu L (2017) Superhydrophobic polyaniline/polystyrene micro/nanostructures as anticorrosion coatings. React Funct Polym 119:95–104

    CAS  Google Scholar 

  • Zhou C, Chen Z, Yang H, Hou K, Zeng X, Zheng Y, Cheng J (2017a) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl Mater Inter 9(10):9184–9194

    CAS  Google Scholar 

  • Zhou H, Wang H, Niu H, Zhao Y, Xu Z, Lin T (2017b) A waterborne coating system for preparing robust, self-healing, superamphiphobic surfaces. Adv Funct Mater 27(14):1604261

    Google Scholar 

  • Zhu Z, Liu Y, Hou H, Shi W, Qu F, Cui F, Wang W (2018) Dual-bioinspired design for constructing membranes with superhydrophobicity for direct contact membrane distillation. Environ Sci Technol 52:3027–3036

    CAS  PubMed  Google Scholar 

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Acknowledgments

The work was financially supported by the Public Technology Research Plan of Zhejiang Province (LGF18E030003) and the Fundamental Research Funds of Zhejiang Sci-Tech University (2019Q008).

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Correspondence to Lin Liu.

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Lu, R., Yu, Y., Adkhamjon, G. et al. Bio-inspired cotton fabric with superhydrophobicity for high-efficiency self-cleaning and oil/water separation. Cellulose 27, 7283–7296 (2020). https://doi.org/10.1007/s10570-020-03281-9

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