Abstract
Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), an antioxidant widely applied in the plastic industry, was used to assist thermal reduction of graphene oxide (GO) on a cotton fabric in air. l-ascorbic acid was also applied for comparison. GO was deposited on the fabric by the padding method. Reduction of GO deposited on fiber surfaces at 180 and 220 °C in air imparted electrical conductivity. For all the materials the conductivity worsened after the reduction during cooling and during the first hours of storage at room conditions. However, the most stable effect of GO reduction was achieved using pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), which assisted the reduction of GO at both 180 and 220 °C, and allowed to obtain the cotton fabric with a stable surface resistivity of 6.6 and 3.7 MΩ/sq, respectively. Moreover, superhydrophobicity of the conductive fabric was achieved by modification with methyltrichlorosilane in an anhydrous environment.
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Acik M, Lee G, Mattevi C, Pirkle A, Wallace RM, Chhowalla M, Cho K, Chabal Y (2011) The role of oxygen during thermal reduction of graphene oxide studied by infrared absorption spectroscopy. J Phys Chem C 115:19761–19781. https://doi.org/10.1021/jp2052618
Attia NF, El Ebissy AA, Hassan MA (2015) Novel synthesis and characterization of conductive and flame retardant textile fabrics. Polym Adv Technol 26:1551–1557. https://doi.org/10.1002/pat.3580
Bussy C, Jasim D, Lozano N, Terry D, Kostarelos K (2015) The current graphene safety landscape—a literature mining exercise. Nanoscale 7:6432–6435. https://doi.org/10.1039/c5nr00236b
Chua CK, Pumera M (2014) Chemical reduction of graphene oxide: a synthetic chemistry viewpoint. Chem Soc Rev 43:291–312. https://doi.org/10.1039/c3cs60303b
De Silva KKH, Huang H-H, Yoshimura M (2018) Progress of reduction of graphene oxide by ascorbic acid. Appl Surf Sci 447:338–346. https://doi.org/10.1016/j.apsusc.2018.03.243
Fernandez-Merino MJ, Guardia L, Paredes JI, Villar-Rodil S, Solis-Fernandez P, Martinez-Alonso A, Tascon JMD (2010) Vitamin C Is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions. J Phys Chem C 114:6426–6432. https://doi.org/10.1021/jp100603h
Huang Y, Zhu MS, Pei ZX, Xue Q, Huang Y, Zhi CY (2016) A shape memory supercapacitor and its application in smart energy storage textiles. J Mater Chem A 4:1290–1297. https://doi.org/10.1039/c5ta09473a
Huang Y, Gao L, Zhao YN, Guo XH, Liu CX, Liu P (2017) Highly flexible fabric strain sensor based on graphene nanoplatelet-polyaniline nanocomposites for human gesture recognition. J Appl Polym Sci 134:8. https://doi.org/10.1002/app.45340
Huh SH (2011) Thermal reduction of graphene oxide. In: Mikhailov S (ed) Physics and applications of graphene—experiments. InTech, London, pp 73–90
Jost K, Perez CR, McDonough JK, Presser V, Heon M, Dion G, Gogotsi Y (2011) Carbon coated textiles for flexible energy storage. Energy Environ Sci 4:5060–5067. https://doi.org/10.1039/c1ee02421c
Juhász M, Kitahara Y, Takahashi S, Fujii T (2012) Thermal stability of vitamin C: thermogravimetric analysis and use of total ion monitoring chromatograms. J Pharm Biomed Anal 59:190–193. https://doi.org/10.1016/j.jpba.2011.10.011
Kiuru M, Alakoski E (2004) Low sliding angles in hydrophobic and oleophobic coatings prepared with plasma discharge method. Mater Lett 58:2213–2216. https://doi.org/10.1016/j.matlet.2004.01.024
Makowski T, Kowalczyk D, Fortuniak W, Jeziorska D, Brzezinski S, Tracz A (2014) Superhydrophobic properties of cotton woven fabrics with conducting 3D networks of multiwall carbon nanotubes, MWCNTs. Cellulose 21:4659–4670. https://doi.org/10.1007/s10570-014-0422-0
Marcato B, Guerra S, Vianello M, Scalia S (2003) Migration of antioxidant additives from various polyolefinic plastics into oleaginous vehicles. Int J Pharm 257:217–225. https://doi.org/10.1016/S0378-5173(03)00143-1
Nooralian Z, Gashti MP, Ebrahimi I (2016) Fabrication of a multifunctional graphene/polyvinylphosphonic acid/cotton nanocomposite via facile spray layer-by-layer assembly. RSC Adv 6:23288–23299. https://doi.org/10.1039/c6ra00296j
Onghena M, Van Hoeck E, Van Loco J, Ibanez M, Cherta L, Portoles T, Pitarch E, Hernandez F, Lemiere F, Covaci A (2015) Identification of substances migrating from plastic baby bottles using a combination of low-resolution and high-resolution mass spectrometric analysers coupled to gas and liquid chromatography. J Mass Spectrom 50:1234–1244. https://doi.org/10.1002/jms.3644
Pei SF, Cheng HM (2012) The reduction of graphene oxide. Carbon 50:3210–3228. https://doi.org/10.1016/j.carbon.2011.11.010
Pelin M, Fusco L, Leon V, Martin C, Criado A, Sosa S, Vazquez E, Tubaro A, Prato M (2017) Differential cytotoxic effects of graphene and graphene oxide on skin keratinocytes. Sci Rep. https://doi.org/10.1038/srep40572
Poletto M, Pistor V, Zattera AJ (2013) Structural characteristics and thermal properties of native cellulose. In: Van De Ven TGM (ed) Cellulose—fundamental aspects. InTech, London, pp 45–68
Rani M, Shim WJ, Han GM, Jang M, Song YK, Hong SH (2017) Benzotriazole-type ultraviolet stabilizers and antioxidants in plastic marine debris and their new products. Sci Total Environ 579:745–754. https://doi.org/10.1016/j.scitotenv.2016.11.033
Ren JS, Wang CX, Zhang X, Carey T, Chen KL, Yin YJ, Torrisi F (2017) Environmentally-friendly conductive cotton fabric as flexible strain sensor based on hot press reduced graphene oxide. Carbon 111:622–630. https://doi.org/10.1016/j.carbon.2016.10.045
Sahito IA, Sun KC, Arbab AA, Qadir MB, Jeong SH (2015) Graphene coated cotton fabric as textile structured counter electrode for DSSC. Electrochim Acta 173:164–171. https://doi.org/10.1016/j.electacta.2015.05.035
Sahito IA, Sun KC, Arbab AA, Qadir MB, Choi YS, Jeong SH (2016) Flexible and conductive cotton fabric counter electrode coated with graphene nanosheets for high efficiency dye sensitized solar cell. J Power Sources 319:90–98. https://doi.org/10.1016/j.jpowsour.2016.04.025
Shateri-Khalilabad M, Yazdanshenas ME (2013a) Fabricating electroconductive cotton textiles using graphene. Carbohyd Polym 96:190–195. https://doi.org/10.1016/j.carbpol.2013.03.052
Shateri-Khalilabad M, Yazdanshenas ME (2013b) Preparation of superhydrophobic electroconductive graphene-coated cotton cellulose. Cellulose 20:963–972. https://doi.org/10.1007/s10570-013-9873-y
Stalder AF, Kulik G, Sage D, Barbieri L, Hoffmann P (2006) A snake-based approach to accurate determination of both contact points and contact angles. Colloids Surf A Physicochem Eng Asp 286:92–103. https://doi.org/10.1016/j.colsurfa.2006.03.008
Stalder AF, Melchior T, Muller M, Sage D, Blu T, Unser M (2010) Low-bond axisymmetric drop shape analysis for surface tension and contact angle measurements of sessile drops. Colloids Surf A Physicochem Eng Asp 364:72–81. https://doi.org/10.1016/j.colsurfa.2010.04.040
Tegou E, Pseiropoulos G, Filippidou MK, Chatzandroulis S (2016) Low-temperature thermal reduction of graphene oxide films in ambient atmosphere: infra-red spectroscopic studies and gas sensing applications. Microelectron Eng 159:146–150. https://doi.org/10.1016/j.mee.2016.03.030
Tissera ND, Wijesena RN, Perera JR, de Silva KMN, Amaratunge GAJ (2015) Hydrophobic cotton textile surfaces using an amphiphilic graphene oxide (GO) coating. Appl Surf Sci 324:455–463. https://doi.org/10.1016/j.apsusc.2014.10.148
Xu P, Wei BQ, Cao ZY, Zheng J, Gong K, Li FX, Yu JY, Li QW, Lu WB, Byun JH, Kim BS, Yan YS, Chou TW (2015) stretchable wire-shaped asymmetric supercapacitors based on pristine and MnO2 coated carbon nanotube fibers. ACS Nano 9:6088–6096. https://doi.org/10.1021/acsnano.5b01244
Zhang J, Zhang F, Yang H, Huang X, Liu H, Zhang J, Guo S (2010a) Graphene oxide as a matrix for enzyme immobilization. Langmuir 26:6083–6085. https://doi.org/10.1021/la904014z
Zhang JL, Yang HJ, Shen GX, Cheng P, Zhang JY, Guo SW (2010b) Reduction of graphene oxide via l-ascorbic acid. Chem Commun 46:1112–1114. https://doi.org/10.1039/b917705a
Zhang XQ, Huang XX, Zhang XD, Zhong B, Xia L, Liu J, Pan H, Wen GW (2016) A facile method to prepare graphene-coat cotton and its application for lithium battery. J Solid State Electrochem 20:1251–1261. https://doi.org/10.1007/s10008-016-3118-6
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The authors would like to thank for the financial support of this work from the National Science Centre Poland (UMO-2014/15/B/ST8/04286).
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Makowski, T., Svyntkivska, M., Piorkowska, E. et al. Conductive and superhydrophobic cotton fabric through pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate) assisted thermal reduction of graphene oxide and modification with methyltrichlorosilane. Cellulose 25, 5377–5388 (2018). https://doi.org/10.1007/s10570-018-1926-9
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DOI: https://doi.org/10.1007/s10570-018-1926-9