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Cellulose

, Volume 25, Issue 2, pp 915–923 | Cite as

Fabrication of iron oxide nanoparticles, and green catalytic application of an immobilized novel iron Schiff on wood cellulose

Original Paper

Abstract

In this work, a fabrication route for generating organic–inorganic polymer hybrid materials has been discussed. Natural cellulose was extracted from Sesbania sesban to design a biodegradable microcomposite. A novel iron Schiff base using 2-hydroxy-1-naphthaldehyde as a ligand was immobilized on cellulose along with amin functionality (FeSAC). The structure, morphology and thermal stability of FeSAC were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDAX), FT-IR, Inductively coupled plasma, thermo gravimetric analysis, and elemental analysis. The synthesized catalyst was successfully applied as a green heterogeneous catalyst in the oxidation reaction under a solvent free media and hydrogen peroxide, providing a promising green system for industrial applications. High yield products and selectivities were observed. The longevity of the micro-catalyst was studied and it was found to be reusable for at least six runs. Finally, α-Fe2O3 was obtained by direct calcinations of this biocatalyst at 650 °C within 3 h. α-Fe2O3 nanoparticles were characterized by SEM, high-resolution transmission electron microscopy, and X-ray powder diffraction.

Keywords

Wood Schiff base Oxidation reactions Iron oxide nanoparticle 

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceUniversity of JiroftJiroftIran
  2. 2.Department of ChemistryKerman Payame Noor UniversityKermanIran
  3. 3.Department of ChemistryPayame Noor University (PNU)TehranIran

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