Skip to main content

Advertisement

Log in

Tunable shaped N-doped CuO nanoparticles on cotton fabric through processing conditions: synthesis, antibacterial behavior and mechanical properties

  • Original Paper
  • Published:
Cellulose Aims and scope Submit manuscript

Abstract

N-doped copper oxide nanoparticles with different sizes and shapes were chemically synthesized on bleached cotton fabric. Various analysis methods including XRD, EDX, SEM, FTIR and UV-Vis were used to determine the presence, structure, shape, size and morphology of the nanoparticles. The effect of temperature, pH and processing time was studied to optimize the conditions for producing small nanoparticles with narrow size distribution and low agglomeration. Wheat-like and spherical shaped N-doped copper oxide nanoparticles were in situ synthesized on cotton fiber with different loadings. The treated cotton fabrics indicated higher hydrophobicity, tenacity, tensile stress and elongation. Further, the treated cotton fabrics showed considerable antibacterial properties against a gram-positive S. aureus and a gram-negative E. coli bacteria. The release of nanoparticles in the washing bath was measured by atomic absorption confirmed the reasonable durability and safety of the treated fabrics. Overall, the cotton fabrics treated with CuO nanoparticles have potential application in electronics as well as medical and technical textiles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

Explore related subjects

Discover the latest articles, news and stories from top researchers in related subjects.

References

  • Allahyarzadeh V, Montazer M, Hemmatinejad N, Samadi N (2013) In situ synthesis of nano silver on polyester using NaOH/Nano TiO2. J Appl Polym Sci 129:892–900

    Article  CAS  Google Scholar 

  • Anyaogu KC, Fedorov AV, Neckers DC (2008) Synthesis, characterization, and antifouling potential of functionalized copper nanoparticles. Langmuir 24:4340–4346

    Article  CAS  Google Scholar 

  • Applerot G, Lellouche J, Lipovsky A, Nitzan Y, Lubart R, Gedanken A, Banin E (2012) Understanding the antibacterial mechanism of CuO nanoparticles: revealing the route of induced oxidative stress. Small 8:3326–3337

    Article  CAS  Google Scholar 

  • Ashraf S, Saif-ur-Rehman Sher F, Khalid ZM, Mehmood M, Hussain I (2014) Synthesis of cellulose–metal nanoparticle composites: development and comparison of different protocols. Cellulose 21:395–405

    Article  CAS  Google Scholar 

  • Bang JH, Suslick KS (2010) Applications of ultrasound to the synthesis of nanostructured materials. Adv Mater 22:1039–1059

    Article  CAS  Google Scholar 

  • Behzadnia A, Montazer M, Rashidi A, Mahmoudi-Rad M (2014) Rapid Sonosynthesis of N-doped nano TiO2 on wool fabric at low temperature: introducing self-cleaning, hydrophilicity, antibacterial/antifungal properties with low alkali solubility, yellowness and cytotoxicity. Photochem Photobiol 90:1224–1233

    Article  CAS  Google Scholar 

  • Cady NC, Behnke JL, Strickland AD (2011) Copper-based nanostructured coatings on natural cellulose: nanocomposites exhibiting rapid and efficient inhibition of a multi-drug resistant wound pathogen, A. baumannii, and mammalian cell biocompatibility in vitro. Adv Funct Mater 21:2506–2514

    Article  CAS  Google Scholar 

  • Cao G (2004) Nanostructures and nanomaterials: synthesis. Imperial College Press, London, Properties and Applications

    Book  Google Scholar 

  • Carnes CL, Stipp J, Klabunde KJ (2002) Synthesis, characterization, and adsorption studies of nanocrystalline copper oxide and nickel oxide. Langmuir 18:1352–1359

    Article  CAS  Google Scholar 

  • Coates J (2000) Interpretation of infrared spectra, a practical approach. In: Meyers RA (ed) Encyclopedia of analytical chemistry. Wiley, Chichester, pp 10815–10837

    Google Scholar 

  • El-Nahhal IM, Zourab SM, Kodeh FS, Semane M, Genois I, Babonneau F (2012) Nano-structured copper oxide-cotton fibers: synthesis, characterization and applications. Int Nano Lett 2:62–67

    CAS  Google Scholar 

  • Etefagh R, Azhir E, Shahtahmasebi N (2013) Synthesis of CuO nanoparticles and fabrication of nanostructural layer biosensors for detecting Aspergillus niger fungi. Sci Iran F 20:1055–1058

    CAS  Google Scholar 

  • Gabbay J, Mishal J, Magen E, Zatcoff R, Shemer-Avni Y, Borkow G (2006) Copper oxide impregnated textiles with potent biocidal activities. J Ind Text 35:323–335

    Article  CAS  Google Scholar 

  • Garnovskii AD, Kharissov BI (2003) Synthetic coordination and organometallic chemistry. CRC Press, New York

    Book  Google Scholar 

  • Giordanino F, Borfecchia E, Lomachenko KA, Lazzarini A, Agostini G, Gallo E, Soldatov AV, Beato P, Bordiga S, Lamberti C (2014) Interaction of NH3 with Cu-SSZ-13 catalyst: a complementary FTIR, XANES, and XES Study. J Phys Chem Lett 5:1552–1559

    Article  CAS  Google Scholar 

  • Hans M, Erbe A, Mathews S, Chen Y, Solioz M, Mucklich F (2013) Role of copper oxides in contact killing of bacteria. Langmuir 29:16160–16166

    Article  CAS  Google Scholar 

  • Harifi T, Montazer M (2014) Photo-, bio-, and magneto-active colored polyester fabric with hydrophobic/hydrophilic and enhanced mechanical properties through synthesis of TiO2/Fe3O4/Ag nanocomposite. Ind Eng Chem Res 53:1119–1129

    Article  CAS  Google Scholar 

  • Hassan IA, Parkin IP, Nair SP, Carmalt CJ (2014) Antimicrobial activity of copper and copper (I) oxide thin films deposited via aerosol-assisted CVD. J Mater Chem B 2:2855–2860

    Article  CAS  Google Scholar 

  • Helios K, Wysokiński R, Pietraszko A, Michalska D (2011) Vibrational spectra and reinvestigation of the crystal structure of a polymeric copper(II)–orotate complex, [Cu(μ-HOr)(H2O)2]n: the performance of new DFT methods, M06 and M05-2X, in theoretical studies. Vib Spectrosc 55:207–215

    Article  CAS  Google Scholar 

  • Hun JJ, Jae WC, Sang HL, Seok WH (2012) Acute toxicity of Ag and CuO nanoparticle suspensions against Daphnia magna: the importance of their dissolved fraction varying with preparation methods. J Hazard Mater 301:227–228

    Google Scholar 

  • Jia B, Mei Y, Cheng L, Zhou J, Zhang L (2012) Preparation of copper nanoparticles coated cellulose films with antibacterial properties through one-step reduction. ACS Appl Mater Interfaces 4:2897–2902

    Article  CAS  Google Scholar 

  • Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Comprehensive Cellulose Chemistry (Vol 2). Wiley-VCH Verlag, Weinheim, Functionalization of Cellulose

    Book  Google Scholar 

  • Kosmulski M (2009) pH-dependent surface charging and points of zero charge. IV. Update and new approach. J Colloid Interface Sci 337:439–448

    Article  CAS  Google Scholar 

  • Kotelnikova N, Vainio U, Pirkkalainen K, Serimaa R (2007) Novel approaches to metallization of cellulose by reduction of cellulose-incorporated copper and nickel ions. Macromol Symp 254:74–79

    Article  CAS  Google Scholar 

  • Lam YL, Kan CW, Yuen CWM (2012) Developments in functional finishing of cotton fibres: wrinkle-resistant, flame-retardant and antimicrobial treatments. Text Prog 44:175–249

    Article  Google Scholar 

  • Mageshwari K, Sathyamoorthy R (2013) Organic free synthesis of flower-like hierarchical CuO microspheres by reflux condensation approach. Appl Nanosci 3:161–166

    Article  CAS  Google Scholar 

  • Montazer M, Maali-Amiri M (2014) ZnO nano reactor on textiles and polymers: ex situ and in situ synthesis, application, and characterization. J Phys Chem B 118:1453–1470

    Article  CAS  Google Scholar 

  • Oskam G (2006) Metal oxide nanoparticles: synthesis, characterization and application. J Sol–Gel Sci Technol 37:161–164

    Article  CAS  Google Scholar 

  • Perelshtein I, Ruderman Y, Perkas N, Beddow J, Singh G, Vinatoru M, Joyce E, Mason JT, Blanes M, Molla K, Gedanken A (2013) The sonochemical coating of cotton withstands 65 washing cycles at hospital washing standards and retains its antibacterial properties. Cellulose 20:1215–1221

    Article  CAS  Google Scholar 

  • Perreault F, Oukarroum A, Melegari SP, Matias WG, Popovic R (2012) Polymer coating of copper oxide nanoparticles increases nanoparticles uptake and toxicity in the green alga Chlamydomonas reinhardtii. Chemosphere 87:1388–1394

    Article  CAS  Google Scholar 

  • Poortavasoly H, Montazer M, Harifi T (2014) Simultaneous synthesis of nano silver and activation of polyester producing higher tensile strength aminohydroxylated fiber with antibacterial and hydrophilic properties. RSC Adv 4:46250–46256

    Article  CAS  Google Scholar 

  • Rubilar O, Rai M, Tortella G, Diez MC, Seabra AB, Durán N (2013) Biogenic nanoparticles: copper, copper oxides, copper sulphides, complex copper nanostructures and their applications. Biotechnol Lett 35:1365–1375

    Article  CAS  Google Scholar 

  • Sarkar S, Guibal E, Quignard F, SenGupta AK (2012) Polymer-supported metals and metal oxide nanoparticles: synthesis, characterization, and applications. J Nanopart Res 14:715–738

    Article  Google Scholar 

  • Sedighi A, Montazer M, Hemmatinejad N (2014a) Copper nanoparticles on bleached cotton fabric: in situ synthesis and characterization. Cellulose 21:2119–2132

    Article  CAS  Google Scholar 

  • Sedighi A, Montazer M, Samadi N (2014b) Synthesis of nano Cu2O on cotton: morphological, physical, biologicaland optical sensing characterizations. Carbohydr Polym 110:489–498

    Article  CAS  Google Scholar 

  • Shahidi S, Aslan N, Ghoranneviss M, Korachi M (2014) Effect of thymol on the antibacterial efficiency of plasma-treated cotton fabric. Cellulose 21:1933–1943

    Article  CAS  Google Scholar 

  • Subramanian B, Priya KA, Rajan ST, Dhandapani P, Jayachandran M (2014) Antimicrobial activity of sputtered nanocrystalline CuO impregnated fabrics. Mater Lett 128:1–4

    Article  CAS  Google Scholar 

  • Torres A, Ruales C, Pulgarin C, Aimable A, Bowen P, Sarria V, Kiwi J (2010) Innovative high-surface-area cuo pretreated cotton effective in bacterial inactivation under visible light. ACS Appl Mater Interfaces 2:2547–2552

    Article  CAS  Google Scholar 

  • Vaseem M, Umar A, Hahn YB (2008) Low-temperature growth and properties of CuO structures prepared by aqueous solution process. J Nanosci Nanotechnol 8:5511–5515

    Article  CAS  Google Scholar 

  • Zhang G, Liu Y, Morikawa H, Chen Y (2013) Application of ZnO nanoparticles to enhance the antimicrobial activity and ultraviolet protective property of bamboo pulp fabric. Cellulose 20:1877–1884

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Majid Montazer.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sedighi, A., Montazer, M. Tunable shaped N-doped CuO nanoparticles on cotton fabric through processing conditions: synthesis, antibacterial behavior and mechanical properties. Cellulose 23, 2229–2243 (2016). https://doi.org/10.1007/s10570-016-0892-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10570-016-0892-3

Keywords

Navigation