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Cellulose nanofibrils—adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive

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In this paper cellulose nanofibrils were used together with a cationic polylelectrolyte, poly(amideamine) epichlorohydrin (PAE), to enhance the wet and the dry strength of paper. The adsorption of nanofibrils and PAE on cellulose model surfaces was studied using quartz crystal microbalance with dissipation (QCM-D) and atomic force microscopy (AFM). The differences in fibril and polyelectrolyte adding strategies onto cellulose fibres were studied by comparing layer-structures and nano-aggregates formed by the nanofibrils and PAE. The results showed that when PAE was first adsorbed on the model fibre surface a uniform and viscous layer of nanofibrils could be adsorbed. When PAE and nanofibrils were adsorbed as cationic aggregates a non-uniform and more rigid layer was adsorbed. Paper sheets were prepared using both the bi-layer and nano-aggregate adding strategy of the nanofibrils and PAE. When PAE and nanofibrils were adsorbed on pulp fibres as a bi-layer system significant increase in both wet and dry tensile strength of paper could be achieved even at low added amounts of PAE. When the substances were added as nano-aggregates the improvements in paper strength properties were not as significant. Bulk and surface nitrogen content analyses of the paper samples showed that the adding strategy does not affect the total adsorbed amount of PAE but it has a strong effect on distribution of substances in the paper matrix which has a crucial effect on paper wet and dry strength development.

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References

  • Andresen M, Johansson L-S, Steinar B et al (2006) Properties and characterization of hydrophobized microfibrillated cellulose. Cellulose 13:665–677

    Article  CAS  Google Scholar 

  • Berglund L (2005) Cellulose-based nanocomposites. In: Mohanty A, Misra M, Drzal L (eds) Natural fibers, biopolymers and biocomposites. CRC Press, Boca Raton

    Google Scholar 

  • Espy H (1995) The mechanism of wet-strength development in paper: a review. Tappi J 78:90–99

    CAS  Google Scholar 

  • Fält S, Wågberg L, Vesterlind E-L (2003) Swelling of model films of cellulose having different charge densities and comparison to the swelling behavior of corresponding fibers. Langmuir 19:7895–7903

    Article  Google Scholar 

  • Gernandt R, Wågberg L, Gärdlund L et al (2003) Polyelectrolyte complexes for surface modification of wood fibres I. Preparation and characterization of complexes for dry and wet strength improvement of paper. Coll Surf A 213:15–25

    Article  CAS  Google Scholar 

  • Gärdlund L, Wågberg L, Gernandt R (2003) Polyelectrolyte complexes for surface modification of wood fibres II. Influence of complexes on wet and dry strength of paper. Coll Surf A 218:137–149

    Article  Google Scholar 

  • Herrick F, Casebier R, Hamilton J et al (1983) Microfibrillated cellulose: morphology and accessibility. J Appl Polym Sci: Appl Polym Symp 37:797–813

    CAS  Google Scholar 

  • Heux L, Dinand E, Vignon M (1999) Structural aspects in ultrathin cellulose microfibrils followed by 13C CP-MAS NMR. Carbohydr Polym 40:115–124

    Article  CAS  Google Scholar 

  • Höök F, Rodahl M, Brzezinski P et al (1998) Energy dissipation kinetics for protein and antibody-antigen adsorption under shear oscillation on a quartz crystal microbalance. Langmuir 14:729–734

    Article  Google Scholar 

  • Jeong C, Maciel A, Pawlak J et al (2005) Following cellulose activity by the quartz crystal microbalance technique. In: Proceedings of the 13th ISWFPC Symposium, Auckland, 2005, pp 495–502

  • Kontturi E, Tammelin T, Österberg M (2006) Cellulose-model films and the fundamental approach. Chem Soc Rev 35:1287–1304

    Article  CAS  Google Scholar 

  • Laine J, Lindström T, Glad Nordmark G et al (2002) Studies on topochemical modification of cellulosic fibres. Part 3. The effect of Carboxymethyl cellulose attachment on wet-strength development by alkaline-curing polyamide-amine epichlorohydrin resins. Nord Pulp Pap Res J 17:57–60

    Article  CAS  Google Scholar 

  • Lindström T, Wågberg L, Larsson T (2005) On the nature of joint strength in paper- a review of dry and wet strength resins used in paper manufacturing. Adv Pap Sci Tech 13th Fund Res Symp 1:457–562

    Google Scholar 

  • Lowys M-P, Desbrieres J, Rinaudo M (2001) Rheological characterization of cellulosic microfibril suspensions. Role of polymeric additives. Food Hydrocolloids 15:25–32

    Article  CAS  Google Scholar 

  • Maximova N, Österberg M, Koljonen K et al (2001) Lignin adsorption on cellulose fibre surfaces: effect on surface chemistry, surface morphology and paper strength. Cellulose 8:113–125

    Article  CAS  Google Scholar 

  • Nakagaito A, Iwamoto S, Yano H (2005) Bacterial cellulose: the ultimate nano-scalar cellulose morphology for the production of high-strength composites. Appl Phys A 80:93–97

    Article  CAS  Google Scholar 

  • Paananen A, Österberg M, Rutland M et al (2004), Interaction between cellulose and xylan: an atomic force microscope and quartz crystal microbalance study. In: Gatenholm P, Tenkanen M (eds) 864 Hemicelluloses: Science and Technology, American Chemical Society. ACS Symp. Ser., Washington, pp 269–290

    Google Scholar 

  • Pääkkö M, Ankerfors M, Kosonen H et al (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8(6):1934–1941

    Article  Google Scholar 

  • Rodahl M, Höök F, Krozer A et al (1995) Quartz crystal microbalance setup for frequency and Q-factor measurements in gaseous and liquid environments. Rev Sci Instrum 66:3924–3930

    Article  CAS  Google Scholar 

  • Saito T, Nishiyama Y, Putaux J-L et al (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7(6):1687–1691

    Article  CAS  Google Scholar 

  • Salmi J, Saarinen T, Laine J et al (2003) The effect of cationic polyelectrolytes on surface forces and structure of cellulose-polyelectrolyte interface. In: Proceedings of the 5th International Paper and Coating Chemistry Symposium, Montreal, pp 157–160

  • Sauerbrey G (1959) Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung. Zeitschrift für Physik 155:206–222

    Article  CAS  Google Scholar 

  • Schaub M, Wenz G, Wegner G et al (1993) Ultrathin films of cellulose silicon wafers. Adv Mater 5:919–922

    Article  CAS  Google Scholar 

  • Tammelin T, Saarinen T, Österberg M et al (2006) Preparation of Langmuir/Blodgett-cellulose surfaces by using horizontal dipping procedure. Application for polyelectrolyte adsorption studies performed with QCM-D. Cellulose 13:519–535

    Article  CAS  Google Scholar 

  • Tammelin T, Johnsen I, Österberg M et al (2007) Adsorption of colloidal extractives and dissolved hemicellulose on thermomechanical pulp fiber components studied by QCM-D. Nord Pulp Pap Res J 22:93–101

    Article  CAS  Google Scholar 

  • Tatsumi D, Ishioka S, Matsumoto T (2002) Effect of fiber concentration and axial ratio on the rheological properties of cellulose fiber suspensions. J Soc Rheol Japan 30:27–32

    Article  CAS  Google Scholar 

  • Turbak A, Snyder F, Sandberg K (1983) Microfibrillated cellulose, a new cellulose product: properties, uses, and commercial potential. J Appl Polym Sci: Appl Polym Symp 37:815–827

    CAS  Google Scholar 

  • Wågberg L, Björklund M (1993) On the mechanism behind wet strength development in papers containing wet strength resins. Nord Pulp Pap Res J 1:53–58

    Article  Google Scholar 

  • Wågberg L, Decher G, Norgren M et al (2007) The build-up of polyelectrolyte multilayers of microfibrillated cellulose (MFC) and cationic polyelectrolytes. Langmuir, submitted

Download references

Acknowledgments

This work has been performed as a part of “Nanostructured cellulose products”-project in the Finnish-Swedish Wood Material Science Research Program. Prof. Tom Lindström and M.Sc. Mikael Ankerfors at STFI-Packforsk are acknowledged for providing the nanofibril samples. Dr. Leena-Sisko Johansson is greatly acknowledged for performing the XPS analysis and helping in the analyzing process. Mrs. Gunborg Glad Nordmark at STFI-Packforsk is acknowledged for performing the bulk nitrogen analysis. The experimental assistance of Mrs Marja Kärkkäinen and Mrs Aila Rahkola is gratefully acknowledged.

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Ahola, S., Österberg, M. & Laine, J. Cellulose nanofibrils—adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive. Cellulose 15, 303–314 (2008). https://doi.org/10.1007/s10570-007-9167-3

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