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Novel cellulose fibre reinforced thermoplastic materials

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Abstract

Spun cellulose fibres from the viscose, lyocell and carbamate processes have been used to reinforce thermoplastic commodity polymers, such as polypropylene (PP), polyethylene (PE) and (high impact) polystyrene (HIPS) as well as poly(lactic acid) (PLA) and a thermoplastic elastomer (TPE) for injection moulding applications. A specially developed double pultrusion technique has been employed for compounding. Fibres were analysed in single fibre tensile tests. Strength, stiffness, impact strength, and heat distortion temperature (HDT) were determined for injection-moulded standard test specimen and structural features were revealed by scanning electron microscopy. A strong reinforcing effect was observed in all cases. In particular, high tenacity tyre cord rayon gives excellent composite strength and impact strength, often doubling or tripling the pristine matrix values. In the case of PP, Lyocell type fibres provide enhanced stiffness and HDT, and thus the combination of both fibre types leads to a balanced composite property profile. The PE case is very similar to PP. For HIPS mainly strength and stiffness is increased, while for TPE the property profile is changed completely. With PLA, a biogenic and biodegradable composite with excellent mechanical properties is presented.

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References

  • Amash A., Zugenmaier P. (1998) Study on cellulose and xylan-filled polypropylene composites. Polym. Bull. 40:251–258

    Article  CAS  Google Scholar 

  • Amash A., Zugenmaier P. (2000) Morphology and properties of isotropic and oriented samples of cellulose fibre–polypropylene composites. Polymer 41:1589–1596

    Article  CAS  Google Scholar 

  • Bader M.G., Hill A.R. (1993) Short Fiber Composites. In: Chou T.-W. (eds) Material Science and Technology – A comprehensive treatment. Vol 13: Structure and Properties of Composites. VCH, Weinheim, pp 291–338

    Google Scholar 

  • Bledzki A.K., Gassan J.(1999) Composites reinforced with cellulose based fibres. Prog. Polym. Sci. 24:221–274

    Article  CAS  Google Scholar 

  • Felix J.M., Gatenholm P. (1991) The nature of adhesion in composites of modified cellulose fibres and polypropylene. J. Appl. Polym. Sci. 42:609–620

    Article  CAS  Google Scholar 

  • Fink H.-P., Weigel P., Geiger O., Busch M. (2004) Neue Commodity-Verbundmaterialien unter Verwendung von Celluloseregeneratfasern. Technische Textilien 47:126–130

    Google Scholar 

  • Ganster J., Fink H.-P. and Pinnow M. 2005. High-tenacity man-made cellulose fibre reinforced thermoplastics – injection moulding compounds with polypropylene and alternative matrices. Comp. A. in press, available online 24 October 2005

  • Gassan J., Einsiedel R., Fink H.-P. and Weigel P. 2003. Profiled part and aggregates for making same. WO 03/033227

  • Lützgendorf R., Mieck K.-P., Reußmann T., Nechwatal A. and Eilers M. 2000. Lyocellfasern – ihr Entwicklungsstand unter dem Aspekt des Einsatzes in Composites. Proceedings of the 3rd International Wood and Natural Fibre Composites Symposium Kassel, Germany, Sept. 19–20, p. 7–1

  • Paunikallio T., Kasanen J., Suvanto M., Pakkanen T.T. (2003) Influence of maleated polypropylene on mechanical properties of composite made of viscose fibre and polypropylene. J. Appl. Polym. Sci. 87: 1895–1900

    Article  CAS  Google Scholar 

  • Paunikallio T., Suvanto M., Pakkanen T.T. (2004) composition, tensile properties, and dispersion of polypropylene composites reinforced with viscose fibres. J. Appl. Polym. Sci. 91: 2676–2684

    Article  CAS  Google Scholar 

  • Seavey K.C., Ghosh I., Davis R.M., Glasser W.G. (2001) Continuous cellulose fibre reinforced cellulose ester composites. I. Manufacturing options. Cellulose 8: 149–159

    Article  CAS  Google Scholar 

  • Seavey K.C., Glasser W.G. (2001) Continuous cellulose fibre reinforced cellulose ester composites. II. Fibre surface modification and consolidation conditions. Cellulose 8: 161–169

    Article  CAS  Google Scholar 

  • Snijder M. and van den Oever M. 2005. Extrusion compounding technology to produce low cost, high performance, natural fibre reinforced plastic granules. 3. N-FibreBase Kongress. Hürth, Germany (see also http://www.agrofibrecomposites.com).

  • Voges M., Brück M., Gensrich J. and Fink H.-P. 2002. The CARBACELL process – an environmentally friendly alternative for cellulosic man-made fibre production. ipw/Das Papier, issue 4, T74

  • Weigel P, Ganster J, Fink H-P, Gassan J, Uihlein K. (2002) Polypropylene-Cellulose Compounds – High Strength Cellulose Fibres Strengthen Injection Moulded Parts. Kunststoffe plast europe 92:35–37

    Google Scholar 

Download references

Acknowledgements

This work has been supported by the Fraunhofer Society within the internal project “Novel polymer-based commodity materials”. We are indebted to Dr M. Pinnow (this institute) for recording the SEM pictures and Cordenka Corp. for long lasting cooperation and support. We thank Tencel Ltd., UK, and Kelheim Faser GmbH, Germany, for providing speciality slivers.

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Correspondence to Hans-Peter Fink.

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Ganster, J., Fink, HP. Novel cellulose fibre reinforced thermoplastic materials. Cellulose 13, 271–280 (2006). https://doi.org/10.1007/s10570-005-9045-9

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  • DOI: https://doi.org/10.1007/s10570-005-9045-9

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