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A Novel NiWS-TiO2(w) Catalyst Using NiWO4 Nanoparticles as Precursor with Enhanced Hydrodesulfurization Activity

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Abstract

In this work, NiWO4 nanoparticles were prepared by a novel simple method and loading on the mesoporous TiO2 whiskers (TiO2(w)) carrier as the precursor of NiWS. In addition, the NiWS-TiO2(w) catalysts showing high hydrodesulfurization (HDS) activity is described. The structure and chemical composition of the as-prepared samples were characterized by X-ray powder diffraction, X-ray photoelectron spectroscopy, temperature-programmed reduction, NH3-temperature programmed desorption and transmission electron microscopy, respectively. Results indicate that smaller crystallite size and better dispersion of active NiWO4 particles could be achieved by using TiO2(w) as the support to disperse NiWO4 nanoparticles. TiO2(w) can also decrease the reduction temperature of Ni–W metal oxide and promote a highly sulfidation degree of Ni and W active sites. The obtained NiWS-TiO2(w) catalysts show much higher dibenzothiop HDS activity than the unsupported NiWS catalyst, and the sulphur content of desulfurated oil can reach 20 ppm at the mild condition of 260 °C and 2 Mpa.

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References

  1. Liu F, Xu SP, Chi YW, Xue DF (2011) Catal Commun 12:521

    Article  CAS  Google Scholar 

  2. Bermúdez V, Luján JM, Piqueras P, Campos D (2014) Energy 66:509

    Article  Google Scholar 

  3. Dhar GM, Srinivas B, Rana M, Kumar M, Maity S (2003) Catal Today 86:45

    Article  CAS  Google Scholar 

  4. Pawelec B, Navarro R, Campos-Martin J, Agudo AL, Vasudevan P, Fierro J (2003) Catal Today 86:73

    Article  CAS  Google Scholar 

  5. Robinson W, Van Veen J, De Beer V, Van Santen R (1999) Fuel Process Technol 61:103

    Article  CAS  Google Scholar 

  6. Ji Y, Afanasiev P, Vrinat M, Li WZ, Li C (2004) Appl Catal A 257:157

    Article  CAS  Google Scholar 

  7. Zhang L, Afanasiev P, Li DD, Long XY, Vrinat M (2007) Catal Commun 8:2232

    Article  CAS  Google Scholar 

  8. Bi YF, Nie H, Li DD, Zeng SQ, Yang QH, Li MF (2010) Chem Commun 46:7430

    Article  CAS  Google Scholar 

  9. Wang H, Wu Y, Liu ZW, He L, Yao ZY, Zhao WY (2014) Fuel 136:185

    Article  CAS  Google Scholar 

  10. Olivas A, Alonso G, Fuentes S (2006) Top Catal 39:175

    Article  CAS  Google Scholar 

  11. Wang HY, Xiao B, Cheng XX, Wang CJ, Zhao L, Zhu YJ, Zhu JH, Lu XH (2015) Appl Catal A 502:157

    Article  CAS  Google Scholar 

  12. Kaluža L, Gulková D, Vít Z, Zdražil M (2015) Appl Catal B 162:430

    Article  Google Scholar 

  13. Ramirez J, Macias G, Cedeno L, Gutierrez-Alejandre A, Cuevas R, Castillo P (2004) Catal Today 98:19

    Article  CAS  Google Scholar 

  14. Guo CL, Wu YY, Wang X, Yang B (2013) J Energy Chem 22:517

    Article  CAS  Google Scholar 

  15. Li LC, Zhu YD, Lu XH, Wei MJ, Zhuang W, Yang ZH, Feng X (2012) Chem Commun 48:11525

    Article  CAS  Google Scholar 

  16. Song H, Dai M, Song HL, Wan X, Xu XW, Zhang CY, Wang HY (2014) Catal Commun 43:151

    Article  CAS  Google Scholar 

  17. Wang HY, Cheng XS, Xiao B, Wang CJ, Zhao L, Zhu YJ (2015) Catal Surv Asia 19:78

    Article  CAS  Google Scholar 

  18. He M, Lu XH, Feng X, Yu L, Yang ZH (2004) Chem Commun 19:2202

    Article  Google Scholar 

  19. DeGuzman RN, Shen YF, Neth EJ, Suib SL, O’Young CL, Levine S, Newsam JM (1994) Chem Mater 6:815

    Article  CAS  Google Scholar 

  20. Oyama S, Wang X, Lee YK, Bando K, Requejo F (2002) J Catal 210:207

    Article  CAS  Google Scholar 

  21. Rodríguez-Castellón E, Jiménez-López A, Eliche-Quesada D (2008) Fuel 87:1195

    Article  Google Scholar 

  22. Palcheva R, Dimitrov L, Tyuliev G, Spojakina A, Jiratova K (2013) Appl Surf Sci 265:309

    Article  CAS  Google Scholar 

  23. Yoshinaka S, Segawa K (1998) Catal Today 45:293

    Article  CAS  Google Scholar 

  24. De León JD, Picquart M, Massin L, Vrinat M, De Los J (2012) Reyes. J Mol Catal A 363:311

    Article  Google Scholar 

  25. Lai WK, Song WJ, Pang LQ, Wu ZF, Zheng N, Li JJ, Zheng JB, Yi XD, Fang WP (2013) J Catal 303:80

    Article  CAS  Google Scholar 

  26. Bi YF, Zeng SQ, Nie H, Li MF, Yang QH, Xia GF, Li DD (2014) Catal Commun 57:5

    Article  CAS  Google Scholar 

  27. Diebold U (2003) Surf Sci Rep 48:53

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The research is financially supported by the National Young Top Talents Plan of China (2013042), National Science Foundation of China (Grant Nos. 51175066), FANEDD (201164), New Century Excellent Talents in University (NCET-12-0704), Provincial Key Laboratory of Oil &Gas Chemical Technology (PS13H11), and the Science Foundation for Distinguished Young Scholars of Heilongjiang Province (JC201403).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, 163318, China

    Chijia Wang, Huaiyuan Wang, Li Zhao, Shuhui Yang & Yanji Zhu

Authors
  1. Chijia Wang
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  2. Huaiyuan Wang
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  3. Li Zhao
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  4. Shuhui Yang
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  5. Yanji Zhu
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Correspondence to Huaiyuan Wang.

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Wang, C., Wang, H., Zhao, L. et al. A Novel NiWS-TiO2(w) Catalyst Using NiWO4 Nanoparticles as Precursor with Enhanced Hydrodesulfurization Activity. Catal Surv Asia 20, 34–40 (2016). https://doi.org/10.1007/s10563-015-9203-5

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