Skip to main content
SpringerLink
Log in

Oxidative Desulfurization by Oxygen Using Amphiphilic Quaternary Ammonium Peroxovanadium Polyoxometalates

  • Published:
Catalysis Surveys from Asia Aims and scope Submit manuscript

Abstract

An amphiphilic peroxovanadium polyoxometalate {[C16H33N(CH3)3]5[PMo10V2O38(O2)2]} (abbreviated as C16PMo10V2(O2)2) was fabricated using surfactant and peroxovanadium polyoxometalate as precursors. It was used as a reverse-micellar catalyst for efficient oxidative desulfurization (ODS) using oxygen as an oxidant under mild conditions (atmospheric pressure, 70 °C). Dibenzothiophene removal could reach 98 % with sulfone 100 % selectivity for 4 h. The catalyst provided a means for improving reaction rates and easy recovery in ODS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Scheme 1
Fig. 7

References

  1. Francisco M, Arce A, Soto A (2010) Fluid Phase Equilib 294:39

    Article  CAS  Google Scholar 

  2. Röthlisberger A, Prins R (2005) J Catal 235:229

    Article  Google Scholar 

  3. Pawelec B, Navarro RM, Campos-Martin JM, Fierro JLG (2011) Catal Sci Technol 1:23

    Article  CAS  Google Scholar 

  4. Stanislaus A, Marafi A, Rana MS (2010) Catal Today 153:1

    Article  CAS  Google Scholar 

  5. Jiang Z, Lü H, Zhang Y, Li C (2011) Chin J Catal 32:707

    Article  CAS  Google Scholar 

  6. Srivastava VC (2012) RSC Adv 2:759

    Article  Google Scholar 

  7. Ismagilov Z, Yashnik S, Kerzhentsev M, Parmon V, Bourane A, Al-Shahrani FM, Hajji AA (2011) Catal Rev 53:199

    Article  CAS  Google Scholar 

  8. Campos-Martin JM, Capel-Sanchez MC, Perez-Presas P, Fierro JLG (2010) J Chem Technol Biotechnol 85:879

    Article  CAS  Google Scholar 

  9. Shojaei AF, Rezvani MA, Loghmani MH (2014) Fuel Process Technol 118:1

    Article  CAS  Google Scholar 

  10. Cho K, Lee Y (2014) Appl Catal B 147:35

    Article  CAS  Google Scholar 

  11. Jin C, Li G, Wang X, Zhao L, Liu L, Liu H, Liu Y, Zhang W, Han X, Bao X (2007) Chem Mater 19:1664

    Article  CAS  Google Scholar 

  12. Zheng H, Sun Z, Chen X, Zhao Q, Wang X, Jiang Z (2013) Appl Catal A 467:26

    Article  CAS  Google Scholar 

  13. Lü H, Ren W, Wang H, Wang Y, Chen W, Suo Z (2013) Appl Catal A 453:376

    Article  Google Scholar 

  14. Lü H, Deng C, Renb W, Yang X (2014) Fuel Process Technol 119:87

    Article  Google Scholar 

  15. Nie Y, Dong Y, Bai L, Dong H, Zhang X (2013) Fuel 103:997

    Article  CAS  Google Scholar 

  16. McNamara ND, Neumann GT, Masko ET, Urban JA, Hicks JC (2013) J Catal 305:217

    Article  CAS  Google Scholar 

  17. Hu X, Lu Y, Dai F, Liu C, Liu Y (2013) Micro Meso Mater 170:36

    Article  CAS  Google Scholar 

  18. Khenkin AM, Neumann R (2011) ChemSusChem 4:346

    Article  CAS  Google Scholar 

  19. Chica A, Corma A, Dómine ME (2006) J Catal 242:299

    Article  CAS  Google Scholar 

  20. Lin F, Zhang Y, Wang L, Zhang Y, Wang D, Yang M, Yang J, Zhang B, Jiang Z, Li C (2012) Appl Catal B 127:363

    Article  CAS  Google Scholar 

  21. Xu X, Moulijn JA, Ito E, Wagemans R, Makkee M (2008) ChemSusChem 1:817

    Article  CAS  Google Scholar 

  22. Mizuno N, Kamata K (2011) Coord Chem Rev 255:2358

    Article  CAS  Google Scholar 

  23. Kholdeeva OA (2013) Eur J Inorg Chem 10–11:1595

    Article  Google Scholar 

  24. Nlate S, Jahier C (2013) Eur J Inorg Chem 10–11:1606

    Article  Google Scholar 

  25. Song YF, Tsunashima R (2012) Chem Soc Rev 41:7384

    Article  CAS  Google Scholar 

  26. Mizuno N, Kamata K (2011) Chem Rev 255:2358

    CAS  Google Scholar 

  27. Gao H, Lü J, Jiang Z, Yang Y, Song B, Li C (2007) Chem Commun 2:150

    Google Scholar 

  28. Tang NF, Zhang YN, Lin F, Lü HY, Jiang ZX, Li C (2012) Chem Commun 48:11647

    Article  CAS  Google Scholar 

  29. Lü H, Ren W, Liao W, Chen W, Li Y, Suo Z (2013) Appl Catal B 138–139:79

    Article  Google Scholar 

  30. Lü H, Zhang Y, Jiang Z, Li C (2010) Green Chem 12:1954

    Article  Google Scholar 

  31. Jiang C, Wang J, Wang S, Guan H, Wang X, Huo M (2011) Appl Catal B 106:343

    Article  CAS  Google Scholar 

  32. Wei M, Zhang C, Sun C, Li A, Wang X (2011) Chin Chem Lett 22:875

    Article  CAS  Google Scholar 

  33. Aubry C, Chottard G, Platzer N, Bregeault JM, Thouvenot R, Chauveau F, Huet C, Ledon H (1991) Inorg Chem 30:4409

    Article  CAS  Google Scholar 

  34. Chen Y, Zhuang J, Liu X, Gao J, Han X, Bao X, Zhou N, Gao S, Xi Z (2004) Catal Lett 93:41

    Article  CAS  Google Scholar 

  35. Ohno T, Masaki Y, Hirayama S, Matsumura M (2001) J Catal 204:163

    Article  CAS  Google Scholar 

  36. Xu LL, Li W, Hu JL, Li KX, Yang X, Ma FY, Guo YN, Yu XD, Guo YH (2009) J Mater Chem 19:8571

    Article  CAS  Google Scholar 

  37. Tsigdinos GA, Hallada CJ (1968) Inorg Chem 7:437

    Article  CAS  Google Scholar 

  38. Takagiwa Y, Kimura K (2014) Dep Adv Mater Sci 15:1

    Google Scholar 

  39. Kumar D, Rub MA, Akram MJ (2014) Colloid Interface Sci 418:324

    Article  CAS  Google Scholar 

  40. Young KL, Personick ML, Engel M, Damasceno PF, Barnaby SN, Bleher R, Li T, Glotzer SC, Lee B, Mirkin CA (2013) Angew Chem Int Ed 52:13980

    Article  CAS  Google Scholar 

  41. Ruckenstein E, Nagarajan RJ (1975) Phys Chem 79:2622

    Article  CAS  Google Scholar 

  42. Nazir N, Ahanger MS, Akbar A (2009) J Dispers Sci Technol 30:51

    Article  CAS  Google Scholar 

  43. Mukherjee P, Mysels KJ (1971) NSRDS-NBS 36

Download references

Acknowledgments

The authors are grateful for the financial supported by the National Natural Science Foundation of China (51078066 and 20871026), the foundation of Jilin Provincial Environmental Protection Bureau (No. 200929).

Author information

Authors and Affiliations

  1. Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun, 130024, Jilin, People’s Republic of China

    Meilin Tao, Hongwei Zheng, Shengtian Wang & Xiaohong Wang

  2. School of Biology, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Guohui Huang

  3. Wood Material Science and Engineering Key Laboratory of Jilin Province, Beihua University, Jilin, 132013, People’s Republic of China

    Junyou Shi

Authors
  1. Meilin Tao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hongwei Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Junyou Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shengtian Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xiaohong Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Guohui Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xiaohong Wang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 3333 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tao, M., Zheng, H., Shi, J. et al. Oxidative Desulfurization by Oxygen Using Amphiphilic Quaternary Ammonium Peroxovanadium Polyoxometalates. Catal Surv Asia 19, 257–264 (2015). https://doi.org/10.1007/s10563-015-9197-z

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10563-015-9197-z

Keywords

Search

Navigation