Skip to main content
SpringerLink
Log in

Synthesis and Adsorption/Catalytic Properties of the Metal Organic Framework CuBTC

  • Published:
Catalysis Surveys from Asia Aims and scope Submit manuscript

Abstract

CuBTC (Copper(II) benzene-1,3,5-tricarboxylate) is one of the most well characterized and widely studied metal organic framework (MOF) structures for potential use in industrial applications due to its relatively easy synthesis and excellent textural and physicochemical properties. In this comprehensive review, a different perspective on MOF materials for future sustainability is presented by critically examining the recent works that have considered the synthesis and adsorption/catalytic applications of CuBTC as a model case.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Tranchemontagne DJ, Mendoza-Cortés JL, O’Keeffe M, Yaghi OM (2009) Chem Soc Rev 38:1257

    Article  CAS  Google Scholar 

  2. Li JR, Kuppler RJ, Zhou HC (2009) Chem Soc Rev 38:1477

    Article  CAS  Google Scholar 

  3. Hu YH, Zhang L (2010) Adv Mater 22:E117

    Article  CAS  Google Scholar 

  4. Morris RE, Wheatley PS (2008) Angew Chem Int Ed 47:4966

    Article  CAS  Google Scholar 

  5. Czaja AU, Trukhan AU, Müller (2009) Chem Soc Rev 38:1284

    Article  CAS  Google Scholar 

  6. Schlichte K, Kratzke T, Kaskel S (2004) Microporous Mesoporous Mater 73:81

    Article  CAS  Google Scholar 

  7. Krawiec P, Kramer M, Sabo M, Kunschke R, Frode H, Kaskel S (2006) Adv Eng Mater 8:293

    Article  CAS  Google Scholar 

  8. Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM (2002) Science 295:469

    Article  CAS  Google Scholar 

  9. Keskin S, van Heest TM, Sholl DS (2010) ChemSusChem 3:879

    Article  CAS  Google Scholar 

  10. Britt D, Tranchemontagne D, Yaghi OM (2008) PNAS 105:11623

    Article  CAS  Google Scholar 

  11. Millward AR, Yaghi OM (2005) J Am Chem Soc 127:17998

    Article  CAS  Google Scholar 

  12. Yazaydın AÖ, Snurr RQ, Park TH, Koh K, Liu J, LeVan MD, Benin AI, Jakubczak P, Lanuza M, Galloway DB, Low JJ, Willis RR (2009) J Am Chem Soc 131:18198

    Article  Google Scholar 

  13. Kim J, Yang ST, Choi SB, Sim J, Kim J, Ahn WS (2011) J Mater Chem 21:3070

    Article  CAS  Google Scholar 

  14. Farrusseng D, Aguado S, Pinel C (2009) Angew Chem Int Ed 48:7502

    Article  CAS  Google Scholar 

  15. Lee JY, Farha OK, Roberts J, Scheidt KA, Nguyen SBT, Hupp JT (2009) Chem Soc Rev 38:1450

    Article  CAS  Google Scholar 

  16. Kim J, Bhattacharjee S, Jeong KE, Jeong SY, Ahn WS (2009) Chem Commun 3904

  17. Kleist W, Maciejewski M, Baiker A (2010) Thermochim Acta 499:71

    Article  CAS  Google Scholar 

  18. Cohen SM (2010) Chem Sci 1:32

    Article  CAS  Google Scholar 

  19. Wang Z, Cohen SM (2009) Chem Soc Rev 38:1315

    Article  CAS  Google Scholar 

  20. Canivet J, Aguado S, Bergeret G, Farrusseng D (2011) Chem Commun 47:11650

    Article  CAS  Google Scholar 

  21. Mueller U, Schubert M, Teich F, Puetter H, Schierle-Arndt K, Pastré J (2006) J Mater Chem 16:626

    Article  CAS  Google Scholar 

  22. Meek ST, Greathouse JA, Allendorf MD (2011) Adv Mater 23:249

    Article  CAS  Google Scholar 

  23. Chui SS-Y, Lo SM-F, Charmant JPH, Orpen AG, Williams ID (1999) Science 283:1148

    Article  CAS  Google Scholar 

  24. Wang QM, Shen D, Bulow M, Lau ML, Deng S, Fitch FR, Lemcoff NO, Semanscin J (2002) Microporous Mesoporous Mater 55:217

    Article  CAS  Google Scholar 

  25. Mateovic T, Kriznar B, Bogataj M, Mrhar A (2002) J Microencapsulation 19:29

    Article  CAS  Google Scholar 

  26. Yang QY, Xue CY, Zhong CL, Chen JF (2007) AIChE J 53:2832

    Article  CAS  Google Scholar 

  27. Chowdhury P, Bikkina C, Meister D, Dreisbach F, Gumma S (2009) Microporous Mesoporous Mater 117:406

    Article  CAS  Google Scholar 

  28. Jiang D, Mallat T, Krumeich F, Baiker A (2011) Catal Commun 12:602

    Article  CAS  Google Scholar 

  29. Seo YK, Hundal G, Jang IT, Hwang YK, Jun CH, Chang JS (2009) Microporous Mesoporous Mater 119:331

    Article  CAS  Google Scholar 

  30. Liu J, Wang Y, Benin AI, Jakubczak P, Wills RR, LeVan MD (2010) Langmuir 26:14301

    Article  CAS  Google Scholar 

  31. Hartmann M, Kunz S, Himsl D, Tangermann O (2008) Langmuir 24:8634

    Article  CAS  Google Scholar 

  32. Liu J, Culp JT, Natesakhawat S, Bockrath BC, Zande B, Sankar SG, Garberoglio G, Johnson JK (2007) J Phys Chem C 111:9305

    Article  CAS  Google Scholar 

  33. Finney KN, Sharifi VN, Swithenbank J (2009) Energy Fuels 23:3195

    Article  CAS  Google Scholar 

  34. Cavenati S, Grande CA, Rodrigues AE (2008) Ind Eng Chem Res 47:6333

    Article  CAS  Google Scholar 

  35. Sun LB, Li JR, Park J, Zhou HC (2012) J Am Chem Soc 134:126

    Article  CAS  Google Scholar 

  36. Rowsell JLC, Yaghi OM (2006) J Am Chem Soc 128:1304

    Article  CAS  Google Scholar 

  37. Diring S, Furukawa S, Takashima Y, Tsuruoka T, Kitagawa S (2010) Chem Mater 22:4531

    Article  CAS  Google Scholar 

  38. Li ZQ, Qiu LG, Xu T, Wu Y, Wang W, Wu ZY, Jiang X (2009) Mater Lett 63:78

    Article  CAS  Google Scholar 

  39. Kim SH, Yang ST, Kim J, Ahn WS (2011) Bull Korean Chem Soc 32:2783

    Article  Google Scholar 

  40. Yuan W, Garay AL, Pichon A, Clowes R, Wood CD, Cooper AI, James SL (2010) CrystEngComm 12:4063

    Article  CAS  Google Scholar 

  41. Klimakow M, Klobes P, Thunemann AF, Rademann K, Emmerling F (2010) Chem Mater 22:5216

    Article  CAS  Google Scholar 

  42. Ameloot R, Vermoortele F, Vanhove W, Roeffaers MBJ, Sels BF, De Vos DE (2011) Nat Chem 3:382

    Article  CAS  Google Scholar 

  43. Choi JS, Son WJ, Kim J, Ahn WS (2008) Microporous Mesoporous Mater 116:727

    Article  CAS  Google Scholar 

  44. Kerner R, Palchik O, Gedanken A (2001) Chem Mater 13:1413

    Article  CAS  Google Scholar 

  45. Xu YP, Tian ZJ, Wang SJ, Hu Y, Wang L, Wang BC, Ma YC, Hou L, Yu JY, Lin LW (2006) Angew Chem Int Ed 45:3965

    Article  CAS  Google Scholar 

  46. Yoon JW, Jang IT, Lee K-Y, Hwang YK, Chang J-S (2010) Bull Korean Chem Soc 31:220

    Article  CAS  Google Scholar 

  47. Tran UPN, Le KKA, Phan NTS (2011) ACS Catal 1:120

    Article  CAS  Google Scholar 

  48. Suslick KS, Hammerton DA, Cline RE (1986) J Am Chem Soc 108:5641

    Article  CAS  Google Scholar 

  49. Tanaka K, Toda F (2000) Chem Rev 100:1025

    Article  CAS  Google Scholar 

  50. Nguyen KL, Friscic T, Day GM, Gladden LF, Jones W (2007) Nat Mater 6:206

    Article  CAS  Google Scholar 

  51. Garay AL, Pichon A, James SL (2007) Chem Soc Rev 36:846

    Article  CAS  Google Scholar 

  52. Shekhah O (2010) Materials 3:1302

    Article  CAS  Google Scholar 

  53. Carbonell C, Imaz I, Maspoch D (2011) J Am Chem Soc 133:2144

    Article  CAS  Google Scholar 

  54. Gascon J, Aguado S, Kapteijn F (2008) Microporous Mesoporous Mater 113:132

    Article  CAS  Google Scholar 

  55. Guerrero VV, Yoo Y, McCarthy MC, Jeong H-K (2010) J Mater Chem 20:3938

    Article  CAS  Google Scholar 

  56. Nan J, Dong X, Wang W, Jin W, Xu N (2011) Langmuir 27:4309

    Article  CAS  Google Scholar 

  57. Balakrishnan S, Downard AJ, Telfer SG (2011) J Mater Chem 21:19207

    Article  CAS  Google Scholar 

  58. Guo H, Zhu G, Hewitt IJ, Qiu S (2009) J Am Chem Soc 131:1646

    Article  CAS  Google Scholar 

  59. Kim J, Kim SH, Yang ST, Ahn WS (2012) Microporous Mesoporous Mater (submitted)

  60. Bae YS, Snurr RQ (2010) Microporous Mesoporous Mater 135:178

    Article  CAS  Google Scholar 

  61. Collins DJ, Zhou HC (2007) J Mater Chem 17:3154

    Article  CAS  Google Scholar 

  62. Rowsell JLC, Yaghi OM (2005) Angew Chem Int Ed 44:4670

    Article  CAS  Google Scholar 

  63. Férey G (2008) Chem Soc Rev 37:191

    Article  Google Scholar 

  64. van den Berg AWC, Areán CO (2008) Chem Commun 668

  65. Murray LJ, Dinca M, Long JR (2009) Chem Soc Rev 38:1294

    Article  CAS  Google Scholar 

  66. Thomas KM (2009) Dalton Trans 1487

  67. Kondo M, Yoshitomi T, Seki K, Matsuzaka H, Kitagawa S (1997) Angew Chem Int Ed 36:1725

    Article  CAS  Google Scholar 

  68. Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM (2003) Science 300:1127

    Article  CAS  Google Scholar 

  69. Panella B, Hirscher M, Pütter H, Müller U (2006) Adv Funct Mater 16:520

    Article  CAS  Google Scholar 

  70. Frost H, Duren T, Snurr RQ (2006) J Phys Chem B 110:9565

    Article  CAS  Google Scholar 

  71. Grzech A, Yang J, Dingemans TJ, Srinivasan S, Magusin PCMM, Mulder FM (2011) J Phys Chem 115:21521

    CAS  Google Scholar 

  72. Wu H, Simmons JM, Liu Y, Brown CM, Wang XS, Ma S, Peterson VK, Southon PD, Kepert CJ, Zhou HC, Yildirim T, Zhou W (2010) Chem Eur J 16:5205

    Article  CAS  Google Scholar 

  73. Li H, Eddaoudi M, Groy TL, Yaghi OM (1998) J Am Chem Soc 120:8571

    Article  CAS  Google Scholar 

  74. Dasgupta S, Biswas N, Aarti, Gode NG, Divekar S, Nanoti A, Goswami AN (2012) Int J Greenhouse Gas Control 7:225

  75. Grajciar L, Wiersum AD, Llewellyn PL, Chang JS, Nachtigall P (2011) J Phys Chem C 115:17925

    Article  CAS  Google Scholar 

  76. Petit C, Mendoza B, O’Donnell D, Bandasz T (2011) Langmuir 27:10234

    Article  CAS  Google Scholar 

  77. Petit C, Levasseur B, Mendoza B, Bandosz TJ (2012) Microporous Mesoporous Mater 154:113

    Google Scholar 

  78. Hinks NJ, McKinlay AC, Xiao B, Wheatley PS, Morris RE (2010) Microporous Mesoporous Mater 129:330

    Article  CAS  Google Scholar 

  79. Klein N, Henschel A, Kaskel S (2010) Microporous Mesoporous Mater 129:238

    Article  CAS  Google Scholar 

  80. Ryan P, Farha OK, Broadbelt LJ, Snurr RQ (2011) AIChE J 57:1759

    Article  CAS  Google Scholar 

  81. Ke F, Qiu LG, Yuan YP, Peng FM, Jiang X, Xie AJ, Shen YH, Zhu JF (2011) J Hazard Mater 196:36

    Article  CAS  Google Scholar 

  82. Rowsell J, Yaghi OM (2004) Microporous Mesoporous Mater 73:3

    Article  CAS  Google Scholar 

  83. Wu C, Hu A, Zhang L, Lin W (2005) J Am Chem Soc 127:8940

    Article  CAS  Google Scholar 

  84. Alaerts L, Seguin E, Poelman H, Thibault-Starzyk F, Jacobs PA, De Vos DE (2006) Chem Eur J 12:7353

    Article  CAS  Google Scholar 

  85. Horcajada P, Surble S, Serre C, Hong DY, Seo YK, Chang JS, Greneche JM, Margiolaki I, Férey G (2007) Chem Commun 2820

  86. Kitagawa S, Kitaura R, Noro S (2004) Angew Chem Int Ed 43:2334

    Article  CAS  Google Scholar 

  87. Rosseinsky M (2004) Microporous Mesoporous Mater 73:15

    Article  CAS  Google Scholar 

  88. Yaghi OM, Davis C, Li G, Li H (1997) J Am Chem Soc 119:2861

    Article  CAS  Google Scholar 

  89. Dhakshinamoorthy A, Alvaro M, Garcia H (2011) ACS Catal 1:48

    Article  CAS  Google Scholar 

  90. Janiak C (2003) Dalton Trans 2781

  91. Huang L, Wang H, Chen J, Wang Z, Sun J, Zhao D, Yan Y (2003) Microporous Mesoporous Mater 58:105

    Article  CAS  Google Scholar 

  92. Lin C, Chui S, Lo S, Shek F, Wu M, Suwinska K, Lipkowski J, Williams I (2002) Chem Commun 1642

  93. Reineke T, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Angew Chem Int Ed 38:2590

    Article  CAS  Google Scholar 

  94. Dhakshinamoorthy A, Alvaro M, Garcia H (2010) Chem Eur J 16:8530

    Article  CAS  Google Scholar 

  95. Dhakshinamoorthy A, Alvaro M, Garcia H (2010) Adv Synth Catal 352:3022

    Article  CAS  Google Scholar 

  96. Dhakshinamoorthy A, Alvaro M, Garcia H (2010) Appl Catal A 378:19

    Article  CAS  Google Scholar 

  97. Pérez-Mayoral E, Čejka J (2011) ChemCatChem 3:157

    Article  Google Scholar 

  98. Corma A, Iglesias M, Llabrés i Xamena FX, Sánchez F (2010) Chem Eur J 16:9789

    Article  CAS  Google Scholar 

  99. Luz I, Llabrés i Xamena FX, Corma A (2010) J Catal 276:134

    Article  CAS  Google Scholar 

  100. Dhakshinamoorthy A, Alvaro M, Garcia H (2009) J Catal 267:1

    Article  CAS  Google Scholar 

  101. Wee LH, Bajpe SR, Janssens N, Hermans I, Houthoofd K, Kirschhock CEA, Martens JA (2010) Chem Commun 46:8186

    Article  CAS  Google Scholar 

  102. Sun CY, Liu SX, Liang DD, Shao KZ, Ren YH, Su ZM (2009) J Am Chem Soc 131:1883

    Article  CAS  Google Scholar 

  103. Hundal G, Hwang YK, Chang JS (2009) Polyhedron 28:2450

    Article  CAS  Google Scholar 

  104. Yang L, Naruke H, Yamase T (2003) Inorg Chem Commun 6:1020

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the NRF Grant funded by MEST (No. 2010-0012257) in Korea.

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Inha University, Incheon, 402-751, Korea

    Jun Kim, Hye-Young Cho & Wha-Seung Ahn

Authors
  1. Jun Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hye-Young Cho
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wha-Seung Ahn
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Wha-Seung Ahn.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, J., Cho, HY. & Ahn, WS. Synthesis and Adsorption/Catalytic Properties of the Metal Organic Framework CuBTC. Catal Surv Asia 16, 106–119 (2012). https://doi.org/10.1007/s10563-012-9135-2

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10563-012-9135-2

Keywords

Search

Navigation