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A Novel Synthesis and Characterization of Titanium Superoxide and its Application in Organic Oxidative Processes

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Abstract

A novel, exceptionally stable titanium superoxide radical ion was prepared and its structure determined by FTIR, ESR, Raman spectroscopy, X-ray diffraction, thermogravimetric/differential thermal analysis and elemental analysis. This heterogeneous catalyst has been found to be effective for the selective oxidation of aromatic amines and phenols to the corresponding nitro aromatics and p-quinones, respectively. In addition, this non-toxic, inexpensive and reusable catalyst has also been used in aminobromination of olefins, which proceed to give the 1, 2-bromoaminated anti-Markovnikov product. A brief account of these results is summarized in this review.

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Acknowledgments

The authors are thankful to the Department of Science and Technology, New Delhi for financial support (No. SR/S1/OC-72/2006). Also, the authors sincerely thank Dr. B. D. Kulkarni, Dy. Director, NCL, Pune, for his constant encouragement.

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Authors and Affiliations

  1. Chemical Engineering and Process Development Division, National Chemical Laboratory, Pashan Road, Pune, 411 008, India

    R. Santhosh Reddy, Tanveer Mahamadali Shaikh, Varun Rawat, Pratibha U. Karabal, Gajanan Dewkar, Gurunath Suryavanshi & Arumugam Sudalai

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  1. R. Santhosh Reddy
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  2. Tanveer Mahamadali Shaikh
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  3. Varun Rawat
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  4. Pratibha U. Karabal
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  7. Arumugam Sudalai
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Correspondence to Arumugam Sudalai.

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Santhosh Reddy, R., Shaikh, T.M., Rawat, V. et al. A Novel Synthesis and Characterization of Titanium Superoxide and its Application in Organic Oxidative Processes. Catal Surv Asia 14, 21–32 (2010). https://doi.org/10.1007/s10563-010-9085-5

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