Abstract
PtSn/Al2O3 and PtSnSr/Al2O3 were prepared by the incipient wetness impregnation method. The added Sn and Sr are uniformly distributed on the surface without damaging the original crystal structure and surface texture properties. The addition of Sn not only changes the dispersion of Pt, reduces the reduction temperature of Pt, but also provides electrons to Pt, increases the electron cloud density on the surface of Pt, and reduces the deep propylene adsorption. The addition of Sr reduces the number of total acid sites and strong acid sites, reduces the generation of adverse effects and carbon deposition, slows down the deactivation of the catalyst, and improves the selectivity of propylene. Pt1.5Sn1.5Sr/Al2O3 showed the best catalytic reaction performance and remained stable after five cycles of regeneration.
Graphical Abstract
Similar content being viewed by others
References
Liu S, Zhang BF, Liu GZ (2021) Metal-based catalysts for the non-oxidative dehydrogenation of light alkanes to light olefins. React Chem Eng 6:9–26. https://doi.org/10.1039/D0RE00381F
Muhlenkamp JA, Cho Y, Hicks JC (2023) Modulating Propane dehydrogenation performance and stability of Ni2P with Co doping. Catal Lett 262:1 10. https://doi.org/10.1007/s10562-023-04357-4
Crivelaro VM, Cortez GG (2023) Propane oxidative dehydrogenation over Sr-doped V catalyst supported on Nb2O5-Al2O3. Catal Lett 153:3651–3664. https://doi.org/10.1007/s10562-022-04262-2
Fu HY, Qian WX, Zhang HT, Ma HF, Ying WY (2023) Different alkali metals promoted Cr/Al2O3 catalysts for propane dehydrogenation. Fuel 342:127774. https://doi.org/10.1016/j.fuel.2023.127774
Tedeeva MA, Kustov AL, Pribytkov PV, Kapustin GI, Leonov AV, Tkachenko OP, Tursunov OB, Evdokimenko ND, Kustov LM (2022) Dehydrogenation of propane in the presence of CO2 on GaOx/SiO2 catalyst: influence of the texture characteristics of the support. Fuel 313:122698. https://doi.org/10.1016/j.fuel.2021.122698
Sun ML, Hu ZP, Wang HY, Suo YJ, Yuan ZY (2023) Design strategies of stable catalysts for propane dehydrogenation to propylene. ACS Catal 13:4719–4741. https://doi.org/10.1021/acscatal.3c00103
Shi XX, Chen S, Li S, Yang YQ, Guan QQ, Ding JN, Liu XY, Liu Q, Xu WL, Lu JL (2023) Particle size effect of SiO2-supported ZnO catalysts in propane dehydrogenation. Catal Sci Technol 13:1866–1873. https://doi.org/10.1039/D2CY02131E
Hu ZP, Yang DD, Wang Z, Yuan ZY (2019) State-of-the-art catalysts for direct dehydrogenation of propane to propylene. Chin J Catal 40:1233–1254. https://doi.org/10.1016/S1872-2067(19)63360-7
Chen S, Chang X, Sun GD, Zhang TT, Xu YY, Wang Y, Pei CL, Gong JL (2021) Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies. Chem Soc Rev 50:3315–3354. https://doi.org/10.1039/D0CS00814A
Nawaz Z (2015) Light alkane dehydrogenation to light olefin technologies: a comprehensive review. Rev Chem Eng 31:413–436. https://doi.org/10.1515/revce-2015-0012
Zuo C, Su Q (2023) Research progress on propylene preparation by propane dehydrogenation. Molecules 28:3594. https://doi.org/10.3390/molecules28083594
Rodaum C, Chaipornchalerm P, Nunthakitgoson W, Thivasasith A, Maihom T, Atithep T, Kidkhunthod P, Uthayopas C, Nutanong S, Thongratkaew S, Faungnawakij K, Wattanakit C (2022) Highly efficient propane dehydrogenation promoted by reverse water–gas shift reaction on Pt–Zn alloy surfaces. Fuel 325:124833. https://doi.org/10.1016/j.fuel.2022.124833
Li YM, Zhang QY, Fu ST, Kondratenko VA, Otroshchenko T, Bartling S, Zhang YY, Zanina A, Wang YJ, Cui GQ, Zhou MX, Zhao Z, Xu CM, Jiang GY, Kondratenko EV (2023) Active species and fundamentals of their creation in co-containing catalysts for efficient propane dehydrogenation to propylene. Chem Eng J 460:141778. https://doi.org/10.1016/j.cej.2023.141778
Choung S, Kim Y, Moon J, Roh J, Hwang J, Han JW (2023) Unveiling the catalyst deactivation mechanism in the non-oxidative dehydrogenation of light alkanes on Rh(111): Density functional theory and kinetic Monte Carlo study. Catal Today 411–412:113819. https://doi.org/10.1016/j.cattod.2022.06.034
Wang HZ, Zhang W, Jiang JW, Sui ZJ, Zhu YA, Ye GH, Chen D, Zhou XG, Yuan WK (2019) The role of H2S addition on Pt/Al2O3 catalyzed propane dehydrogenation: a mechanistic study. Catal Sci Technol 9:867–876. https://doi.org/10.1039/C8CY02393J
Luo QX, Zhang XK, Hou BL, Chen JG, Zhu C, Liu ZW, Liu ZT, Lu J (2018) Catalytic function of VOx/Al2O3 for oxidative dehydrogenation of propane: support microstructure-dependent mass transfer and diffusion. Catal Sci Technol 8:4864–4876. https://doi.org/10.1039/C8CY00564H
Rimaz S, Chen LW, Kawi S, Borgna A (2019) Promoting effect of Ge on Pt-based catalysts for dehydrogenation of propane to propylene. Appl Catal A 588:117266. https://doi.org/10.1016/j.apcata.2019.117266
Wu J, Peng ZM, Bell AT (2014) Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100−x/Mg(Al)O (70⩽x⩽100). J Catal 311:161–168. https://doi.org/10.1016/j.jcat.2013.11.017
Nagaraja BM, Shin CH, Jung KD (2013) Selective and stable bimetallic PtSn/θ-Al2O3 catalyst for dehydrogenation of n-butane to n-butenes. Appl Catal A 467:211–223. https://doi.org/10.1016/j.apcata.2013.07.022
Wang YS, Hu ZP, Tian WW, Gao LJ, Wang Z, Yuan ZY (2019) Framework-confined Sn in Si-beta stabilizing ultra-small Pt nanoclusters as direct propane dehydrogenation catalysts with high selectivity and stability. Catal Sci Technol 9:6993–7002. https://doi.org/10.1039/C9CY01907C
Rimaz S, Chen LW, Monzón A, Kawi S, Borgna A (2021) Enhanced selectivity and stability of Pt–Ge/Al2O3 catalysts by Ca promotion in propane dehydrogenation. Chem Eng J 405:1266560. https://doi.org/10.1016/j.cej.2020.126656
Sricharoen C, Jongsomjit B, Panpranot J, Praserthdam P (2021) The key to catalytic stability on sol–gel derived SnOx/SiO2 catalyst and the comparative study of side reaction with K-PtSn/Al2O3 toward propane dehydrogenation. Catal Today 375:343–351. https://doi.org/10.1016/j.cattod.2020.05.053
Jang EJ, Lee J, Jeong HY, Kwak JH (2019) Controlling the acid-base properties of alumina for stable PtSn-based propane dehydrogenation catalysts. Appl Catal A 572:1–8. https://doi.org/10.1016/j.apcata.2018.12.024
Xu ZK, Xu R, Yue YY, Yuan P, Bao XJ, Abou-Hamad E, Basset JM, Zhu HB (2019) Bimetallic Pt–Sn nanocluster from the hydrogenolysis of a well-defined surface compound consisting of [(AlO)Pt(COD)Me] and [(AlO)SnPh3] fragments for propane dehydrogenation. J Catal 374:391–400. https://doi.org/10.1016/j.jcat.2019.04.035
Zhu XY, Wang TH, Xu ZK, Yue YY, Lin MG, Zhu HB (2022) Pt–Sn clusters anchored at Al3+penta sites as a sinter-resistant and regenerable catalyst for propane dehydrogenation. J Energy Chem 65:293–301. https://doi.org/10.1016/j.jechem.2021.06.002
Jiang P, Fu HY, Ma HF, Qian WX, Zhang HT, Ying WY (2020) Dehydrogenation of propane over sugar foams templated Ga2O3 nanoparticles catalysts. Catal Lett 151:1894–1901. https://doi.org/10.1007/s10562-020-03452-0
Shi Y, Li XR, Rong X, Gu B, Wei HZ, Zhao Y, Wang W, Sun CL (2020) Effect of aging temperature of support on catalytic performance of PtSnK/Al2O3 propane dehydrogenation catalyst. Catal Lett 150:2283–2293. https://doi.org/10.1007/s10562-020-03115-0
Yu QQ, Yu T, Chen HY, Fang GZ, Pan XL, Bao XH (2020) The effect of Al3+ coordination structure on the propane dehydrogenation activity of Pt/Ga/Al2O3 catalysts. J Energy Chem 41:93–99. https://doi.org/10.1016/j.jechem.2019.04.027
Wang GJ, Lu K, Yin CQ, Meng FF, Zhang QQ, Yan XL, Bing LC, Wang F, Han DZ (2020) One-step fabrication of PtSn/γ-Al2O3 catalysts with La post-modification for propane dehydrogenation. Catalysts 10:1042. https://doi.org/10.3390/catal10091042
Qiu Y, Li XY, Zhang YY, Xie C, Zhou S, Wang R, Luo SZ, Jing FL, Chu W (2019) Various metals (Ce, In, La, and Fe) promoted Pt/Sn-SBA-15 as highly stable catalysts for propane dehydrogenation. Ind Eng Chem Res 58:10804–10818. https://doi.org/10.1021/acs.iecr.9b01413
Sattler JJHB, Ruiz-Martinez J, Santillan-Jimenez E, Weckhuysen BM (2014) Catalytic dehydrogenation of light alkanes on metals and metal oxides. Chem Rev 114:10613–10653. https://doi.org/10.1021/cr5002436
Zhang YW, Zhou YM, Shi JJ, Zhou SJ, Sheng XL, Zhang ZW, Xiang SM (2014) Comparative study of bimetallic Pt–Sn catalysts supported on different supports for propane dehydrogenation. J Mol Catal A: Chem 381:138–147. https://doi.org/10.1016/j.molcata.2013.10.007
Lee MH, Nagaraja BM, Lee KY, Jung KD (2014) Dehydrogenation of alkane to light olefin over PtSn/θ-Al2O3 catalyst: effects of Sn loading. Catal Today 232:53–62. https://doi.org/10.1016/j.cattod.2013.10.011
Deng LD, Wang JW, Wu ZK, Liu CH, Qing L, Liu XW, Xu J, Zhou ZJ, Xu MH (2022) Effects of second metals (M = Fe, Cu, Ga, In, Sn) on the geometric and electronic properties of platinum for the direct dehydrogenation of propane. J Alloys Compd 909:164820. https://doi.org/10.1016/j.jallcom.2022.164820
Gómez-Quero S, Tsoufis T, Rudolf P, Makkee M, Kapteijn F, Rothenberg G (2013) Kinetics of propane dehydrogenation over Pt–Sn/Al2O3. Catal Sci Technol 3:962–971. https://doi.org/10.1039/C2CY20488F
Deng L, Han SB, Li Y, Shen WJ (2022) Subnanometric Pt–Sn monolayers over a rod-shaped Al2O3 for propane dehydrogenation. ChemCatChem 14:e202200400. https://doi.org/10.1002/cctc.202200400
Rimaz S, Sabbaghan M, Kosari M, Zarinejad M, Amini M (2022) Anti-sintering MgAl2O4 supported Pt–Ge nanoparticles for propane dehydrogenation: catalytic insights and machine-learning aided performance analysis. Mol Catal 531:112695. https://doi.org/10.1016/j.mcat.2022.112695
Xu JS, Shi CX, Zhang SG, Zheng QC, Pan L, Zhang XW, Zou JJ (2022) Framework Zr stabilized PtSn/Zr-MCM-41 as a promising catalyst for non-oxidative ethane dehydrogenation. Chin J Chem 40:918–924. https://doi.org/10.1002/cjoc.202100657
Zhang YW, Zhou YM, Zhang SB, Zhou SJ, Sheng XL, Wang QL, Zhang C (2015) Catalytic structure and reaction performance of PtSnK/ZSM-5 catalyst for propane dehydrogenation: influence of impregnation strategy. J Mater Sci 50:6457–6468. https://doi.org/10.1007/s10853-015-9201-z
Liu X, Lang WZ, Long LL, Hu CL, Chu LF, Guo YJ (2014) Improved catalytic performance in propane dehydrogenation of PtSn/γ-Al2O3 catalysts by doping indium. Chem Eng J 247:183–192. https://doi.org/10.1016/j.cej.2014.02.084
Cao L, Qian R, Zhang YY, Luo SZ, Jiang CF, Jing FL (2023) Surface modification of PtSn/Al2O3 catalyst by organic acid chelation and its effect on propane dehydrogenation performance. J Phys Chem Solids 178:111331. https://doi.org/10.1016/j.jpcs.2023.111331
Naseri M, Tahriri ZF, Taeb A (2021) Effects of Mg, Ca and K addition on Pt–Sn/γ-Al2O3 for propane dehydrogenation. Iran J Chem Chem Eng 41:1921 1931. https://doi.org/10.30492/IJCCE.2021.134840.4283
Shao HQ, Wang X, Gu X, Wang DL, Jiang T, Guo XY (2021) Improved catalytic performance of CrOx catalysts supported on foamed Sn-modified alumina for propane dehydrogenation. Microporous Mesoporous Mater 311:110684. https://doi.org/10.1016/j.micromeso.2020.110684
Feng BH, Wei YC, Song WY, Xu CM (2022) A review on the structure-performance relationship of the catalysts during propane dehydrogenation reaction. Petrol Sci 19:819–838. https://doi.org/10.1016/j.petsci.2021.09.015
Li Q, Sui ZJ, Zhou XG, Zhu Y, Zhou JH, Chen D (2011) Coke formation on Pt–Sn/Al2O3 catalyst in propane dehydrogenation: coke characterization and kinetic study. Top Catal 54:888–896. https://doi.org/10.1007/s11244-011-9708-8
Kwon HC, Park Y, Park JY, Ryoo R, Shin H, Choi M (2021) Catalytic interplay of Ga, Pt, and Ce on the alumina surface enabling high activity, selectivity, and stability in propane dehydrogenation. ACS Catal 11:10767–10777. https://doi.org/10.1021/acscatal.1c02553
Xie LJ, Chai YC, Sun LL, Dai WL, Wu GJ, Guan NJ, Li LD (2021) Optimizing zeolite stabilized Pt–Zn catalysts for propane dehydrogenation. J Eng Chem 57:92–98. https://doi.org/10.1016/j.jechem.2020.08.058
Fan XQ, Li JM, Zhao Z, Wei YC, Liu J, Duan AJ, Jiang GY (2015) Dehydrogenation of propane over PtSnAl/SBA-15 catalysts: Al addition effect and coke formation analysis. Catal Sci Technol 5:339–350. https://doi.org/10.1039/C4CY00951G
Chen C, Sun ML, Hu ZP, Ren JT, Zhang SM, Yuan ZY (2019) New insight into the enhanced catalytic performance of ZnPt/HZSM-5 catalysts for direct dehydrogenation of propane to propylene. Catal Sci Technol 9:1979–1988. https://doi.org/10.1039/C9CY00237E
Acknowledgements
We gratefully acknowledge the financial support from the Fundamental Research Funds for the Central Universities (No. JKA01221712).
Author information
Authors and Affiliations
Contributions
HF: Conceptualization, Methodology, Investigation, Writing—original draft, Visualization. HZ: Writing—review & editing, Supervision, Funding acquisition. HM: Resources, Funding acquisition. WQ: Funding acquisition. WY: Writing—review & editing, Supervision, Funding acquisition.
Corresponding author
Ethics declarations
Conflicts of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Fu, H., Zhang, H., Ma, H. et al. Strontium Promoted PtSn/Al2O3 Catalysts for Propane Dehydrogenation to Propylene. Catal Lett (2024). https://doi.org/10.1007/s10562-024-04619-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10562-024-04619-9