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Synthesis of Mo-Based/Carbon Nanocomposistes for Water Decontamination via Percarbonate Activation

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Abstract

Sodium percarbonate (SPC) is recently developed as the most promising alternative for liquid H2O2 on the sewage treatment, because of its excellent explosion-resistance, high stability and safety. Herein, we first designed and synthesized a series of Mo-based/carbon nanocomposites (MoCNs) with core–shell and nanorod structures, derived from metal organic frameworks, for activating percarbonate in the efficient removal of tetracycline. The detailed characterizations confirmed MoCN-600 (a mixture of MoO3, MoC and MoO2) exhibited a nanorod structure with outer Zn and Co co-doped carbon layer. MoCN-600/SPC system exhibited a strong anti-interference ability for common anions and organic matter in TC degradation. Quenching tests and EPR results demonstrated that ·CO3− was the dominating reactive oxygen species in MoCN-600/SPC system. Compared with H2O2, MoCN-600/SPC system presented the excellent catalytic performance in TC degradation at a wider pH range. This work not only provides an efficient method for the synthesis of Mo-based heterogeneous catalysts, but also offers an excellent catalytic system for antibiotics removal.

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Acknowledgements

Financial support from the NSFC (Nos.21972073, 22136003, 21805166 and 22206188), the 111 Project of China (No. D20015) and Natural Science Foundation of Hubei Province, China (No. 2022CFB275) is gratefully acknowledged and thanks eceshi (http://www.eceshi.com) for the ICP test and Yuan Zhou from Shiyanjia Lab (http://www.shiyanjia.com) for EPR test.

Funding

Funding was provided by Data Center of Management Science, National Natural Science Foundation of China - Peking University (Grant Number: 21805166).

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Authors and Affiliations

  1. Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region of Ministry of Education, College of Materials and Chemical Engineering, China Three Gorges University, Yichang, 443002, Hubei, China

    Kun Pang, Chen Fang, Yingping Huang, Di Huang & Xiang Liu

  2. Department of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, China

    Yanlan Wang

  3. College of Hydraulic and Environmental Engineering, China Three Gorges University, Yichang, 443002, Hubei, China

    Yingping Huang

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  1. Kun Pang
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  2. Chen Fang
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  3. Yanlan Wang
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  4. Yingping Huang
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  5. Di Huang
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  6. Xiang Liu
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Pang, K., Fang, C., Wang, Y. et al. Synthesis of Mo-Based/Carbon Nanocomposistes for Water Decontamination via Percarbonate Activation. Catal Lett 154, 2999–3008 (2024). https://doi.org/10.1007/s10562-023-04517-6

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