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Chemical Kinetics of Serial Processes for Photogenerated Charges at Semiconductor Surface: A Classical Theoretical Calculation

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Abstract

The slow charge reactions at the semiconductor surface severely encumber the photocatalysis applications, which are elusive and complicated in a serial charge excitation-separation-reaction process. Both experimental and theoretical studies are essential in this area. Here, a classical numerical calculation of the charge reaction microkinetic is developed based on a simple consecutive charge separation and reaction model, a conservation law of photogenerated charges, and differential analysis. Several reaction conditions have been discussed to elucidate how a fast charge separation and reaction rate constant influence the apparent reaction kinetics. It is shown that a slower charge separation rate strongly limits the detection of higher-order reaction rates, and higher-order kinetics can be detected with all other processes faster than the reactions. This numerical calculation projects the possible limitations of kinetics study by transient techniques.

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Data Availability

The datasets generated during and/or analysed during the current study are not publicly available due financial support, but are available from the corresponding author on reasonable request.

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Acknowledgements

The fund for the research is obtained from the National Natural Science Foundation of China (Project. No. 22008163), the projects (20KJB150042 and 21KJB150038) from Natural Science Research Project of Higher Education Institutions in Jiangsu Province, the projects from Natural Science Foundation of Jiangsu Province (BK20210867 and BK20180103) and the University Startup. We thank Mr. Guangming Cao and Xinwei Wang for checking the equations.

Funding

Natural Science Foundation of Jiangsu Province, BK20180103, BK20210867, Natural Science Research Project of Higher Education Institutions in Jiangsu Province, 20KJB150042, 21KJB150038, National Natural Science Foundation of China, 22008163

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Authors and Affiliations

  1. Institute of Materials Science and Devices, School of Materials Science and Engineering, Suzhou University of Science and Technology, 1 Kerui Road, Suzhou, 215011, China

    Zhiyuan Deng, Yinying Shu, Meiying Gong, Jundie Hu, Jiafu Qu & Xiaogang Yang

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  1. Zhiyuan Deng
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  2. Yinying Shu
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Deng, Z., Shu, Y., Gong, M. et al. Chemical Kinetics of Serial Processes for Photogenerated Charges at Semiconductor Surface: A Classical Theoretical Calculation. Catal Lett 153, 3750–3760 (2023). https://doi.org/10.1007/s10562-022-04267-x

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