Abstract
We here report the synthesis, characterization, and catalytic performance of new supported Pd(0) catalysts. The catalysts were characterized by SEM, TEM, XRD, FT-IR, VSM, XPS, TG and AAS. The results showed that the catalyst exhibited good catalytic activity in the reaction of degradation of 4-NP and organic dyes MO and MB in water with NaBH4 and amino borane (AB) as the hydrogen sources. At the same time, the catalyst has good recoverability and is easily recovered and recycled from the reaction mixture by applying an external magnet and reusing it in five cycles without significant loss in activity.
Graphical Abstract
In the present work, our deliberately designed experiments demonstrate that Ni@Pd immobilized on the surface of hollow Fe3O4@PPy-Gly (HFPG) under mild condition. It exhibits high activity for the reduction of 4-NP and organic dyes by NaBH4 and AB.
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Zhao, Y., Wang, P., Hong, X. et al. Ni@Pd Core–Shell Nanoparticles with Tunable Comosition Supported on Glycine-Functionalized Hollow Fe3O4@PPy for Tandem Degradation Reduction of 4-Nitrophenol and Toxic Organic Dyes by Hydrogen Generation via Hydrolysis of NaBH4 and NH3BH3. Catal Lett 153, 3591–3604 (2023). https://doi.org/10.1007/s10562-022-04242-6
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DOI: https://doi.org/10.1007/s10562-022-04242-6