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Enhanced Benzene Oxidation of Sintered Pd/γ-Al2O3 Catalysts by SO2 Treatment

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Abstract

The effect of sulfurization by SO2 on the activity of Pd/γ-Al2O3 for benzene oxidation was investigated. The activity decreased by heat treatment at 800 °C due to Pd particle coarsening. SO2 treatment at 600 °C suppressed the formation of byproduct compounds on the catalyst and improved the activity of the sintered Pd/γ-Al2O3 catalyst.

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Acknowledgements

This work was financially supported by JST A-STEP program (JPMJTR20TE), JST SICORP program (JPMJSC18H3), and JSPS KAKENHI Grant Number 21H03635. X-ray absorption fine structure (XAFS) measurements were performed at SAGA-LS BL 07 (Proposal numbers: 1907058R, 2007068F).

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Authors and Affiliations

  1. Department of Molecular and Material Sciences, Graduate School of Engineering Sciences, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka, 816-8580, Japan

    Saki Shigenobu

  2. Research Center for Synchrotron Light Application, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka, 816-8580, Japan

    Takeharu Sugiyama

  3. Department of Advanced Materials Science and Engineering, Faculty of Engineering Sciences, Kyushu University, 6-1, Kasugakoen, Kasuga, Fukuoka, 816-8580, Japan

    Hajime Hojo & Hisahiro Einaga

Authors
  1. Saki Shigenobu
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  2. Takeharu Sugiyama
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  3. Hajime Hojo
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  4. Hisahiro Einaga
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Correspondence to Hisahiro Einaga.

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Shigenobu, S., Sugiyama, T., Hojo, H. et al. Enhanced Benzene Oxidation of Sintered Pd/γ-Al2O3 Catalysts by SO2 Treatment. Catal Lett 153, 3423–3432 (2023). https://doi.org/10.1007/s10562-022-04233-7

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  • DOI: https://doi.org/10.1007/s10562-022-04233-7

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