Skip to main content
SpringerLink
Log in

Specifically Designed Metal Functional Group Doped Hydrophobic Zeolite for Acetone Removal with Low Temperature Catalytic Reaction

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Acetone is solvent widely used in laboratories and factories. Serious problems will occur when it is exposed to the environment. Therefore, a new design for a bimetallic metal functional group catalyst that can convert acetone into carbon dioxide and water within 250 °C was prepared, in order to effectively treat acetone and reduce the required energy. Hydrophobic Y type zeolite adsorption and low-temperature catalytic combustion were used to continuously treat acetone, and the effect of different operating parameters (including different metal loads, metal content, transformation temperature, pollutant concentration, and space velocity) on the efficiency of acetone treatment was discussed in this study. The isothermal adsorption model, kinetics, and thermodynamic model analysis were also used to establish the reaction mechanism, and to explore the factors affecting the catalyst reaction rate. The results show that the acetone conversion rate of 10-Fe1Mn1-USY reaches 90% at 400 ppm, 20,000 h−1 space velocity, and 227 °C. The kinetic behavior of the reaction between 10-Fe1Mn1-USY and acetone is more suited to the Power-rate Law model. Arrhenius equation analysis results show that the required activation energy for the reaction between 10-Fe1Mn1-USY and acetone is 70.2 kJ mol−1, and the collision frequency factor is 2.81 × 105 s−1. This reaction is an endothermic reaction, and the main reaction mechanism is surface metal oxidation.

Graphical Abstract

A new design for a bimetallic metal functional group catalyst that can convert acetone into carbon dioxide and water within 250 ℃ was prepared, in order to effectively treat acetone and reduce the required energy. Hydrophobic Y type zeolite adsorption and low-temperature catalytic combustion were used to continuously treat acetone, and the effect of different operating parameters on the efficiency of acetone treatment was discussed in this study. Result shown that the redox reaction between the adsorbed acetone and the active oxygen on the surface of the catalyst to generate CO2 and H2O.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. Zaitan H, Manero MH, Valdes H (2016) Application of high silica zeolite ZSM-5 in a hybrid treatment process based on sequential adsorption and ozonation for VOCs elimination. J Environ Sci 41:59–68

    Article  CAS  Google Scholar 

  2. Bhatia S, Abdullah AZ, Wong CT (2009) Adsorption of butyl acetate in air over silver-loaded Y and ZSM-5 Zeolites: Experimental and modelling studies. J Hazard Mater 163:73–81

    Article  CAS  PubMed  Google Scholar 

  3. Huang HF, Rong WJ, Gu YY, Chang RQ, Lu HF (2014) Study on the adsorption-desorption performance of ZSM-5 zeolite molecular sieves for VOCs. Acta Sci Circum 34:3144–3154

    CAS  Google Scholar 

  4. Altass HM, Ahmed SA, Salama RS, Moussa Z, Jassas RS, Alsantali RI, Al-Rooqi MM, Ibrahim AA, Khder MA, Morad M, Ahmed AI, Khder AS (2022) Low temperature CO oxidation over highly active gold nanoparticles supported on reduced graphene oxide@Mg-BTC nanocomposite. Catal Lett. https://doi.org/10.1007/s10562-022-04026-y

    Article  Google Scholar 

  5. Liu GZ, Tian YJ, Zhang BF, Wang L, Zhang XW (2019) Catalytic combustion of VOC on sandwich-structured Pt@ZSM-5 nanosheets prepared by controllable intercalation. J Hazard Mater 367:568–576

    Article  CAS  PubMed  Google Scholar 

  6. Jablonska M, Krol A, Kukulska-Zajac E, Taracha K, Girman V, Chmielarz L, Gora-Marek K (2015) Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration. Appl Catal BEnviron 166–167:353–365

    Article  Google Scholar 

  7. Zhao Q, Ge YL, Fu KX, Zheng YF, Liu QL, Song CF, Ji N, Ma DA (2019) Catalytic performance of the Pd/TiO2 modified with MnOx catalyst for acetone total oxidation. Appl Surf Sci 496:1–8

    Article  Google Scholar 

  8. Zhang Y, Wang L, Ma QQ, Wang N, Pan ZY (2022) Pd nanoparticles on SBA-15 containing F for 2-ethyl-anthraquinone hydrogenation: effects of hydrophobicity. Catal Lett 152:1495–1505

    Article  CAS  Google Scholar 

  9. Napruszewska BD, Michalik-Zym A, Dula R, Duraczynska D, Rojek W, Socha RP, Litynska-Dobrzynska L, Bahranowskic K, Serwicka EM (2019) VOCs combustion catalysts based on composites of exfoliated organo-laponite and multimetallic (Mn, Al, Zr, Ce) hydrotalcites prepared by inverse microemulsion. Catal Today 333:182–189

    Article  CAS  Google Scholar 

  10. Dai QG, Wu JY, Deng W, Hu JS, Wu QQ, Guo LM, Sun W, Zhan WC, Wang XY (2019) Comparative studies of P/CeO2 and Ru/CeO2 catalysts for catalytic combustion of dichloromethane: From effects of H2O to distribution of chlorinated by-products. Appl Catal B Environ 249:9–18

    Article  CAS  Google Scholar 

  11. Shah PM, Day AN, Davies TE, Morgan DJ, Taylor SH (2019) Mechanochemical preparation of ceria-zirconia catalysts for the total oxidation of propane and naphthalene volatile organic compounds. Appl Catal B Environ 253:331–340

    Article  CAS  Google Scholar 

  12. More RK, Lavande NR, More PM (2020) Mn supported on Ce substituted hydroxyapatite for VOC oxidation: catalytic activity and calcination effect. Catal Lett 150:419–428

    Article  CAS  Google Scholar 

  13. Zhao Q, Zheng YF, Song CF, Liu QL, Ji N, Ma DA, Lu XB (2020) Novel monolithic catalysts derived from in-situ decoration of Co3O4 and hierarchical Co3O4@MnOx on Ni foam for VOC oxidation. Appl Catal B Environ 265:1–12

    Article  Google Scholar 

  14. Milojevic-Rakic M, Dondur V, Damjanovic-Vasilic L, Rac V, Rakic V (2018) The accessibility of sites active in the dissociative adsorption of aromatic hydrocarbons in FeZSM-5 zeolite. React Kinet Mech Catal 123(1):231–246

    Article  CAS  Google Scholar 

  15. Qin L, Huang XM, Zhao B, Wang Y, Han J (2020) Iron oxide as a promoter for toluene catalytic oxidation over Fe–Mn/γ-Al2O3 catalysts. Catal Lett 150:802–814

    Article  CAS  Google Scholar 

  16. Piumetti M, Fino D, Russo N (2015) Mesoporous manganese oxides prepared by solution combustion synthesis as catalysts for the total oxidation of VOCs. Appl Catal B Environ 163:277–287

    Article  CAS  Google Scholar 

  17. Liu Y, Zhou H, Cao RR, Liu XY, Zhang PY, Zhan JJ, Liu LF (2019) Facile and green synthetic strategy of birnessite-type MnO2with high efficiency for airborne benzene removal at low temperatures. Appl Catal B Environ 245:569–582

    Article  CAS  Google Scholar 

  18. Sun YG, Zhang X, Li N, Xing X, Yang HL, Zhang FL, Cheng J, Zhang ZS, Hao ZP (2019) Surface properties enhanced MnxAlO oxide catalysts derived from MnxAl layered double hydroxides for acetone catalytic oxidation at low temperature. Appl Catal B Environ 251:295–304

    Article  CAS  Google Scholar 

  19. Dong YL, Zhao JY, Zhang JY, Chen Y, Yang XX, Song WN, Wei LG, Li W (2020) Synergy of Mn and Ni enhanced catalytic performance for toluene combustion over Ni-doped α-MnO2 catalysts. Chem Eng J 88:1–12

    Google Scholar 

  20. Hu CQ, Zhu QS, Jiang Z, Chen L, Wu RF (2009) Catalytic combustion of dilute acetone over Cu-doped ceria catalysts. Chem Eng J 152:583–590

    Article  CAS  Google Scholar 

  21. Liu FY, Zhang HP, Yan Y, Wang T (2020) Preparation and characterization of Cu and Mn modified beta zeolite membrane catalysts for toluene combustion. Mater Chem Phys 241(122322):1–9

    Article  Google Scholar 

  22. Peng Q, Hou D, Chen Y, Lin L, Sadeghzadeh SM (2022) Cu(II)-based ionic liquid supported on SBA-15 nanoparticles catalyst for the oxidation of various alcohols into carboxylic acids in the presence of CO2. Catal Lett 152:1308–1320

    Article  CAS  Google Scholar 

  23. Gao W, Zhao B, Fan X, Liu L, He B, Li Y, Li B (2022) Production of iso-octanoic acid via efficiently synergetic catalysis of Zn-modified ZSM-5/HMS. Catal Lett 152:1461–1475

    Article  CAS  Google Scholar 

  24. Qiu B, Zhang Y, Zhang Y (2022) A stable zinc zeolite catalyst for dehydrogenation of ethane to aromatics and ethylene. Catal Lett 152:1372–1385

    Article  CAS  Google Scholar 

  25. Li R, Chong SJ, Altaf N, Gao YS, Louis B, Wang Q (2019) Synthesis of ZSM-5/siliceous zeolite composites for improvement of hydrophobic adsorption of volatile organic compounds. Front Chem 7(505):1–10

    Google Scholar 

  26. Huang HW (2018) Study on treatment of HMDS and acetone in exhaust gas using porous composites. National Yilan University, Master thesis

  27. Zeng JL, Liu XL, Wang J, Lv HL, Zhu TY (2015) Catalytic oxidation of benzene over MnOx/TiO2 catalysts and the mechanism study. J Mol Catal A Chem 408:221–227

    Article  CAS  Google Scholar 

  28. Wang Y, Wang BD, Li JH, Zhu TL (2020) Study on the structure-activity relationship of Fe-Mn oxide catalysts for chlorobenzene catalytic combustion. Chem Eng J 395(125172):1–13

    Google Scholar 

  29. Zhao Q, Ge YL, Fu KX, Zheng YF, Liu QL, Song CF, Ji N, Ma DA (2019) Catalytic performance of the Pd/TiO2 modified with MnOx catalyst for acetone total oxidation. Appl Surf Sci 496(143579):1–8

    Google Scholar 

  30. Zhang Y, Zhang HP, Yan Y (2020) Catalytic combustion kinetic studies of trichloroethylene over Cr modified ZSM-5 zeolite membrane catalyst. Sep Purif Technol 1(116827):1–27

    Google Scholar 

Download references

Acknowledgements

The authors acknowledge financial supports form the Taiwan’s Ministry of Science and Technology (MOST 110-2622-E-197-006). First author acknowledges the Department of Environmental Engineering, National I–Lan University, Taiwan to support his research at the university.

Author information

Authors and Affiliations

  1. Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei, 10608, Taiwan

    Nhat-Thien Nguyen & Gui-Bing Hong

  2. Faculty of Environmental and Natural Sciences, Duy Tan University, Da Nang, 550000, Vietnam

    Thi-Minh-Phuong Nguyen

  3. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Vietnam

    Thi-Minh-Phuong Nguyen

  4. School of Chemical Engineering and Chemistry, Mapúa Institute of Technology, 1002, Manila, Philippines

    Alvin-R. Caparanga

  5. Department of Environmental Engineering, National I-Lan University, I-Lan, 26047, Taiwan

    Yi-Ren Chiu, Chung-Yu Guan & Chang-Tang Chang

  6. Southern Institute of Water Resources Research, Ho Chi Minh, 700000, Vietnam

    Cong-Chinh Duong

  7. Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology, Ho Chi Minh, 700000, Vietnam

    Thi-Thanh Duong

Authors
  1. Nhat-Thien Nguyen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Thi-Minh-Phuong Nguyen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Alvin-R. Caparanga
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yi-Ren Chiu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Cong-Chinh Duong
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Thi-Thanh Duong
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Chung-Yu Guan
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Gui-Bing Hong
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Chang-Tang Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Gui-Bing Hong or Chang-Tang Chang.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 1034 kb)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nguyen, NT., Nguyen, TMP., Caparanga, AR. et al. Specifically Designed Metal Functional Group Doped Hydrophobic Zeolite for Acetone Removal with Low Temperature Catalytic Reaction. Catal Lett 153, 3492–3503 (2023). https://doi.org/10.1007/s10562-022-04189-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-022-04189-8

Keywords

Search

Navigation