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Palladium-Decorated Covalent Organic Framework Supported on Zinc Ferrite as Magnetic Catalyst for Suzuki Reaction and p-nitrophenol Reduction

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Abstract

In this work, the synthesis of magnetic recyclable catalyst (ZnFe2O4@PDA/COF@Pd) based on palladium nanoparticles immobilized on covalent organic framework (COF) carrier and polydopamine as the linking agent for zinc ferrite (ZnFe2O4) and COF is presented. The morphology, element composition, and surface energies of the compounds were characterized. The prepared ZnFe2O4@PDA/COF@Pd exhibits excellent catalytic activity for Suzuki coupling reaction under mild conditions (TON = 4.7 × 104, TOF = 4.7 × 104 h−1). In addition, p-nitrophenol can be completely reduced within 2–9 min in the presence of NaBH4. Besides, it has remarkable promoting effect on the degradation of dyes. The above characterizations and results indicate that COF is an ideal platform for homogeneously and dispersedly immobilizing Pd NPs, which prohibit the aggregation and leaching of Pd NPs. More importantly, in the recovery of p-nitrophenol reduction reaction, the yield of p-aminophenol can still reach more than 97% after five successive cycles, demonstrating the favorable stability and durability of ZnFe2O4@PDA/COF@Pd.

Graphical Abstract

ZnFe2O4@PDA/COF@Pd showed high activity in dye degradation and Suzuki reactions. The Kapp value of ZnFe2O4@PDA/COF@Pd in the reduction of p-NP was 0.0276 s−1. Polydopamine as a linker between ZnFe2O4 and COF enhanced the stability of the catalyst structure, resulting in excellent recovery efficiency and recyclability.

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Acknowledgements

This work was sponsored by Fundamental Research Funds for the Central Universities (N2105005), Scientific Research Fund project of Ningde Normal University (2020Z02)and Fujian Provincial Key Laboratory of Featured Biochemical and Chemical Materials, Ningde Normal University.

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Authors and Affiliations

  1. Center for Molecular Science and Engineering, College of Science, Northeastern University, Shenyang, 110819, People’s Republic of China

    Kexin Lv, Gongshu Wang, Zhangpei Chen & Jianshe Hu

  2. Fujian Provincial Key Laboratory of Featured Biochemical and Chemical Materials, Ningde Normal University, Ningde, Fujian, 352100, People’s Republic of China

    Kexin Lv, Guiyang Yan & Jianshe Hu

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  1. Kexin Lv
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  2. Guiyang Yan
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  3. Gongshu Wang
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Correspondence to Guiyang Yan or Jianshe Hu.

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Lv, K., Yan, G., Wang, G. et al. Palladium-Decorated Covalent Organic Framework Supported on Zinc Ferrite as Magnetic Catalyst for Suzuki Reaction and p-nitrophenol Reduction. Catal Lett 153, 2959–2974 (2023). https://doi.org/10.1007/s10562-022-04113-0

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