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Encapsulation of Sandwich POM in MIL-101 as Efficient Oxidative Desulfurization Catalyst of DBT

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Abstract

This study shows the successful encapsulation of sandwich cobalt–tungsten polyoxomolybdate (Na12[WCo3(H2O)2(CoW9O34)2], abbreviated as CoWPOM) guest in mesoporous metal–organic framework MIL-101 host under static condition via a facile post-synthesis strategy. Several characterizations including powder XRD, FTIR, TGA, SEM–EDS, UV–vis DRS, XRF, and low temperature N2 adsorption–desorption isotherm demonstrate the incorporation and homogenous-distribution of the sandwich CoWPOM guests in cavities of the MIL-101 host. The CoWPOM@MIL-101 composite possesses a better synergistic effect, and it demonstrates an excellent oxidative desulfurization catalytic activity with the DBT removal of 98.1% and recyclability at least 5 times without obvious activity decrease.

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Acknowledgements

The study was funded by National Natural Science Foundation of China (Grant Nos. 22078227, 22108145), State Key Laboratory of Heavy Oil Processing (Grant No. SKLOP201902005), Qing Lan Project of Jiangsu Province, Natural Science Foundation of Jiangsu Province (Grant No. BK20210144), Natural Science Foundation of Shandong Province (Grant No. ZR2020QB189), Science and Technology Support Program (Social Development) of Taizhou (Grant No. SSF20210021), Research Foundation for Talented Scholars of Taizhou University (Grant Nos. QD2016007, QD2016012) and Undergraduate Training Program for Innovation and Entrepreneurship of Jiangsu Province (202112917039Y).

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Author notes

  1. Jilei Liang and Mengmeng Wu have contributed equally to this work.

Authors and Affiliations

  1. Jiangsu Key Laboratory of Chiral Pharmaceuticals Biosynthesis, College of Pharmacy and Chemistry and Chemical Engineering, Taizhou University, Taizhou, 225300, People’s Republic of China

    Jilei Liang, Mengwei Fan, Wenjie Wu, Mengmeng Wu, Wangshui Cai, Gao Xinxing & Haiyun Rui

  2. State Key Laboratory Base for, Eco-Chemical Engineering in College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, People’s Republic of China

    Tingting Huang

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  1. Jilei Liang
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Correspondence to Jilei Liang.

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Liang, J., Fan, M., Wu, W. et al. Encapsulation of Sandwich POM in MIL-101 as Efficient Oxidative Desulfurization Catalyst of DBT. Catal Lett 153, 1159–1169 (2023). https://doi.org/10.1007/s10562-022-04057-5

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