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Synthesis and Study of Catalytic Perspectives of DABCO Based Ionic Liquid for the Synthesis of 2,3-Dihydro-1,5-Benzothiazepines and 2-Phenylbenzothiazoles

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Abstract

In this study, a novel DABCO based dicationic acidic ionic liquid [C4H10-DABCO][HSO4]2 has been synthesized, characterized, and applied successfully as an eco-friendly and reusable catalyst in the synthesis of 2,3-dihydro-1,5-benzothiazepine and 2-phenylbenzothiazole derivatives. This work shows the impact of cations and anions on the catalytic applicability and moisture-resistance properties of DABCO based ionic liquids through the comparison of [H2-DABCO][HSO4]2, [H2-DABCO][H2PO4]2, [H2-DABCO][ClO4]2, and [C4H10-DABCO][HSO4]2. The proposed method displayed several advantages over prior methods, including use of non-metal and inexpensive catalyst, shorter reaction times, green solvent media, moderate to excellent product yields, easy work-up, and recyclability of the ionic liquid for subsequent reactions without a considerable reduction in activity.

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Acknowledgements

The author is pleased to acknowledge the Department of Science & Technology (DST) New Delhi for the award of Junior Research Fellowship (JRF) and Senior Research fellowship (SRF) [Grant No: DST/INSPIRE Fellowship/IF160600] for the research work.

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  1. School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, Maharashtra, 431606, India

    Priyanka Pinate & Sangita Makone

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Pinate, P., Makone, S. Synthesis and Study of Catalytic Perspectives of DABCO Based Ionic Liquid for the Synthesis of 2,3-Dihydro-1,5-Benzothiazepines and 2-Phenylbenzothiazoles. Catal Lett 153, 995–1012 (2023). https://doi.org/10.1007/s10562-022-04033-z

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