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Ruthenium Nanocatalysts Immobilized on DFNS-IL Heterogeneous Catalyst for Hydroformylation of Alkenes with CO2 and H2

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Abstract

The current study reports the synthesis of multi-site ionic liquids immobilized on DFNS (DFNS-IL) in an aqueous medium. Hence, the ruthenium nanoparticles (NPs) are well-dispersed over the DFNS-IL (DFNS-IL@Ru). Its catalytic function for hydroformylation of alkenes using CO2/H2 as a syngas surrogate is described here under mild conditions. Resultants with good to excellent performance were created employing DFNS-IL@Ru nanocatalyst. The structure of the catalyst was specified by a variety of techniques, including FT-IR, XRD, SEM, TGA, AFM, XPS, TEM, and EDX. The stability of the catalytic system was enhanced after releasing a large quantity of DFNS. The recycling state of the catalyst and the procedure of the coupling reactions were repeatedly investigated.

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Acknowledgements

This work was sponsored in part by Key research and development project of Lvliang city in 2019 (Key technology and mechanism of PI monomer, GXZDYF2019085)

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Authors and Affiliations

  1. Department of Mining Engineering, Lvliang University, Lüliang, 033001, Shanxi, China

    Yinyan Li

  2. Energy Information Dispatching Center of Lvliang City, Lüliang, 033001, Shanxi, China

    Shen Song

  3. Department of Chemistry, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    Seyed Mohsen Sadeghzadeh

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  1. Yinyan Li
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  2. Shen Song
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  3. Seyed Mohsen Sadeghzadeh
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Correspondence to Yinyan Li or Seyed Mohsen Sadeghzadeh.

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Li, Y., Song, S. & Sadeghzadeh, S.M. Ruthenium Nanocatalysts Immobilized on DFNS-IL Heterogeneous Catalyst for Hydroformylation of Alkenes with CO2 and H2. Catal Lett 153, 95–103 (2023). https://doi.org/10.1007/s10562-022-03968-7

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  • DOI: https://doi.org/10.1007/s10562-022-03968-7

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