Abstract
This paper describes the specific features of the formation of an unsupported nickel-tungsten sulfide nanosize catalyst in situ in a hydrocarbon feedstock from oil-soluble precursors—nickel and tungsten compounds in the presence of elemental sulfur additive. The catalysts formed at different times of the catalytic experiment (2, 5, 7 and 10 h) were analyzed by transmission electron microscopy and X-ray photoelectron spectroscopy. According to STEM-EDX elemental spectra, the formation of tungsten and nickel sulfides was established, with a further increase in the amount of active Ni-W-S phase on the surface of the crystalline nickel sulfide. It was found that the time of catalyst formation affects its morphology and phase composition. Evaluation of the hydrogenating catalytic activity confirms that an increase in the time of catalyst formation leads to an increase in its activity, which is associated with the peculiarities of the morphology of sulfide particle aggregates as well as an increase in the degree of promotion of tungsten disulfide crystallites by nickel atoms.
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Alonso-Ramírez G, Cuevas-García R, Sánchez-Minero F, Ramírez J, Moreno-Montiel M, Silva-Oliver G, Ancheyta J, Carbajal-Vielman R (2021) Catalytic hydrocracking of a Mexican heavy oil on a MoS2/al2o3catalyst: II. Study of the transformation of isolated aromatics fraction obtained from SARA analysis. Fuel 288:119541. https://doi.org/10.1016/j.fuel.2020.119541
Morel F, Kressmann S, Harlé V, Kasztelan S (1997) Processes and catalysts for hydrocracking of heavy oil and residues. In: Froment GF, Delmon B, Grange P (eds) Studies in surface science and catalysis, vol 106. Elsevier, Amsterdam, pp 1–16. https://doi.org/10.1016/S0167-2991(97)80003-1
Kang KH, Nguyen NT, Seo PW, Seo H, Kim GT, Kang N, Lee CW, Han SJ, Chung M-C, Park S (2020) Slurry-phase hydrocracking of heavy oil over Mo precursors: effect of triphenylphosphine ligands. J Catal 384:106–121. https://doi.org/10.1016/j.jcat.2020.02.007
Kuchinskaya T, Kniazeva M, Samoilov V, Maximov A (2020) In situ generated nanosized sulfide Ni-W catalysts based on zeolite for the hydrocracking of the pyrolysis fuel oil into the BTX fraction. Open Access 10(10):1152
Villasana Y, Méndez FJ, Luis-Luis M, Brito JL (2019) Pollutant reduction and catalytic upgrading of a Venezuelan extra-heavy crude oil with Al2O3-supported NiW catalysts: effect of carburization, nitridation and sulfurization. Fuel 235:577–588. https://doi.org/10.1016/j.fuel.2018.08.047
Shan S, Yuan P, Han W, Shi G, Bao X (2015) Supported NiW catalysts with tunable size and morphology of active phases for highly selective hydrodesulfurization of fluid catalytic cracking naphtha. J Catal 330:288–301. https://doi.org/10.1016/j.jcat.2015.06.019
Chianelli RR, Berhault G, Torres B (2009) Unsupported transition metal sulfide catalysts: 100 years of science and application. Catal Today 147(3):275–286. https://doi.org/10.1016/j.cattod.2008.09.041
Le Z, Afanasiev P, Li D, Long X, Vrinat M (2008) Solution synthesis of the unsupported Ni–W sulfide hydrotreating catalysts. Catal Today 130(1):24–31. https://doi.org/10.1016/j.cattod.2007.07.002
Alkhaldi S, Husein MM (2014) Hydrocracking of heavy oil by means of in situ prepared ultradispersed nickel nanocatalyst. Energy Fuels 28(1):643–649. https://doi.org/10.1021/ef401751s
Hur YG, Lee D-W, Lee K-Y (2016) Hydrocracking of vacuum residue using NiWS(x) dispersed catalysts. Fuel 185:794–803. https://doi.org/10.1016/j.fuel.2016.08.027
Guisnet M, Gilson J-P (2005) Zeolites for cleaner technologies. Imperial College Press, London
Eijsbouts S, Mayo SW, Fujita K (2007) Unsupported transition metal sulfide catalysts: from fundamentals to industrial application. Appl Catal A 322:58–66. https://doi.org/10.1016/j.apcata.2007.01.008
Besenbacher F, Brorson M, Clausen BS, Helveg S, Hinnemann B, Kibsgaard J, Lauritsen JV, Moses PG, Nørskov JK, Topsøe H (2008) Recent STM, DFT and HAADF-STEM studies of sulfide-based hydrotreating catalysts: Insight into mechanistic, structural and particle size effects. Catal Today 130(1):86–96. https://doi.org/10.1016/j.cattod.2007.08.009
Lacroix M, Vrinat M, Breysse M (1986) Unsupported nickel tungsten sulfide catalysts: Part 1: catalytic behaviour in hydrogenation and hydrodesulfurization reactions. Appl Catal 21(1):73–83. https://doi.org/10.1016/S0166-9834(00)81329-9
Zheng P, Li T, Chi K, Xiao C, Fan J, Wang X, Duan A (2019) DFT insights into the formation of sulfur vacancies over corner/edge site of Co/Ni-promoted MoS2 and WS2 under the hydrodesulfurization conditions. Appl Catal B 257:117937. https://doi.org/10.1016/j.apcatb.2019.117937
Topsøe H, Clausen BS, Candia R, Wivel C, Mørup S (1981) In situ Mössbauer emission spectroscopy studies of unsupported and supported sulfided CoMo hydrodesulfurization catalysts: evidence for and nature of a CoMoS phase. J Catal 68(2):433–452. https://doi.org/10.1016/0021-9517(81)90114-7
Topsøe H (2007) The role of Co–Mo–S type structures in hydrotreating catalysts. Appl Catal A 322:3–8. https://doi.org/10.1016/j.apcata.2007.01.002
Spojakina A, Palcheva R, Jiratova K, Tyuliev G, Petrov L (2005) Synergism between Ni and W in the Niw/ γ-Al2O3 hydrotreating catalysts. Catal Lett 104(1):45–52. https://doi.org/10.1007/s10562-005-7434-1
Van Der Meer Y, Vissenberg MJ, De Beer VHJ, Van Veen JAR, Van Der Kraan AM (2002) Characterization of carbon- and alumina-supported NiW and CoW sulfided catalysts. In: Cook DC, Hoy GR (eds) Industrial applications of the Mössbauer effect. Springer, Dordrecht, pp 51–57
Hensen EJM, van der Meer Y, van Veen JAR, Niemantsverdriet JW (2007) Insight into the formation of the active phases in supported NiW hydrotreating catalysts. Appl Catal A 322:16–32. https://doi.org/10.1016/j.apcata.2007.01.003
Zhang L, Afanasiev P, Li D, Long X, Vrinat M (2007) Solution synthesis of unsupported Ni–W–S hydrotreating catalysts. Catal Commun 8(12):2232–2237. https://doi.org/10.1016/j.catcom.2007.05.001
Vutolkina AV, Baygildin IG, Glotov AP, Cherednichenko KA, Maksimov AL, Karakhanov EA (2021) Dispersed Ni-Mo sulfide catalysts from water-soluble precursors for HDS of BT and DBT via in situ produced H2 under Water gas shift conditions. Appl Catal B 282:119616. https://doi.org/10.1016/j.apcatb.2020.119616
Le Z, Afanasiev P, Li D, Shi Y, Vrinat M (2008) Synthesis of unsupported Ni–W–S hydrotreating catalysts from the oxothiosalt (NH4)2WO2S2. C R Chim 11(1):130–136. https://doi.org/10.1016/j.crci.2007.04.012
Zuo D, Vrinat M, Nie H, Maugé F, Shi Y, Lacroix M, Li D (2004) The formation of the active phases in sulfided NiW/Al2O3 catalysts and their evolution during post-reduction treatment. Catal Today 93–95:751–760. https://doi.org/10.1016/j.cattod.2004.06.078
Eijsbouts S, Li X, Bergwerff J, Louwen J, Woning L, Loos J (2017) Nickel sulfide crystals in Ni-Mo and Ni-W catalysts: eye-catching inactive feature or an active phase in its own right? Catal Today 292:38–50. https://doi.org/10.1016/j.cattod.2016.08.028
Olivas A, Avalos M, Fuentes S (2000) Evolution of crystalline phases in nickel–tungsten sulfide catalysts. Mater Lett 43(1):1–5. https://doi.org/10.1016/S0167-577X(99)00218-9
Kasztelan S, Toulhoat H, Grimblot J, Bonnelle JP (1984) A geometrical model of the active phase of hydrotreating catalysts. Appl Catal 13(1):127–159. https://doi.org/10.1016/S0166-9834(00)83333-3
Hassanzadeh H, Abedi J (2010) Modelling and parameter estimation of ultra-dispersed in situ catalytic upgrading experiments in a batch reactor. Fuel 89(10):2822–2828. https://doi.org/10.1016/j.fuel.2010.02.012
Daage M, Chianelli RR (1994) Structure-function relations in molybdenum sulfide catalysts: the “Rim-Edge” model. J Catal 149(2):414–427. https://doi.org/10.1006/jcat.1994.1308
Stanislaus A, Cooper BH (1994) Aromatic hydrogenation catalysis: a review. Catal Rev 36(1):75–123. https://doi.org/10.1080/01614949408013921
Woolfolk LG, Geantet C, Massin L, Laurenti D, De los Reyes JA (2017) Solvent effect over the promoter addition for a supported NiWS hydrotreating catalyst. Appl Catal B 201:331–338. https://doi.org/10.1016/j.apcatb.2016.07.052
Díaz de León JN, Picquart M, Massin L, Vrinat M, de los Reyes JA (2012) Hydrodesulfurization of sulfur refractory compounds: effect of gallium as an additive in NiWS/γ-Al2O3 catalysts. J Mol Catal A: Chem 363–364:311–321. https://doi.org/10.1016/j.molcata.2012.07.006
Breysse M, Cattenot M, Decamp T, Frety R, Gachet C, Lacroix M, Leclercq C, de Mourgues L, Portefaix JL, Vrinat M, Houari M, Grimblot J, Kasztelan S, Bonnelle JP, Housni S, Bachelier J, Duchet JC (1988) Influence of sulphidation conditions on the properties of NiW/Al2O3 hydrotreating catalysts. Catal Today 4(1):39–55. https://doi.org/10.1016/0920-5861(88)87045-7
Rodríguez-Castellón E, Jiménez-López A, Eliche-Quesada D (2008) Nickel and cobalt promoted tungsten and molybdenum sulfide mesoporous catalysts for hydrodesulfurization. Fuel 87(7):1195–1206. https://doi.org/10.1016/j.fuel.2007.07.020
Pawelec B, Mariscal R, Fierro JLG, Greenwood A, Vasudevan PT (2001) Carbon-supported tungsten and nickel catalysts for hydrodesulfurization and hydrogenation reactions. Appl Catal A 206(2):295–307. https://doi.org/10.1016/S0926-860X(00)00605-0
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This study was performed within the framework of the State Assignment of the Institute of Petrochemical Synthesis of the Russian Academy of Sciences.
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TSK: Supervision, Project administration, Conceptualization, Investigation, Methodology, Writing—review & editing, Writing-original draft, Visualization., MIK: Conceptualization, Writing -original draft, Writing—review & editing, ALM: Supervision, Conceptualization.
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Kuchinskaya, T.S., Knyazeva, M.I. & Maximov, A.L. Specific Features of the In Situ Formation of an Unsupported NiWS Nanosize Catalyst from Oil-Soluble Precursors. Catal Lett 153, 198–207 (2023). https://doi.org/10.1007/s10562-022-03966-9
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DOI: https://doi.org/10.1007/s10562-022-03966-9