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The Fabrication of PMo11Fe Cluster Supporting on SBA-15 and Catalytic Epoxidation of Cyclooctene with H2O2 as Oxidant

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Abstract

The transition metal iron substituted polyoxometalates cluster (PMo11Fe) was immobilized on NH2 functionalized SBA-15 with the post-modified method, the resulting composite materials, abbreviated as PMo11Fe/SBA. Multiple characteristic methods including X-ray powder diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy were used to characterize the composite PMo11Fe/SBA, it is concluded that PMo11Fe cluster was supported on the NH2 functionalized SBA-15, and the Keggin structure of PMo11Fe cluster kept retained during the immobilized process. The cyclooctene epoxidation results with H2O2 as the oxidant demonstrated that PMo11Fe/SBA performed better catalytic activities and recyclability, the conversion of cyclooctene kept about 50% after several recycled reactions. The superior recyclability of PMo11Fe/SBA could be attributed to the multiple electrostatic and coordinative interactions between PMo11Fe clusters and functionalities –NH2 located at the 3D pore wall of SBA-15. Besides, the catalytic activities and stability could be improved through the partial substitute of transition metal Fe instead of Mo atom in phosphomolybdic acids clusters.

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Acknowledgements

This work was supported by the Foundation of Liaoning Key Laboratory of Chemical Additive Synthesis and Separation (ZJNK2104), Regional Innovation Joint Fund of Liaoning Province (2020-YKLH-36), Excellent Talents of Science and Technology in Yingkou Institute of Technology (RC201805), Basic Scientific Research Project of Liaoning Provincial Department of Education (LJKQZ2021183).

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Authors and Affiliations

  1. Liaoning Key Laboratory of Chemical Additive Synthesis and Separation, Yingkou Institute of Technology, Yingkou, 115014, China

    Xiaolu Chen, Yue Yu, Hong Chen, Xiao Wu & Shuang Gao

  2. CenerTech Tianjin Chemical Research and Design Institute Co. Ltd., CNOOC, Tianjin, 300131, China

    Jing Wang

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  1. Xiaolu Chen
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  2. Jing Wang
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  3. Yue Yu
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Correspondence to Shuang Gao.

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Chen, X., Wang, J., Yu, Y. et al. The Fabrication of PMo11Fe Cluster Supporting on SBA-15 and Catalytic Epoxidation of Cyclooctene with H2O2 as Oxidant. Catal Lett 152, 3807–3813 (2022). https://doi.org/10.1007/s10562-022-03950-3

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