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Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran

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Abstract

A series of hydroxyapatite (HAP) supports with different Ca/P ratios were synthesized to prepare the MnOx/HAP catalysts. A MnOx/HAP catalyst showed highly efficient conversion of 5-hydroxymethylfurfural (HMF) into 2, 5-diformylfuran (DFF) in toluene solvent under no-alkali condition. 86.4% conversion of HMF with 90.9% selectivity of DFF at 120 °C for 12 h under 1.0 MPa O2 over the MnOx/HAP-10.0-400 were obtained. The redox of Mn4+/Mn3+ improved the oxidation of 5-HMF to DFF by the lattice oxygen, and the lattice oxygen was replenished by adsorbing O2 molecules. The reusability tests were found the catalyst could be reused up to four cycles without notable loss of catalytic activity. The MnOx/HAP-10.0-400 was a stable and reusable material for further industrial exploration of DFF in an environmentally friendly way.

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Acknowledgements

The research was supported by the Natural Science Foundation of China (21808163 and 21690083).

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Authors and Affiliations

  1. School of Environmental Science and Engineering, Tianjin University, Tianjin, 300072, China

    Hong Chen, Yingying Li, Sen Wang, Xueli Ma & Can Wang

  2. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China

    Linhao Yu & Yongdan Li

  3. Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, 02150, Espoo, Finland

    Yongdan Li

Authors
  1. Hong Chen
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  2. Yingying Li
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  3. Linhao Yu
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  4. Sen Wang
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  5. Xueli Ma
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  6. Can Wang
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  7. Yongdan Li
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Contributions

HC: supervision, conceptualization, writing—review & editing. YL: methodology, investigation, writing—original draft. LY: conceptualization, writing—review & editing. SW: formal analysis, soft-ware. XM: software, visualization. CW: writing—review & editing. YL: writing—review & editing.

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Correspondence to Hong Chen.

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Chen, H., Li, Y., Yu, L. et al. Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran. Catal Lett 152, 3716–3724 (2022). https://doi.org/10.1007/s10562-022-03945-0

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