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The Novel Monolithic Pr1-xCexCo0.5Mn0.5O3 Oxides Catalysts for the Selective Catalytic Reduction of NOx by NH3

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Abstract

Efficient monolithic catalyst for NH3 selective catalytic reduction is of great significance for the purification of NOx from coal mine diesel vehicles. In this study, a series of Pr1-xCexCo0.5Mn0.5O3 catalysts were prepared by a simple and convenient glucose complexation method with elements Pr, Ce, Mn and Co for the selective catalytic reduction of NOx by NH3 (NH3-SCR). The Pr1-xCexCo0.5Mn0.5O3 catalysts were studied by XRD, SEM, FT-IR and H2-TPR characterization experiments, the results showed that Pr0.8Ce0.2Co0.5Mn0.5O3 catalyst had porous structure and excellent low temperature redox performance. Moreover, Pr0.8Ce0.2Co0.5Mn0.5O3 catalyst was identified as the most active catalyst, on which the conversion could reach 90% at 400 °C. Then, this catalyst was loaded on cordierite honeycomb ceramic support by impregnation method. NOx conversion of monolithic catalyst supported on cordierite honeycomb ceramic could reach 95% at 350 °C. By simulating the adsorption capacity of cordierite honeycomb ceramic carrier for NO, it can be seen that cordierite honeycomb ceramic carrier has good adsorption effect for NO. It provided research ideas for the development and practical application of industrial monolithic catalyst for NH3-SCR.

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Acknowledgements

This work has been funded by the National Natural Science Foundation of China (Nos. 51874191 and 52174191), the National Key R&D Program of China (2017YFC0805201), Qingchuang Science and Technology Project of Shandong Province University (2020KJD002), Taishan scholars project special funding (TS20190935).

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Authors and Affiliations

  1. College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, Shandong Province, China

    Wen Nie, Weiwei Zhou, Na Li, Jiayi Yan, Yun Hua, Qiu Bao, Fengning Yu & Wenjin Niu

  2. College of Energy and Mining Engineering, Shandong University of Science and Technology, Qingdao, 266590, Shandong Province, China

    Mingyue Yuan

  3. State Key Laboratory of Mining Disaster Prevention and Control Co-Found By Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology, Qingdao, 266590, China

    Wen Nie, Weiwei Zhou, Na Li, Mingyue Yuan, Jiayi Yan, Yun Hua, Qiu Bao, Fengning Yu & Wenjin Niu

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  1. Wen Nie
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Nie, W., Zhou, W., Li, N. et al. The Novel Monolithic Pr1-xCexCo0.5Mn0.5O3 Oxides Catalysts for the Selective Catalytic Reduction of NOx by NH3. Catal Lett 152, 3642–3654 (2022). https://doi.org/10.1007/s10562-022-03922-7

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