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Phosphine-Functionalized Chitosan Microparticles as Support Materials for Palladium Nanoparticles in Heck Reactions

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Abstract

Herein, we investigated the activation and stabilization of Pd nanoparticles using microparticles of chitosan-functionalized with phosphine moieties. The catalytic activity of the prepared material was assessed in a series of Heck reactions, which demonstrated the potential of our catalyst concerning yields and reaction scope. Comparative experiments confirmed the superior performance of the phosphine-modified material with respect to a similar catalyst derived from non-functionalized chitosan. Finally, the prepared catalyst also exhibited appreciable activity even after four consecutive reaction runs, with minimal loss of Pd by leaching.

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Acknowledgements

The authors are thankful to CNPq (Process 404744/2018-4). A.R.F. also thanks CNPq for his PQ fellowship (Process 303872/2019-5). This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Brazil (CAPES/Proap), Finance Code 001.

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Authors and Affiliations

  1. Laboratório de Tecnologia e Desenvolvimento de Compósitos e Materiais Poliméricos (LaCoPol), Universidade Federal de Pelotas (UFPel), Campus Capão do Leão s/n, Pelotas-RS, 96010-900, Brazil

    Jaqueline F. de Souza, Thalia S. A. Lemos & André R. Fajardo

  2. Grupo de Catálise e Estudos Teóricos (GCATE), Universidade Federal de Pelotas (UFPel), Campus Capão do Leão s/n, Pelotas-RS, 96010-900, Brazil

    André F. P. Biajoli

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  1. Jaqueline F. de Souza
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  2. Thalia S. A. Lemos
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  3. André F. P. Biajoli
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Correspondence to André R. Fajardo.

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de Souza, J.F., Lemos, T.S.A., Biajoli, A.F.P. et al. Phosphine-Functionalized Chitosan Microparticles as Support Materials for Palladium Nanoparticles in Heck Reactions. Catal Lett 152, 2933–2946 (2022). https://doi.org/10.1007/s10562-021-03914-z

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