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Preparation and Catalytic Performance in Propylene Epoxidation of Hydrophobic Hierarchical Porous TS-1 Zeolite

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Abstract

The contribution introduced a new type of titanosilicate molecular sieve HTS-1-X with high specific surface area, high titanium content, hierarchical pores, hydrophobicity, and reusable by one-step dry gel conversion method using phenolic resin as a hydrophobic reagent. The HTS-1-X catalysts showed good catalytic ability in the propylene epoxidation reaction, and the high specific surface area greatly increased the conversion rate of hydrogen peroxide (H2O2). By controlling the content of phenolic resin, the selectivity of propylene oxide (PO) could reach the optimal value. After five cycles of reusability, the selectivity of PO was still maintained at a high position (88.94%). Through Raman, 13C-MAS-NMR and other characterization methods, the possible preparation mechanism of phenolic resin hydrophobic modification of titanium silicalite-1 was proposed. This research put forwarded a simple and novel operation method to make high-performance and hydrophobic hierarchical porous molecular sieve, making it a highly efficient catalyst that would be widely used in the oxidation of macromolecular olefins.

Graphic Abstract

The simple and efficient dry gel conversion method was chosen to prepare titanium silicalite-1 (TS-1) instead of the traditional hydrothermal synthesis method. The hydrophobic carbon source (phenolic resin) was added in the one-step synthesis process, and the hydrophobic hierarchical porous HTS-1-X was successfully synthesized.

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References

  1. Han Z, Shen Y, Qin X et al (2019) ChemistrySelect 4(5):1618–1626

    Article  CAS  Google Scholar 

  2. Zhang T, Chen X, Chen G et al (2018) J Mater Chem A 6(20):9473–9479

    Article  CAS  Google Scholar 

  3. Wu M, Song H, Chou L (2013) RSC Adv 3(45):23562–23570

    Article  CAS  Google Scholar 

  4. Feng X, Liu Y, Li Y et al (2016) AIChE J 62(11):3963–3972

    Article  CAS  Google Scholar 

  5. Li Y, Fan Q, Li Y et al (2019) Appl Surf Sci 483:652–660

    Article  CAS  Google Scholar 

  6. Zhu Q, Liu H, Miao C et al (2020) Ind Eng Chem Res 59(7):2828–2838

    Article  CAS  Google Scholar 

  7. Taramasso M, Perego G, Notari B (1983) US Pat 4410501

  8. Lin J, Xin F, Yang L et al (2014) Catal Commun 45(45):104–108

    Article  CAS  Google Scholar 

  9. Wu X, Wang Y, Zhang T et al (2014) Catal Commun 50:59–62

    Article  CAS  Google Scholar 

  10. Tao H, Li C, Ren J et al (2011) J Solid State Chem 184(7):1820–1827

    Article  CAS  Google Scholar 

  11. Ok D-Y, Jiang N, Prasetyanto EA et al (2011) Microporous Mesoporous Mater 141(1):2–7

    Article  CAS  Google Scholar 

  12. White RJ, Fischer A, Goebel C et al (2014) J Am Chem Soc 136(7):2715–2718

    Article  CAS  PubMed  Google Scholar 

  13. Wang Z, Xu L, Jiang J et al (2012) Microporous Mesoporous Mater 156:106–114

    Article  CAS  Google Scholar 

  14. Liu D, Li G, Liu J et al (2018) ACS Appl Mater Interfaces 10(26):22119–22129

    Article  CAS  PubMed  Google Scholar 

  15. Milina M, Mitchell S, Crivelli P et al (2014) Nat Commun 5(1):3922

    Article  Google Scholar 

  16. Tao Y, Kanoh H, Kaneko K et al (2003) J Am Chem Soc 125(20):6044–6045

    Article  CAS  PubMed  Google Scholar 

  17. Zhu Q, Liang M, Yan W et al (2019) Microporous Mesoporous Mater 278:307–313

    Article  CAS  Google Scholar 

  18. Lv G, Deng S, Zhai Y et al (2018) Appl Catal A 567:28–35

    Article  CAS  Google Scholar 

  19. Wei Y, Li G, Su R et al (2019) Appl Catal A 582:117108

    Article  CAS  Google Scholar 

  20. Shen X, Wang J, Liu M et al (2019) Catal Lett 149(9):2586–2596

    Article  CAS  Google Scholar 

  21. Peng H-G, Li X-H, Xu L et al (2013) Chin Chem Lett 24(7):559–562

    Article  CAS  Google Scholar 

  22. Weissenberger T, Leonhardt R, Zubiri BA et al (2019) Chem-Eur J 25(63):14430–14440

    Article  CAS  PubMed  Google Scholar 

  23. Jiao Y, Adedigba A-L, He Q et al (2018) Catal Sci Technol 8(8):2211–2217

    Article  CAS  Google Scholar 

  24. Dvoyashkin M, Wilde N, Haase J et al (2018) RSC Adv 8(68):38941–38944

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  25. Du Q, Guo Y, Wu P et al (2019) Microporous Mesoporous Mater 275:61–68

    Article  CAS  Google Scholar 

  26. Ge T, Hua Z, Lv J et al (2017) CrystEngComm 19(10):1370–1376

    Article  CAS  Google Scholar 

  27. Du C, Cui N, Li L et al (2019) RSC Adv 9(17):9694–9699

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  28. Wei Y, Parmentier TE, Zečević J et al (2015) Chem Soc Rev 44(20):7234–7261

    Article  CAS  PubMed  Google Scholar 

  29. Zhang M, Lin Z, Huang Q et al (2020) Adv Powder Technol 31(5):2025–2034

    Article  CAS  Google Scholar 

  30. Wang B, Lu L, Ge B et al (2019) J Porous Mater 26(1):227–237

    Article  CAS  Google Scholar 

  31. Wang B, Han H, Ge B et al (2019) New J Chem 43(26):10390–10397

    Article  CAS  Google Scholar 

  32. Adedigba A-L, Sankar G, Catlow CRA et al (2017) Microporous Mesoporous Mater 244:83–92

    Article  CAS  Google Scholar 

  33. Lv G, Wang F, Zhang X et al (2018) Langmuir 34(1):302–310

    Article  CAS  PubMed  Google Scholar 

  34. Khomane RB, Kulkarni BD, Paraskar A et al (2002) Mater Chem Phys 76(1):99–103

    Article  CAS  Google Scholar 

  35. Pang C, Xiong J, Li G et al (2018) J Catal 366:37–49

    Article  CAS  Google Scholar 

  36. Wang B, Lin M, Zhu B et al (2016) CN Pat 106145148A

  37. Shakeri M, Dehghanpour SB (2020) Microporous Mesoporous Mater 298:110066

    Article  CAS  Google Scholar 

  38. Naik SP, Chiang AST, Thompson RW et al (2003) Chem Mater 15(3):787–792

    Article  CAS  Google Scholar 

  39. Wang X, Xiao C, Zheng P et al (2020) J Catal 384:136–146

    Article  CAS  Google Scholar 

  40. Zuo Y, Liu M, Zhang T et al (2015) ChemCatChem 7(17):2660–2668

    Article  CAS  Google Scholar 

  41. Zhou H, Xiao L, Liu X et al (2012) Chem Commun 48(55):6954–6956

    Article  CAS  Google Scholar 

  42. Kulinich SA, Farzaneh M (2009) Appl Surf Sci 255(7):4056–4060

    Article  CAS  Google Scholar 

  43. Tekla J, Tarach KA, Olejniczak Z et al (2016) Microporous Mesoporous Mater 233:16–25

    Article  CAS  Google Scholar 

  44. Guo Q, Sun K, Feng Z et al (2012) Chem-A Eur J 18(43):13854–13860

    Article  CAS  Google Scholar 

  45. Zhang K, Chen X-J (2018) AIP Adv 8(2):025004

    Article  Google Scholar 

  46. Renda CG, Bertholdo R (2018) J Polym Res 25(11):24111

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial support by the National Natural Science Foundation of China (Grant No. 21606168).

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, No. 92 Weijin Road, Nankai District, Tianjin, 300072, China

    Baohe Wang, Yuan Zhu, Huanhuan Han, Qiaoyun Qin, Zhaobang Zhang & Jing Zhu

  2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, No. 92 Weijin Road, Nankai District, Tianjin, 300072, China

    Baohe Wang, Yuan Zhu, Huanhuan Han, Qiaoyun Qin, Zhaobang Zhang & Jing Zhu

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  1. Baohe Wang
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  2. Yuan Zhu
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  3. Huanhuan Han
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  4. Qiaoyun Qin
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  5. Zhaobang Zhang
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  6. Jing Zhu
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Correspondence to Jing Zhu.

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Wang, B., Zhu, Y., Han, H. et al. Preparation and Catalytic Performance in Propylene Epoxidation of Hydrophobic Hierarchical Porous TS-1 Zeolite. Catal Lett 152, 3076–3088 (2022). https://doi.org/10.1007/s10562-021-03805-3

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  • DOI: https://doi.org/10.1007/s10562-021-03805-3

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