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One-Step Synthesis of High-Silica ZSM-5 Zeolite with Less Internal Silicon Hydroxyl Groups: Highly Stable Catalyst for Methanol to Propene Reaction

Abstract

High-silica ZSM-5 zeolite with less internal silicon hydroxyl groups was directly synthesized through a one-step hydrothermal crystallization method. The physicochemical properties of high-silica ZSM-5 zeolite with less internal silicon hydroxyl groups together with its catalytic capability for methanol to propene reaction were roundly compared with that of commercial ZSM-5 zeolite and another high-silica ZSM-5 zeolite with similar acid distribution but different hydroxyl distribution to it. The results show that high-silica ZSM-5 zeolite with less internal silicon hydroxyl groups has good crystallinity, uniform crystal size and moderate acidity, which is a highly stable catalyst for methanol to propene reaction. Based on the characterization and reaction results, the high stability of high-silica ZSM-5 zeolite with less internal silicon hydroxyl groups in methanol to propene reaction proves that the distribution of silicon hydroxyl groups plays a significant role in the deactivation of ZSM-5 zeolite.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21978155) and the Postdoctoral Applied Research Project of Qingdao (01020240113).

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Correspondence to Dongmei Xu or Chunyi Li.

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Huang, H., Yuan, C., Zhong, P. et al. One-Step Synthesis of High-Silica ZSM-5 Zeolite with Less Internal Silicon Hydroxyl Groups: Highly Stable Catalyst for Methanol to Propene Reaction. Catal Lett (2021). https://doi.org/10.1007/s10562-021-03796-1

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Keywords

  • Methanol
  • Propene
  • High-silica ZSM-5 zeolite
  • Silicon hydroxyl groups
  • Deactivation