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Charge Modified Porous Organic Polymer Stabilized Ultrasmall Platinum Nanoparticles for the Catalytic Dehydrogenative Coupling of Silanes with Alcohols

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Abstract

Developing an ideal stabilizer to prevent the aggregation of nanoparticles is still a big challenge for the practical application of noble metal nanocatalysts. Herein, we develop a charge (NTf2−) modified porous organic polymer (POP-NTf2) to stabilize ultrasmall platinum nanoparticles. The catalyst is characterized and applied in the catalytic dehydrogenative coupling of silanes with alcohols. The catalyst exhibits excellent catalytic performance with highly dispersed ultrasmall platinum nanoparticles (ca. 2.22 nm). Moreover, the catalyst can be reused at least five times without any performance significant loss and Pt NPs aggregation.

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Acknowledgements

This research was supported by the National Natural Science Foundation of China (Grant No. 22002056).

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Author notes

  1. Shaohua Wu and Tongtong Su have contributed equally to this work.

Authors and Affiliations

  1. Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, College of Chemistry, Nanchang University, Nanchang, 330031, Jiangxi, People’s Republic of China

    Shaohua Wu, Tongtong Su, Senqun Liu, Dan Cheng, Xiaohua Ma, Sanqi Liang, Shunmin Ding & Chao Chen

  2. Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices, School of Chemistry, Biology and Materials Science, East China University of Technology, Nanchang, 330013, People’s Republic of China

    Rong Zeng

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  1. Shaohua Wu
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  2. Tongtong Su
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  5. Rong Zeng
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Correspondence to Rong Zeng, Shunmin Ding or Chao Chen.

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Wu, S., Su, T., Liu, S. et al. Charge Modified Porous Organic Polymer Stabilized Ultrasmall Platinum Nanoparticles for the Catalytic Dehydrogenative Coupling of Silanes with Alcohols. Catal Lett 152, 1711–1718 (2022). https://doi.org/10.1007/s10562-021-03763-w

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  • DOI: https://doi.org/10.1007/s10562-021-03763-w

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