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One-Pot Three-Component Synthesis of 2,4,5-Triaryl-1H-imidazoles Using Mn2+ Complex of [7-Hydroxy-4-methyl-8-coumarinyl] Glycine as a Heterogeneous Catalyst

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Abstract

A highly efficient and simple synthesis of 2,4,5-trisubstituted imidazoles has been developed using highly reusable support‐free Mn2+complex of [7-hydroxy-4-methyl-8-coumarinyl] glycine as a heterogeneous catalyst via a one-pot three-component reaction of benzil, aldehydes and ammonium acetate as a nitrogen source. Moreover, this catalyst was characterized by various techniques such as field emission scanning electron microscope (FE-SEM), energy dispersive X-ray spectroscopy (EDX), FT-IR spectroscopy, powder X-ray diffraction (XRD), inductively coupled plasma (ICP) and thermal gravimetric analysis (TGA). Also, the catalyst is stable and could be reused for at least six times without significant loss of activity.

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Acknowledgements

We gratefully acknowledge the support of this work by the Shiraz University Research Council.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, Shiraz University, 71454, Shiraz, Iran

    Hashem Sharghi & Seyyede Faeze Razavi

  2. Faculty of Shahid Rajaee, Shiraz Branch, Department of Chemical and Materials Engineering, Technical and Vocational University (TVU), Shiraz, Iran

    Mahdi Aberi

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  1. Hashem Sharghi
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  2. Seyyede Faeze Razavi
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  3. Mahdi Aberi
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Correspondence to Hashem Sharghi.

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Sharghi, H., Razavi, S.F. & Aberi, M. One-Pot Three-Component Synthesis of 2,4,5-Triaryl-1H-imidazoles Using Mn2+ Complex of [7-Hydroxy-4-methyl-8-coumarinyl] Glycine as a Heterogeneous Catalyst. Catal Lett 152, 1769–1783 (2022). https://doi.org/10.1007/s10562-021-03717-2

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