Abstract
Understanding the effects of cerium in the formaldehyde (HCHO) catalytic oxidation performance over Ag/MCM-41 catalysts, cerium modified MCM-41 mesoporous materials (Ce-MCM-41) with different ratios were synthesized by one-step hydrothermal method. The activity test results showed that Ag/Ce-MCM-41 with the ratio of Si:Ce = 1:1 catalysts could reach complete HCHO oxidation above 130 °C. These Ag/Ce-MCM-41 catalysts with different Si:Ce ratios were characterized by IR, SXRD, XRD, TEM, UV–Vis, Raman, XPS and H2-TPR. The results show that the interactions between Ag and Ce, between Ce and SiO2 in our Ag/Ce-MCM-41 are enhanced due to adding Ce to MCM-41. The presence of Ce-SiO2 interaction dramatically enhances the reducibility of surface-capping oxygen of CeO2, promotes the bulk oxygen migration to the surface and creates oxygen vacancies in the bulk region of CeO2 and the presence of more oxygen vacancies can facilitate the anchoring and dispersing of Ag particles, which lastly improves the interaction between Ag and Ce. In addition, the amount of formed oxygen vacancy is the highest when the Si:Ce = 1:1. The activation of surface oxygen is closely related to oxygen vacancy, O2 may be transformed into the highly active O2−. The high active O2− in surface adsorbed oxygen promotes the activation of oxygen molecules and enhanced the catalytic oxidation of HCHO.
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Lu S, Li K, Huang F, Chen C, Sun B (2017) Appl Surf Sci 400:277–282
Jia M, Bai H, Zhao R, Shen Y, Li Y (2008) J Rare Earths 26:528–531
Yong CH, Ke QS, Ke HH, Liu G, Bo QX (2010) Catal Today 158:415–422
Yan Z, Xu Z, Yu J, Jaroniec M (2016) Appl Catal B-Environ 199:458–465
Ma L, Wang D, Li J, Bai B, Fu L, Li Y (2014) Appl Catal B-Environ 148:14936–14943
Chen D, Shi J, Yao Y, Wang S, Wu C (2019) React Kinet Mech Catal 127:315–329
Chen D, Qu Z, Lv Y, Lu X, Chen W, Gao X (2015) J Mol Catal A Chem 404–405:98–105
Chen D, Qu Z, Sun Y, Gao K, Wang Y (2013) Appl Catal B-Environ 142–143:838–848
Chen D, Qu Z, Shen S, Li X, Shi Y, Wang Y, Fu Q, Wu J (2011) Catal Today 175:338–345
Yin AY, Wen C, Wei LD, Fan KN (2011) Appl Catal B Environ 108–109:90–99
Kumar N, Konova PM, Naydenov A, Heikillä T, Salmi T, Murzin DY (2004) Catal Lett 98:57–60
Qu Z, Chen D, Sun Y, Wang Y (2014) Appl Catal A Gen 487:100–109
Na H, Zhu T, Liu Z (2014) Catal Sci Technol 4:2051–2057
Ma C, Wang D, Xue W, Dou B, Wang H, Hao Z (2011) Environ Sci Technol 45:3628–3634
Chen J, Yan D, Xu Z, Chen X, Chen X, Xu W, Jia H, Chen J (2018) Environ Sci Technol 52:4728–4737
Xia Y, Dai H, Zhang L, Deng J, He H, Chak TA (2010) Appl Catal B Environ 100:229–237
Bai L, Wyrwalski F, Lamonier JF, Khodakov AY, Monflier E, Ponchel A (2013) Appl Catal B Environ 138–139:381–390
Beste A, Overbury SH (2016) Surf Sci 648:242–249
Imamura S, Uchihori D, Utani K, Ito T (1994) Catal Lett 24:377–384
Pino L, Vita A, Cipitì F, Laganà M, Recupero V (2011) Appl Catal B Environ 104:64–73
Dai Q, Wang X, Chen G, Zheng Y, Lu G (2007) Microporous Mesoporous Mat 100:268–275
Wang S, Zhao C, Wang D, Wang Y, Liu F (2016) RSC Adv 6:18800–18808
Pal N, Cho EB, Kim D (2014) RSC Adv 4:9213–9222
Shi X, Ji S, Wang K (2008) Catal Lett 125:331–339
Wang K, Li X, Ji S, Shi X, Tang J (2009) Energy Fuels 23:25–31
Sahu P, Eniyarppu S, Ahmed M, Sharma D, Sakthivel A (2017) J Porous Mat 25:999–1005
Laha SC, Mukherjee P, Sainkar SR, Kumar R (2002) J Catal 207:213–223
Dehghani S, Haghighi M (2019) Waste Manag 95:584–592
Alibeik MA, Pouriayevali M (2012) Catal Commun 22:13–18
Bing J, Li L, Lan B, Liao G, Zeng J, Zhang Q, Li X (2012) Appl Catal B Environ 115–116:16–24
Portela R, Canela MC, Sanchez B, Marques FC, Stumbo AM, Tessinari RF, Coronado JM, Suarez S (2008) Appl Catal B Environ 84:643–650
Ying Z, Li ZH, Yong Z, Shen XN, Lin LX (2006) Mater Lett 60:3221–3223
Carvalho WA, Varaldo PB, Wallau M, Schuchardt U (1997) Zeolites 18:408–416
Yang G, Xu Y, Su X, Xie Y, Yang C, Dong Z, Wang J (2014) Ceram Int 40:3969–3973
Ma L, Ji J, Yu F, Ai N, Jiang H (2013) Microporous Mesoporous Mat 16:6–13
Zhang X, Yang Y, Song L, Wang Y, He C, Wang Z, Cui L (2018) Mol Catal 447:80–89
Mandi U, Kundu SK, Salam N, Bhaumik A, Islam SM (2016) J Colloid Interface Sci 467:291–299
Chen H, Liu Y, Zhao G (2011) Electron Mater Lett 7:151–154
Pan W-G, Zhou Y, Guo R-T, Jin Q, Ding C-G, Guo S-Y (2013) Asian J Chem 25:9079–9082
Wang N, Chu W, Zhang T, Zhao XS (2012) Int J Hydrogen Energy 37:19–30
Shi C, Cheng M, Qu Z, Bao X (2005) J Mol Catal A Chem 235:35–43
Renuka NK, Praveen AK, Aniz CU (2013) Microporous Mesoporous Mat 169:35–41
Vargas OAG, Heredia JADR, Toriello VAS, Rangel RH, Wang JA, Chen LF (2018) J Mater Sci Mater Electron 29:15621–15631
Police AKR, Basavaraju S, Valluri D, Machiraju S (2015) Bull Mat Sci 38:234
Encina ER, Coronado EA (2011) J Phys Chem C 115:15908–15914
Wu Z, Li M, Howe J, Meyer HM, Overbury SH (2010) Langmuir 26:16595–16606
Li H-F, Zhang N, Chen P, Luo M-F, Lu J-Q (2011) Appl Catal B Environ 110:279–285
Katta L, Sudarsanam P, Thrimurthulu G, Reddy BM (2010) Appl Catal B Environ 101:101–108
Spanier JE, Robinson RD, Zhang F, Chan SW, Herman IP (2001) Phys Rev B 64(24):245407
Wang Y, Yang Y, Liu N, Wang Y, Zhang X (2018) RSC Adv 8:33096–33102
Wang L, Yin G, Yang Y, Zhang X, Kinetics R (2019) React Kinet Mech Catal 128:193–204
Hu F, Chen J, Peng Y, Song H, Li K, Li J (2018) Chem Eng J 331:425–434
Shen WJ, Tang XF, Chen JL, Li YG, Li Y, Xu YD (2006) Chem Eng J 118:119–125
Zheng Y, Li K, Wang H, Wang Y, Tian D, Wei Y, Zhu X, Zeng C, Luo Y (2016) J Catal 344:365–377
Zhang Z, Shi H, Wu Q, Bu X, Yang Y, Zhang J (2019) Mater Lett 242:20–23
Liu S, Wu X, Liu W, Chen W, Ran R, Li M, Weng D (2016) J Catal 337:188–198
Zhang X, Wang Y, Hou F, Li H, Yang Y, Zhang X, Yang Y, Wang Y (2017) Appl Surf Sci 391:476–483
Weaver JF, Hoflund GB (1994) J Phys Chem 98:8519–8524
Xie S, Liu Y, Deng J, Zhao X, Yang J, Zhang K, Han Z, Dai H (2016) J Catal 342:17–26
Chen Z, Wang L, Xu H, Wen Q (2020) Chem Eng J 389:124345
Wei Y, Liu J, Zhao Z, Chen Y, Xu C, Duan A, Jiang G, He H (2011) Angew Chem Int Ed Engl 50:2326–2329
Wang Y, Yu L, Wang R, Wang Y, Zhang X (2020) J Colloid Interface Sci 564:392–405
Hu Y, Lü W, Liu D, Liu J, Shi L, Sun Q (2009) J NAT GAS Chem 18:445–448
Ma L, Seo CY, Chen X, Li J, Schwank JW (2018) Chem Eng J 350:419–428
Liu B, Li C, Zhang Y, Liu Y, Hu W, Wang Q (2012) Appl Catal B Environ 111–112:467–475
Yang S, Liu D, LiuTop S (2008) Catal 47:101–108
Perala V, Devaiah D, Deshetti J, Deboshree M, Muga V, Benjaram R (2019) Catal Lett 150:948–962
Dai Q, Bai S, Wang Z, Wang X, Lu G (2012) Appl Catal B Environ 126:64–75
Yamazaki K, Kayama T, Dong F, Shinjoh H (2011) J Catal 282:289–298
Machida M, Murata Y, Kishikawa K, Zhang D, Ikeue K (2008) Chem Mat 20:4489–4494
Acknowledgements
This work was supported by Natural Science Fund for Colleges and Universities in Jiangsu Province, China (20KJB610013), National Nature Science Foundation of China (NO.21507109, NO.51909230), The China Postdoctoral Science Foundation funded project (Grant No. 2019 M661948). The study was supported by Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering, MOE (KLIEEE-17-02).
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Chen, D., Shen, H., Zhang, Y. et al. HCHO Catalytic Oxidation Performance over Cerium Containing MCM-41 Type Mesoporous Materials Supported Ag Catalysts. Catal Lett 152, 187–198 (2022). https://doi.org/10.1007/s10562-021-03611-x
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DOI: https://doi.org/10.1007/s10562-021-03611-x