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Hyaluronic Acid-Guided Synthesis of Pd Nanocatalysts for Transfer Hydrogenation of 4-Nitrophenol

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Abstract

Herein Pd nanocatalysts for transfer hydrogenation were synthesized by using hyaluronic acid (HA) as both the reductant and the stabilizer. The effects of molecular weight of HA, molar ratio of [HA]/[Na2PdCl4] and reduction temperature, were evaluated in Pd-catalyzed transfer hydrogenation of 4-nitrophenol. The most active Pd NPs show the TOF value of 131.07 h−1 at 50 °C with the equimolar mixture of formic acid and sodium formate. Further, uniformly distributed Pd NPs were successfully synthesized through the reduction of Pd (II) precursors on HA-modified magnetic NPs, which were constructed through electrostatic layer-by-layer assembly. The hybrid catalysts also exhibit high activity with the mixed hydrogen source. This work paves a promising way to construct highly active hybrid catalysts through the combination of in-situ reduction and electrostatic layer-by-layer methods.

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Acknowledgements

This study was funded by National Natural Science Foundation of China (21878225, 21776215).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Tianjin University, 135 Yaguan Road, Jinnan District, Tianjin, 300350, People’s Republic of China

    Danyang Yin, Jinli Zhang, Wei Li & Yan Fu

  2. Frontier Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering (Ministry of Education), Tianjin University, Tianjin, 300072, People’s Republic of China

    Danyang Yin, Jinli Zhang, Wei Li & Yan Fu

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  1. Danyang Yin
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  2. Jinli Zhang
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  3. Wei Li
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  4. Yan Fu
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Correspondence to Yan Fu.

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Yin, D., Zhang, J., Li, W. et al. Hyaluronic Acid-Guided Synthesis of Pd Nanocatalysts for Transfer Hydrogenation of 4-Nitrophenol. Catal Lett 151, 1902–1910 (2021). https://doi.org/10.1007/s10562-020-03455-x

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