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Ferrocene-Modified Metal–Organic Frameworks as a Peroxidase-Mimicking Catalyst

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Abstract

Recently, the development of enzyme-like catalysts attracts increasing attention owing to their remarkable advantages over natural enzymes. Metal organic frameworks (MOFs) are ideal candidates for building biomimetic systems, because their diverse composition and structure can generate various biomimetic active centers. In this study, the postsynthetic modification was performed to create a peroxidase (POD)-mimicking catalyst through grafting ferrocene group to a Zr-based MOF material (UiO-66-NH2). The obtained UiO-66-Fc shows significant POD-like catalytic ability in the oxidation of 3,3′,5,5′-tetramethylbenzidine with the adding of hydrogen peroxide (H2O2). In addition, benefiting from the MOF moiety, UiO-66-Fc displayed enhanced catalytic activity, improved optimum condition and favorable reusability. Finally, based on the catalytic function of UiO-66-Fc, simple colorimetric methods for the quantitative detection of H2O2, glucose and uric acid were established respectively, which displayed wider linear range and lower limit of detection.

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Acknowledgements

This work was supported by the Natural Science Foundation of China (21621004 and 21676191) and Tianjin Key Technology R&D Program of China (17YFZCSF00970).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin, 300350, China

    Pengfei Gao, Yaoyao Feng, Mengfan Wang, Wei Qi, Rongxin Su & Zhimin He

  2. The Co-Innovation Centre of Chemistry and Chemical Engineering of Tianjin, Tianjin, 300350, China

    Wei Qi & Rongxin Su

  3. Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin, 300350, China

    Mengfan Wang, Wei Qi & Rongxin Su

  4. National Center for Fire Engineering Technology, Tianjin Fire Research Institute of MEM, Tianjin, 300381, China

    Nan Jiang

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  1. Pengfei Gao
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  2. Yaoyao Feng
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Correspondence to Mengfan Wang.

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Gao, P., Feng, Y., Wang, M. et al. Ferrocene-Modified Metal–Organic Frameworks as a Peroxidase-Mimicking Catalyst. Catal Lett 151, 478–486 (2021). https://doi.org/10.1007/s10562-020-03314-9

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  • DOI: https://doi.org/10.1007/s10562-020-03314-9

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